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L-edge X-ray absorption spectra for first-row transition metal complexes are obtained from relativistic equation-of-motion singles and doubles coupled-cluster (EOM-CCSD) calculations that make use of the core-valence separation (CVS)…

Light-matter interactions are known to lead to the formation of polariton states through what is called strong coupling, leading to the formation of two hybrid states usually tagged as Upper and Lower Polaritons. Here, we consider a similar…

We propose collective nuclear polaritons formed by hybridizing a 229Th nuclear ensemble with a vacuum-ultraviolet cavity mode generated via four-wave mixing, achieving a collective light-matter coupling that scales as $\sqrt{N}$. In the…

Quantum Physics · Physics 2026-03-17 Liufeng Yang , Jinling Wang , Huijun Li , Junhui Cao , Alexey Kavokin , Congjun Wu

We investigate the microscopic description of exciton-polaritons that involves electrons, holes and photons within a two-dimensional microcavity. We show that in order to recover the simplified exciton-photon model that is typically used to…

Quantum Gases · Physics 2021-09-06 Jesper Levinsen , Guangyao Li , Meera M. Parish

We investigate theoretically the photo absorbtion of the cluster of alkali atoms embedded into a single mode quantum microcavity. We show that when the energy of the giant plasmonic resonance lies close to the energy of the cavity mode, the…

Mesoscale and Nanoscale Physics · Physics 2013-03-15 I. G. Savenko , R. G. Polozkov , I. A. Shelykh

We study the vacuum Rabi splitting of a qubit ultrastrongly coupled to a high-$Q$ cavity mode and a radiation reservoir. Three methods are employed: a numerically exact variational approach with a multiple Davydov ansatz, the rotating-wave…

Quantum Physics · Physics 2023-04-07 Yiying Yan , Tadele T. Ergogo , Zhiguo Lü , Lipeng Chen , JunYan Luo , Yang Zhao

Optical aberrations have been studied for centuries, placing fundamental limits on the achievable resolution in focusing and imaging. In the context of structured light, the spatial pattern is distorted in amplitude and phase, often arising…

We present a quantitative study of the nonlinear optical response of layered perovskites placed inside planar photonic microcavities in the regime of strong light matter coupling, when excitonic and photonic modes hybridize and give rise to…

Mesoscale and Nanoscale Physics · Physics 2022-11-15 A. D. Belogur , D. A. Baghdasaryan , I. V. Iorsh , I. A. Shelykh , V. Shahnazaryan

Molecular polaritons, hybrid light-matter states resulting from strong cavity coupling of optical transitions, may provide a new route to guide chemical reactions. However, demonstrations of cavity-modified reactivity in clean benchmark…

Chemical Physics · Physics 2024-08-20 Liying Chen , Ashley P. Fidler , Alexander M. McKillop , Marissa L. Weichman

Molecular polaritons, hybrid light-matter states formed from the strong coupling of molecular transitions and discrete photonic modes, are a compelling platform for optical control of chemical reactivity. Despite the origins of the field of…

Chemical Physics · Physics 2026-02-11 Jane C. Nelson , Trevor H. Wright , Neo Lin , Madeline Rohde , Marissa L. Weichman

Separation of the two mirror images of a chiral molecule, the enantiomers, is a historically complicated problem of major relevance for biological systems. Since chiral molecules are optically active, it has been speculated that strong…

Chemical Physics · Physics 2024-10-23 Rosario R. Riso , Matteo Castagnola , Enrico Ronca , Henrik Koch

Exciton-polaritons in semiconductor microcavities generate fascinating effects such as long-range spatial coherence and Bose-Einstein Condensation (BEC), which are attractive for their potential use in low threshold lasers, vortices and…

Mesoscale and Nanoscale Physics · Physics 2017-09-27 Shuai Zhang , Qiuyu Shang , Wenna Du , Jia Shi , Yang Mi , Jie Chen , Zhiyong Wu , Yuanzheng Li , Mei Liu , Qing Zhang , Xinfeng Liu

The prototypical system constituted by a two-level atom interacting with a quantized single-mode electromagnetic field is described by the quantum Rabi model (QRM). The QRM is potentially valid at any light-matter interaction regime,…

Accurate rovibrational molecular models are employed to gain insight in high-resolution into the collective effects and intermolecular processes arising when molecules in the gas phase are interacting with a resonant infrared (IR) radiation…

Chemical Physics · Physics 2025-01-20 Tamás Szidarovszky

We demonstrate coherent one-color photoassociation of a Bose-Einstein condensate, which results in Rabi oscillations between atomic and molecular condensates. We attain atom-molecule Rabi frequencies that are comparable to decoherence rates…

Atomic Physics · Physics 2013-10-11 Mi Yan , B. J. DeSalvo , Ying Huang , P. Naidon , T. C. Killian

Vacuum birefringence (VB), a fundamental prediction of nonlinear quantum electrodynamics (QED), has eluded direct laboratory detection due to its extreme weakness. We propose a compact, "self-probing" scheme where a GeV electron beam…

Light-matter coupling in van der Waal's materials holds significant promise in realizing Bosonic condensation and superfluidity. The underlying semiconductor's crystal asymmetry, if any, can be utilized to form anisotropic half-light…

Polaritonic states arise when a bright optical transition of a molecular ensemble is resonantly matched to an optical cavity mode frequency. Here, we lay the groundwork to study the behavior of polaritons in clean, isolated systems by…

Chemical Physics · Physics 2023-10-20 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

Accuracy and precision of measurements are important for patient follow up in oncology but, unfortunately, partial volume effects introduce an undesired variability between observers. Super resolution techniques (SR) combine multiple…

Medical Physics · Physics 2015-06-25 Estanislao Oubel , Hubert Beaumont , Antoine Iannessi

We calculate the intensity of the polariton mediated inelastic light scattering in semiconductor microcavities. We treat the exciton-photon coupling nonperturbatively and incorporate lifetime effects in both excitons and photons, and a…

Strongly Correlated Electrons · Physics 2008-05-04 L. M. Leon Hilario , A. Bruchhausen , A. M. Lobos , A. A. Aligia