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Interaction between light and molecular vibrations leads to hybrid light-matter states called vibrational polaritons. Even though many intriguing phenomena have been predicted for single-molecule vibrational strong coupling (VSC), several…

Strong cavity coupling of gas-phase molecules will enable studies of benchmark chemical processes under strong light-matter interactions with a high level of experimental control and no solvent effects. We recently demonstrated the…

Chemical Physics · Physics 2023-10-26 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

The quantum Rabi model is in the scientific spotlight due to the recent theoretical and experimental progress. Nevertheless, a full-fledged classification of its coupling regimes remains as a relevant open question. We propose a spectral…

Quantum Physics · Physics 2017-07-27 Daniel Z. Rossatto , Celso J. Villas-Bôas , Mikel Sanz , Enrique Solano

Light-matter interactions can occur when an ensemble of molecular resonators is placed in a confined electromagnetic field. In the strong coupling regime the rapid exchange of energy between the molecules and the electromagnetic field…

Mesoscale and Nanoscale Physics · Physics 2020-08-10 Philip A. Thomas , Wai Jue Tan , Henry A. Fernandez , William L. Barnes

Advances in vectorial polarisation-resolved imaging are bringing new capabilities to applications ranging from fundamental physics through to clinical diagnosis. Imaging polarimetry requires determination of the Mueller matrix (MM) at every…

The strong coupling between molecules and photonic modes in a Fabry-P\'{e}rot optical cavity, which forms hybrid light-matter states called polaritons, has been demonstrated as a promising route to control the rates of chemical reactions.…

Quantum Physics · Physics 2025-05-22 Kunyang Sun , Matthew Du , Joel Yuen-Zhou

Molecular polaritons arise from electronic or vibrational strong coupling (ESC and VSC) with confined electromagnetic fields. While these have been widely studied, the influence of electron-nuclear dynamics in driven cavities remains…

Strong coupling in the conventional sense requires that the Rabi cycling process between two interacting states is faster than other dissipation rates. Some recent experimental findings show intriguing properties that were attributed to…

Materials Science · Physics 2026-03-09 Ben Johns , Nitin Yadav , Anand Vinod , Kuljeet Kaur , Jino George

We investigate the interaction of excitons in a two dimensional lattice and photons in a planar cavity in the presence of disorder. The strong exciton-photon coupling is described in terms of polariton quasi-particles, which are scattered…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Michal Grochol , Carlo Piermarocchi

Vectorial forms of structured light that are non-separable in their spatial and polarisation degrees of freedom have become topical of late, with an extensive toolkit for their creation and control. In contrast, the toolkit for quantifying…

Molecular polaritons arise when molecules interact so strongly with light that they become entangled with each other. This light-matter hybridization alters the chemical and physical properties of the molecular system and allows chemical…

Chemical Physics · Physics 2023-07-28 Tor S. Haugland , John P. Philbin , Tushar K. Ghosh , Ming Chen , Henrik Koch , Prineha Narang

Quantum vortices are the quantized version of classical vortices. Their center is a phase singularity or vortex core around which the flow of particles as a whole circulates and is typical in superfluids, condensates and optical fields.…

Several years ago, it was shown that strong coupling between an electronic transition in organic molecules and a resonant photonic structure can modify the electronic landscape of the molecules and affect their chemical behavior. Since…

We study light scattering by systems combining randomly rough surface and volume dielectric fluctuations. We introduce a general model including correlations between surface and volume disorders, and we study the scattering properties…

Optics · Physics 2020-05-27 J. -P. Banon , I. Simonsen , R. Carminati

Vacuum Rabi splitting relies on symmetrical splitting of the common resonance frequency of atoms and the cavity in which the atoms reside. In this work, we argue that vacuum Rabi splitting is a manifestation of virtual light-matter two-mode…

Quantum Physics · Physics 2024-03-20 Karol Gietka

Strong light-matter coupling is a quantum process in which light and matter are coupled together, generating hybridized states. This is similar to the notion of molecular hybridization, but one of the components is light. Here, we utilized…

Applied Physics · Physics 2024-02-20 Jhuma Dutta , Pooja Bhatt , Kuljeet Kaur , Daniel E. Gómez , Jino George

We present a formalism to study molecular polaritons based on the bosonization of molecular vibronic states. This formalism accommodates an arbitrary number of molecules $N$, excitations and internal vibronic structures, making it ideal for…

Quantum Physics · Physics 2025-03-18 Juan B. Pérez-Sánchez , Joel Yuen-Zhou

We investigate how proximity to a metal nanostructure, particularly to a flat mirror or a cavity confined between two mirrors, affects the vibronic structure of Raman scattering signals. We find that such proximity, particularly for the…

Optics · Physics 2026-05-28 Zeyu Zhou , Maxim Sukharev , Abraham Nitzan , Joseph Eli Subotnik

We experimentally demonstrate collective strong coupling, optical bi-stability (OB) and all-optical switching in a system consisting of ultracold 85Rb atoms, trapped in a dark magneto-optical trap (DMOT), coupled to an optical Fabry-Perot…

Atomic Physics · Physics 2017-03-23 Sourav Dutta , S. A. Rangwala

This review outlines several linear optical effects featured by molecular polaritons arising in the collective strong light-matter coupling regime. Under weak laser irradiation and when the single-molecule light-matter coupling can be…