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We discuss the production of ultracold molecules in their electronic ground state by photoassociation employing electronically excited states with ion-pair character and strong spin-orbit interaction. A short photoassociation laser pulse…

We demonstrate experimentally how the process of Stimulated Raman Adiabatic Passage (STIRAP) can be utilized for efficient coherent internal state transfer in single trapped and laser-cooled $^{40}$Ca$^+$ ions. The transfer from the…

The strong dipole-dipole interaction of trapped Rydberg ions offers the possibility of sub-microsecond entanglement gates. For example a two-qubit Control-Phase gate in 88 Sr + ions can be realized, by simultaneous excitation to the Rydberg…

Quantum Physics · Physics 2026-04-16 K. N. Zlatanov , M. Mallweger , M. Hennrich , N. V. Vitanov

We combined high-resolution Fourier-transform spectroscopy and large-scale electronic structure calculation to study energy and radiative properties of the high-lying (3)1{\Pi} and (5)1{\Sigma}+ states of the RbCs molecule. The…

Atomic Physics · Physics 2019-05-22 K. Alps , A. Kruzins , O. Nikolayeva , M. Tamanis , R. Ferber , E. A. Pazyuk , A. V. Stolyarov

Efficient preparation and detection of the motional state of trapped ions is important in many experiments ranging from quantum computation to precision spectroscopy. We investigate the stimulated Raman adiabatic passage (STIRAP) technique…

Quantum Physics · Physics 2016-02-17 Florian Gebert , Yong Wan , Fabian Wolf , Jan C. Heip , Piet O. Schmidt

We propose a novel scheme to efficiently tune the scattering length of two colliding ground-state atoms by off-resonantly coupling the scattering-state to an excited Rydberg-molecular state using laser light. For the s-wave scattering of…

Quantum Gases · Physics 2017-10-04 Nóra Sándor , Rosario González-Férez , Paul S. Julienne , Guido Pupillo

Stimulated Raman adiabatic passage (STIRAP) describes adiabatic population transfer between two states coherently coupled via a mediating state that remains unoccupied. This renders STIRAP robust against loss in the mediating state, leading…

We report the successful production of an ultracold sample of absolute ground-state $^{23}$Na$^{87}$Rb molecules. Starting from weakly-bound Feshbach molecules formed via magneto-association, the lowest rovibrational and hyperfine level of…

Achieving a high population of antihydrogen/hydrogen atoms in the 2S level is essential for spectroscopy measurements testing similarities between matter and antimatter. We propose and examine the efficiency of applying the STIRAP…

Atomic Physics · Physics 2025-09-19 AbdAlGhaffar K. Amer , A. Capra , T. Friesen , M. C. Fujiwara , T. Momose , C. So , F. Robicheaux

We present 17 experimentally confirmed Feshbach resonances in optically trapped 85Rb. Seven of the resonances are in the ground-state channel (f,m_f) = (2,+2)+(2,+2), and nine are in the excited-state channel (2,-2)+(2,-2). We find a wide…

We consider two-color heteronuclear photoassociation of atoms into dipolar molecules in the J=1 electro-vibrational ground state, where a free-ground laser couples atoms directly to the ground state and a free-bound laser couples the atoms…

Quantum Gases · Physics 2009-11-19 Matt Mackie , Catherine DeBrosse

We study the rovibronic transitions in NaK$_2$ between its electronic ground state $1^2A'$ and its second excited state $3^2A'$, to identify possible pathways for the creation of ultracold ground-state triatomic molecules. Our methodology…

Quantum Gases · Physics 2026-01-16 Baraa Shammout , Leon Karpa , Silke Ospelkaus , Eberhard Tiemann , Olivier Dulieu

We report on the observation of blue-detuned photoassociation in Rb2, in which vibrational levels are energetically above the corresponding excited atomic asymptote. 85Rb atoms in a MOT were photoassociated at short internuclear distances…

Efficient initialization and manipulation of quantum states is important for numerous applications and it usually requires the ability to perform high fidelity and robust swapping of the populations of quantum states. Stimulated Raman…

Quantum Physics · Physics 2023-03-01 Genko T. Genov , Simon Rochester , Marcis Auzinsh , Fedor Jelezko , Dmitry Budker

STIRAP (Stimulated Raman Adiabatic Passage) is a powerful laser-based method, usually involving two photons, for efficient and selective transfer of population between quantum states. A particularly interesting feature is the fact that the…

We report on the production of ultracold heteronuclear YbLi* molecules in a dual-species magneto-optical trap by photoassociation (PA). The formation of the electronically excited molecules close to dissociation was observed by trap loss…

We report the observation of microwave coherent control of rotational states of ultracold $^{85}$Rb$^{133}$Cs molecules formed in their vibronic ground state by short-range photoassociation. Molecules are formed in the single rotational…

Atomic Physics · Physics 2020-07-10 Zhonghua Ji , Ting Gong , Yonglin He , Jeremy M. Hutson , Yanting Zhao , Liantuan Xiao , Suotang Jia

We observe a magnetic Feshbach resonance in a collision between the ground and metastable states of two-electron atoms of ytterbium (Yb). We measure the on-site interaction of doubly-occupied sites of an atomic Mott insulator state in a…

Quantum Gases · Physics 2013-05-01 Shinya Kato , Seiji Sugawa , Kosuke Shibata , Ryuta Yamamoto , Yoshiro Takahashi

We demonstrate the production of ultracold polar RbCs molecules in their vibronic ground state, via photoassociation of laser-cooled atoms followed by a laser-stimulated state transfer process. The resulting sample of $X ^1\Sigma^+ (v=0)$…

Atomic Physics · Physics 2009-11-11 J. M. Sage , S. Sainis , T. Bergeman , D. DeMille

Starting from an ultracold sample of ground-state $^{23}$Na$^{87}$Rb molecules, we investigate the lowest ro-vibrational level of the $b^3\Pi$ state with high resolution laser spectroscopy. This electronic spin-forbidden $X^1\Sigma^+…

Atomic Physics · Physics 2021-11-17 Junyu He , Junyu Lin , Romain Vexiau , Nadia Bouloufa , Olivier Dulieu , Dajun Wang
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