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The electronic structure and the chemical state in Am binary oxides and Am-doped UO$_2$ were studied by means of x-ray absorption spectroscopy at shallow Am core ($4d$ and $5d$) edges. In particular, the Am $5f$ states were probed and the…

Chemical Physics · Physics 2023-03-17 S. M. Butorin , D. K. Shuh

Non-resonant inelastic x ray scattering (NIXS) experiments have been performed to probe the 5d-5f electronic transitions at the uranium O(4,5) absorption edges in uranium dioxide. For small values of the scattering vector q, the spectra are…

Strongly Correlated Electrons · Physics 2013-12-19 R. Caciuffo , G. van der Laan , L. Simonelli , T. Vitova , C. Mazzoli , M. A. Denecke , G. H. Lander

Resonant X-ray scattering (RXS) is a spectroscopy where both the power of site selective diffraction and the power of local absorption spectroscopy regarding atomic species are combined. By virtue of the dependence on the core level state…

Materials Science · Physics 2007-11-12 Yves Joly , Elena S. Nazarenko , José-Emilio Lorenzo , Sergio Di Matteo , Calogero R. Natoli

We study the electronic structure of Ta2NiSe5 in its low-temperature semiconducting phase, using resonant inelastic x-ray scattering (RIXS) at the Ta L3 edge. We also investigate the electronic properties of Ta2NiSe5 within the…

Strongly Correlated Electrons · Physics 2024-12-23 D. A. Kukusta , L. V. Bekenov , A. N. Yaresko , K. Ishii , T. Takayama , H. Takagi , V. N. Antonov

Valence band electronic structure of mixed uranium oxides (UO2, U4O9, U3O7, U3O8, UO3) has been studied by the resonant inelastic X-ray scattering (RIXS) technique at the U M5 edge and by computational methods. We show here that the RIXS…

Young's archetypal double-slit experiment forms the basis for modern diffraction techniques: the elastic scattering of waves yields an interference pattern that captures the real-space structure. Here, we report on an inelastic incarnation…

The crystal-field (CF) splitting of the $^6H_{5/2}$ Hund's rule ground state of Sm$^{3+}$ in the strongly correlated topological insulator SmB$_6$ has been determined with high resolution resonant inelastic x-ray scattering (RIXS) at the Sm…

Low-energy electron excitation spectra were measured on a single crystal of a typical iron-based superconductor PrFeAsO$_{0.7}$ using resonant inelastic X-ray scattering (RIXS) at the Fe-$L_3$ edge. Characteristic RIXS features are clearly…

Strongly Correlated Electrons · Physics 2016-07-18 T. Nomura , Y. Harada , H. Niwa , K. Ishii , M. Ishikado , S. Shamoto , I. Jarrige

We have investigated the electronic structure of Ba$_5$AlIr$_2$O$_{11}$ within the density functional theory using the generalized gradient approximation while considering strong Coulomb correlations in the framework of the fully…

Strongly Correlated Electrons · Physics 2025-04-21 D. A. Kukusta , L. V. Bekenov , V. N. Antonov

We present a study of resonant inelastic X-ray scattering (RIXS) spectra collected at the rare-earth $L$ edges of divalent hexaborides YbB$_6$ and EuB$_6$. In both systems, RIXS-active features are observed at two distinct resonances…

We theoretically analyze the intensity of the resonant inelastic X-ray scattering (RIXS) based on Ansatz that the electron is fractionalized into two components. By fitting the angle resolved photoemission spectroscopy (ARPES) data of a…

Strongly Correlated Electrons · Physics 2021-07-26 Masatoshi Imada

The electronic structure change of NiS$_{2-x}$Se$_x$ as a function of Se concentration $x$ has been studied by Ni $L$-edge X-ray absorption spectroscopy (XAS). The XAS spectra show distinct features in Ni $L_3$ edge, indicating whether the…

Strongly Correlated Electrons · Physics 2018-02-14 Jinwon Jeong , Kyung Ja Park , En-Jin Cho , Han-Jin Noh , Sung-Baek Kim , Hyeong-Do Kim

We investigate the electronic structure of americium (Am) across its four experimentally confirmed high-pressure phases Am-I (P63/mmc), Am-II (Fm-3m), Am-III (Fddd), and Am-IV (Pnma) up to 100 GPa, using density functional theory combined…

Strongly Correlated Electrons · Physics 2026-04-15 Haiyan Lu

Element- and site-specific resonant inelastic x-ray scattering spectroscopy (RIXS) is employed to investigate electron correlation effects in {$\rm NaV_2O_5$}. In contrast to single photon techniques, RIXS at the vanadium $L_3$ edge is able…

Strongly Correlated Electrons · Physics 2009-11-07 G. P. Zhang , T. A. Callcott , G. T. Woods , L. Lin , Brian Sales , D. Mandrus , J. He

Resonant inelastic x-ray scattering (RIXS) is a widely used spectroscopic technique, providing access to the electronic structure and dynamics of atoms, molecules, and solids. However, RIXS requires a narrow bandwidth x-ray probe to achieve…

The resonant inelastic x-ray scattering (RIXS) was measured in an insulating SrCuO$_{2}$ with changing the incident photon energy ($h\nu$) near the Cu $1s$ absorption edge (K-edge). Complex structures and their dependences on the momentum…

We report an Fe $K$-edge resonant inelastic X-ray scattering (RIXS) study of K$_{0.83}$Fe$_{1.53}$Se$_2$. This material is an insulator, unlike many parent compounds of iron-based superconductors. We found a sharp excitation around 1 eV,…

Understanding the electronic structure of actinide materials is crucial for both fundamental research and nuclear applications. The partially filled 5f shells exhibit complex behavior due to strong correlations and ligand hybridization,…

Resonant inelastic x-ray scattering (RIXS) provides remarkable opportunities to interrogate ultrafast dynamics in liquids. Here we use RIXS to study the fundamentally and practically important hydroxyl radical in liquid water, OH(aq).…

Resonant inelastic x-ray scattering (RIXS) spectra at the Fe K-edge were measured for a single crystal of the iron oxypnictide superconductor PrFeAsO0.7 (Tc=42 K). They disclose a weak, broad feature centered around 4.5 eV energy loss,…

Strongly Correlated Electrons · Physics 2015-05-14 I. Jarrige , K. Ishii , M. Yoshida , T. Fukuda , K. Ikeuchi , M. Ishikado , N. Hiraoka , K. D. Tsuei , H. Kito , A. Iyo , H. Eisaki , S. Shamoto
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