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Starting from a microscopic model, we investigate the optical spectra of molecules in strongly-coupled organic microcavities examining how they might self-consistently adapt their coupling to light. We consider both rotational and…

Mesoscale and Nanoscale Physics · Physics 2016-03-25 Justyna A. Cwik , Peter Kirton , Simone De Liberato , Jonathan Keeling

We observe vacuum Rabi splitting in a lossy nearly confocal cavity indicating the strong coupling regime, despite a weak single-atom single-mode coupling. Strong collective interaction manifests itself in the typical $\sqrt{N}$-dependence…

Quantum Gases · Physics 2011-11-30 A. Wickenbrock , P. Phoonthong , F. Renzoni

We apply the Kubo-Anderson stochastic theory of molecular spectral lineshape to the case of polaritons formed in the collective strong coupling regime. We investigate both the fast and slow limits of the random frequency modulation of the…

Chemical Physics · Physics 2023-10-24 Clàudia Climent , Joseph E. Subotnik , Abraham Nitzan

We present a full quantum theory for the dissipative dynamics of an optical cavity in the ultra-strong light-matter coupling regime, in which the vacuum Rabi frequency is comparable to the electronic transition frequency and the…

Other Condensed Matter · Physics 2009-11-11 Cristiano Ciuti , Iacopo Carusotto

We present experimental observation of the strong light-matter coupling regime in ZnO bulk microcavities grown on silicon. Angle resolved reflectivity measurements, corroborated by transfer-matrix simulations, show that Rabi splittings in…

The way molecules absorb, transfer, and emit light can be modified by coupling them to optical cavities. The extent of the modification is often defined by the cavity-molecule coupling strength, which depends on the number of coupled…

Optics · Physics 2021-06-11 Adarsh B Vasista , Kishan S Menghrajani , William L Barnes

Breaking the time-reversal symmetry of light is of great importance for fundamental physics and has attracted increasing interest in the study of non-reciprocal photonic devices. Here, we experimentally demonstrate a chiral cavity QED…

Quantum Physics · Physics 2023-04-20 Pengfei Yang , Ming Li , Xing Han , Hai He , Gang Li , Chang-Ling Zou , Pengfei Zhang , Yuhua Qian , Tiancai Zhang

The strong coupling regime is observed in a system of two-dimensional electrons whose cyclotron motion is coupled to an electro-magnetic mode in a Fabry-Perot cavity resonator. The Rabi splitting of eigenfrequencies of coupled motion is…

Mesoscale and Nanoscale Physics · Physics 2016-07-28 L. V. Abdurakhimov , R. Yamashiro , A. O. Badrutdinov , D. Konstantinov

Polaritons are compositional light-matter quasiparticles that have recently enabled remarkable breakthroughs in quantum and nonlinear optics, as well as in material science. Despite the enormous progress, however, a direct nanometer-scale…

We study the light-matter coupling of microcavity photons and an interband transition in a one-dimensional (1D) nanowire. Due to the Van Hove singularity in the density of states, resulting in a resonant character of the absorption line,…

Mesoscale and Nanoscale Physics · Physics 2013-03-12 K. B. Arnardottir , O. Kyriienko , M. E. Portnoi , I. A. Shelykh

Chemical reactions and energy transport phenomena have been experimentally reported to be significantly affected by strong light-matter interactions and vibrational polariton formation. These quasiparticles exhibit nontrivial transport…

Chemical Physics · Physics 2023-07-21 Enes Suyabatmaz , Raphael F. Ribeiro

We demonstrate that collective vibrational strong coupling of molecules in thermal equilibrium can give rise to significant local electronic polarizations in the thermodynamic limit. We do so by first showing that the full non-relativistic…

Molecular polaritons are hybrid states of photonic and molecular character that form when molecules strongly interact with light. Strong coupling tunes energy levels and importantly, can modify molecular properties (e.g. photoreaction…

Chemical Physics · Physics 2023-02-14 Francesca Fassioli , Kyu Hyung Park , Sarah E. Bard , Gregory D. Scholes

Accessing chaos in the quantum Rabi model (QRM) usually requires operating far from resonance, combined with ultra- or deep-strong light-matter coupling. This makes direct experiments challenging. In this manuscript, we propose a solution…

Quantum Physics · Physics 2026-03-11 Yan-Song Hu , Yuan Qiu , Ye-Hong Chen , XinYu Zhao , Yan Xia

We show that strong electron-electron interactions in cavity-coupled quantum materials can enable collectively enhanced light-matter interactions with ultrastrong effective coupling strengths. As a paradigmatic example we consider a…

Strongly Correlated Electrons · Physics 2019-09-04 Martin Kiffner , Jonathan Coulthard , Frank Schlawin , Arzhang Ardavan , Dieter Jaksch

$\mathcal{N}$ emitters collectively coupled to a quantised cavity mode are described by the Tavis-Cummings model. We present complete analytical solution of the model in the presence of inhomogeneous couplings and energetic disorder. We…

Quantum Gases · Physics 2022-12-29 M. Ahsan Zeb

Molecular complexes are held together via a variety of bonds, but they all share the common feature that their individual entities are in contact. In this work, we introduce and demonstrate the concept of a \textit{molecular optical bond},…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Jahangir Nobakht , André Pscherer , Jan Renger , Stephan Götzinger , Vahid Sandoghdar

Enhancement of light-matter interactions is of great importance for many nanophotonic devices, and one way to achieve it is to feed energy perfectly to the strongly coupled system. Here, we propose gap-perturbed dimerized gratings based on…

Optics · Physics 2023-02-08 Xin Gu , Xing Liu , Xiaofei Yan , Qi Lin , Wenjuan Du , Lingling Wang , Guidong Liu

Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity…

Quantum Gases · Physics 2014-03-06 Justyna A. Cwik , Sahinur Reja , Peter B. Littlewood , Jonathan Keeling

Plasmonic dimer cavities can induce extreme electric-field hot spots that allow one to access ultrastrong coupling regimes using Raman-type spectroscopy on single vibrating molecules. Using a generalized master equation, we study resonant…

Quantum Physics · Physics 2021-07-29 Stephen Hughes , Alessio Settineri , Salvatore Savasta , Franco Nori
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