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We report experimental measurements of the transmission spectrum of an optical cavity coupled with cold Rb atoms. We observe the multi-atom vacuum Rabi splitting of a composite cavity and atom system. When a coupling field is applied to the…

Optics · Physics 2009-11-13 Gessler Hernandez , Jiepeng Zhang , Yifu Zhu

Polaritons are compositional light-matter quasiparticles that arise as a result of strong coupling between a vacuum field of a resonant optical cavity and electronic excitations in quantum emitters. Reaching such a regime is often hard, as…

Recent experiments have revealed the profound effect of strong light-matter interactions in optical cavities on the electronic ground state of molecular systems. This phenomenon, known as vibrational strong coupling (VSC), can modify…

Quantum Physics · Physics 2023-12-19 Thomas Schnappinger , Markus Kowalewski

Coherent light-matter interaction at the single photon and electronic qubit level promises the remarkable potential for nonclassical information processing. Against the efforts of improving the figure of merit of the cavities, here we…

Quantum Physics · Physics 2015-06-19 Yong-Chun Liu , Xingsheng Luan , Hao-Kun Li , Qihuang Gong , Chee Wei Wong , Yun-Feng Xiao

We consider parametric interactions of laser pulses in a coherent macroscopic ensemble of resonant atoms, which are possible in the strong coupling regime of light-matter interaction. The spectrum condensation (lasing at collective vacuum…

Quantum Physics · Physics 2007-05-23 I. B. Mekhov , V. S. Egorov , V. N. Lebedev , P. V. Moroshkin , I. A. Chekhonin , S. N. Bagayev

Vibrational polaritons form in a planar Fabry-Perot microcavity when a vibrational mode of a layer of molecules is near resonant with an infrared cavity mode. Herein, dispersion relations of vibrational polaritons are studied when the…

Chemical Physics · Physics 2024-06-18 Tao E. Li

We experimentally resolve the dispersion of multiple vibro-polariton modes issued from the strong coupling of different vibrational bands of the methylene group (CH2) in a 2.56$\mu$m thick polyethylene film with the confined modes of a…

A theoretical variation between the two distinct light-matter coupling regimes, namely weak and strong coupling, becomes uniquely feasible in open optical Fabry-P\'erot microcavities with low mode volume, as discussed here. In combination…

Applied Physics · Physics 2019-12-02 Franziska Wall , Oliver Mey , Lorenz Maximilian Schneider , Arash Rahimi-Iman

It is usually considered that the spectrum of an optical cavity coupled to an atomic medium does not exhibit a normal-mode splitting unless the system satisfies the strong coupling condition, meaning the Rabi frequency of the coherent…

Quantum Physics · Physics 2017-01-06 Y. -H. Lien , G. Barontini , M. Scheucher , M. Mergenthaler , J. Goldwin , E. A. Hinds

Polaritonic chemistry offers the possibility of modifying molecular properties and even influencing chemical reactivity through strong coupling between vibrational transitions and confined light modes in optical cavities. Despite…

Chemical Physics · Physics 2025-05-16 Thomas Schnappinger , Markus Kowalewski

We explore the nonlinear response of tailor-cut light-matter hybrid states in a novel regime, where both the Rabi frequency induced by a coherent driving field and the vacuum Rabi frequency set by a cavity field are comparable to the…

Quantum Physics · Physics 2021-05-05 J. Mornhinweg , M. Halbhuber , C. Ciuti , D. Bougeard , R. Huber , C. Lange

Despite the potential paradigm breaking capability of microcavities to control chemical processes, the extent to which photonic devices change properties of molecular materials is still unclear, in part due to challenges in modeling hybrid…

Chemical Physics · Physics 2021-12-30 Raphael F. Ribeiro

We simulate vibrational strong (VSC) and ultrastrong coupling (V-USC) for liquid water with classical molecular dynamics simulations. When the cavity modes are resonantly coupled to the O-H stretch mode of liquid water, the infrared…

Chemical Physics · Physics 2020-07-21 Tao E. Li , Joseph E. Subotnik , Abraham Nitzan

Recent experimental advances in Positronium (Ps) physics have made it possible to produce dense Ps ensembles in which Ps-Ps interactions may occur, leading to the production of Ps$_2$ molecules and paving the way to the realization of a Ps…

Atomic Physics · Physics 2023-03-31 Erika Cortese , David B. Cassidy , Simone De Liberato

We demonstrate Resonant Tunneling Diodes, embedded in double metal cavities, strongly coupled to the cavity field, while maintaining their electronic properties. We measure the polariton dispersion and find a relative vacuum Rabi splitting…

The coherent strong coupling of molecules with confined light fields to create polaritons - part matter, part light - is opening exciting opportunities ranging from extended exciton transport and inter-molecular energy transfer to modified…

Experiments have demonstrated that the strong light-matter coupling in polaritonic microcavities significantly enhances transport. Motivated by these experiments, we have solved the disordered multimode Tavis-Cummings model in the…

Optics · Physics 2023-06-01 Georg Engelhardt , Jianshu Cao

The interaction between excited states of a molecule and excited states of metal nanostructure (e.g. plasmons) leads to hybrid states with modified optical properties. When plasmon resonance is swept through molecular transition frequency…

Chemical Physics · Physics 2022-05-04 Monosij Mondal , Maicol A. Ochoa , Maxim Sukharev , Abraham Nitzan

One of the most popular subjects now being researched in molecular science is strong light-matter coupling. The introduction of vibrational strong coupling and the formation vibro-polaritonic states tend to modify chemical reactivity,…

Chemical Physics · Physics 2023-08-10 Akhila Kadyan , Monu P. Suresh , Ben Johns , Jino George

Strong coupling between light and matter is possible with a variety of organic materials. In contrast to the simpler inorganic case, organic materials often have a complicated spectrum, with vibrationally dressed electronic transitions.…

Mesoscale and Nanoscale Physics · Physics 2018-02-02 M. Ahsan Zeb , Peter G. Kirton , Jonathan Keeling