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We derive and solve a differential equation satisfied by the probability distribution of the work done on a single biomolecule in a mechanical unzipping experiment. The unzipping is described as a thermally activated escape process in an…

Soft Condensed Matter · Physics 2007-05-23 Alberto Imparato , Luca Peliti

When a thermally isolated system performs a driving process in the quasistatic regime, its variation of average energy is equal to its quasistatic work. Even though presenting this simple definition, few attempts have been made to describe…

Statistical Mechanics · Physics 2025-02-17 Pierre Nazé

We have studied the nature of classical work ($W_{c}$) and thermodynamic work ($W$) fluctuations in systems driven out of equilibrium both in transient and time periodic steady state. As the observation time of trajectory increases, we show…

Classical Physics · Physics 2015-05-13 Mamata Sahoo , A. M Jayannavar

One particle in a classical perfect gas is driven out of equilibrium by changing its mass over a short time interval. The work done on the driven particle depends on its collisions with the other particles in the gas. This model thus…

Statistical Mechanics · Physics 2014-04-22 T. G. Philbin , J. Anders

We investigate the work dissipated during the irreversible unfolding of single molecules by mechanical force, using the simplest model necessary to represent experimental data. The model consists of two levels (folded and unfolded states)…

Biological Physics · Physics 2012-08-27 F. Ritort , C. Bustamante , I. Tinoco,

The work performed on a system in a microcanonical state by changes in a control parameter is characterized in terms of its statistics. The transition probabilities between eigenstates of the system Hamiltonians at the beginning and the end…

Statistical Mechanics · Physics 2014-01-21 Peter Talkner , Manuel Morillo , Juyeon Yi , Peter Hanggi

The theory of quantum thermodynamics predicts fundamental bounds on work extraction from quantum states. As these bounds are derived in a very general and abstract setting, it is unclear how relevant they are in an experimental context,…

Quantum Physics · Physics 2018-07-13 Niels Lörch , Christoph Bruder , Nicolas Brunner , Patrick P. Hofer

Probability distributions of the magnetic work are computed for the 2D Ising model by means of Monte Carlo simulations. The system is first prepared at equilibrium for three temperatures below, at and above the critical point. A magnetic…

Statistical Mechanics · Physics 2007-05-23 Christophe Chatelain , Dragi Karevski

The Jarzynski equality relates the free energy difference between two equilibrium states to the fluctuating irreversible work afforded to switch between them. The prescribed fixed temperature for the equilibrium states implicitly constrains…

Statistical Mechanics · Physics 2020-09-03 Tobias Thalheim , Marco Braun , Gianmaria Falasco , Klaus Kroy , Frank Cichos

The Jarzynski Equality relates the free energy difference between two equilibrium states of a system to the average of the work over all irreversible paths to go from one state to the other. We claim that the derivation of this equality is…

Statistical Mechanics · Physics 2009-11-10 E. G. D. Cohen , David Mauzerall

Nonequilibrium processes of small systems such as molecular machines are ubiquitous in biology, chemistry and physics, but are often challenging to comprehend. In the past two decades, several exact thermodynamic relations of nonequilibrium…

Statistical Mechanics · Physics 2018-02-26 Thai M. Hoang , Rui Pan , Jonghoon Ahn , Jaehoon Bang , H. T. Quan , Tongcang Li

The transition between a regime in which thermodynamic relations apply only to ensembles of small systems coupled to a large environment and a regime in which they can be used to characterize individual macroscopic systems is analyzed in…

Statistical Mechanics · Physics 2015-05-30 Alberto Suárez , Robert Silbey , Irwin Oppenheim

For processes during which a macroscopic system exchanges no heat with its surroundings, the second law of thermodynamics places two lower bounds on the amount of work performed on the system: a weak bound, expressed in terms of a…

Statistical Mechanics · Physics 2019-07-24 Christopher Jarzynski

A main goal of single-molecule experiments is to evaluate equilibrium free energy differences by applying fluctuation relations to repeated work measurements along irreversible processes. We quantify the error that is made in a free energy…

Statistical Mechanics · Physics 2009-06-22 Alessandro Mossa , Sara de Lorenzo , Josep Maria Huguet , Felix Ritort

Almost 25 years ago, Jarzynski published a paper in which it was asserted: the work done, W, in driving a system from state A to state B, characterized by the Helmholtz free energies FA and FB, satisfies an equality in which an average over…

General Physics · Physics 2022-06-07 Ronald F. Fox

In quantum systems which satisfy the hypothesis of equal weights for eigenstates [4], the maximum work principle (for extremely slow and relatively fast operation) is derived by using quantum dynamics alone. This may be a crucial step in…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

We derive optimal-work finite time protocols for a colloidal particle in a Gaussian well in the general non-Markovian underdamped regime in contact with a single reservoir. Optimal work protocols with and without measurements of position…

Statistical Mechanics · Physics 2018-05-08 Oscar Paredes-Altuve , Ernesto Medina , Pedro J. Colmenares

Jarzynski's identity for the free energy difference between two equilibrium states can be viewed as a special case of a more general procedure based on phase space mappings. Solving a system's equation of motion by approximate means…

Statistical Mechanics · Physics 2009-11-11 Wolfgang Lechner , Harald Oberhofer , Christoph Dellago , Phillip L. Geissler

The Jarzynski equality (JE) is analyzed in regard to its validity for both quasi-static transformations in the thermodynamic limit and Hamiltonian evolutions of the work protocol. In the first case, we show that the JE holds for isothermal…

Statistical Mechanics · Physics 2020-05-15 Amilcare Porporato , Salvatore Calabrese

Analytical work probability distributions for open classical systems are scarce; they can only be calculated in a few examples. In this work, I present a new method to derive such quantities for weakly driven processes in the overdamped…

Statistical Mechanics · Physics 2025-04-09 Pierre Nazé