Optical formation of ultracold NaK$_2$ ground state molecules
Abstract
We study the rovibronic transitions in NaK between its electronic ground state and its second excited state , to identify possible pathways for the creation of ultracold ground-state triatomic molecules. Our methodology relies on the computation of potential energy surfaces and transition dipole moment surfaces for the relevant electronic states using ab initio methods. Rovibrational energy levels and wave functions are determined using the discrete variable representation approach. A double-well structure of the potential energy surface is identified for both states, and the related transition strengths between the rovibrational levels are derived. Our calculations show that the formation of ultracold ground-state NaK molecules is expected when starting from an excited electronic state of NaK, which can be created by photoassociation of NaK and K observed by optical means by Cao et al. (Phys. Rev. Lett. 2024, 132, 093403).
Keywords
Cite
@article{arxiv.2508.18010,
title = {Optical formation of ultracold NaK$_2$ ground state molecules},
author = {Baraa Shammout and Leon Karpa and Silke Ospelkaus and Eberhard Tiemann and Olivier Dulieu},
journal= {arXiv preprint arXiv:2508.18010},
year = {2026}
}