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Photoassociation of two ultracold rubidium atoms and the subsequent formation of stable molecules in the singlet ground and lowest triplet states is investigated theoretically. The method employs laser pulses inducing transitions via…

Atomic Physics · Physics 2007-05-23 Christiane P. Koch , Ronnie Kosloff , Françoise Masnou-Seeuws

Collective two-color photoassociation of a freely-interacting 87Rb Bose-Einstein condensate is theoretically examined, focusing on stimulated Raman adiabatic passage (STIRAP) from an atomic to a stable molecular condensate. In particular,…

Atomic Physics · Physics 2016-09-08 Matt Mackie , Anssi Collin , Juha Javanainen

We recently reported the formation of ultracold LiCs molecules in the rovibrational ground state X1Sigma+,v''=0,J''=0 [J. Deiglmayr et al., PRL 101, 133004 (2008)]. Here we discuss details of the experimental setup and present a thorough…

Atomic Physics · Physics 2015-05-13 J. Deiglmayr , M. Repp , A. Grochola , K. Mörtlbauer , C. Glück , O. Dulieu , J. Lange , R. Wester , M. Weidemüller

We analyze coherent two-color photoassociation of a Bose-Einstein condensate, focusing on stimulated Raman adiabatic passage (STIRAP) in free-bound-bound transitions from atoms to molecules. This problem is of particular interest since…

Atomic Physics · Physics 2009-10-31 Matt Mackie , Ryan Kowalski , Juha Javanainen

We reveal the existence of high-density Feshbach resonances in the collision between the ground and metastable states of $^{171}$Yb and coherently produce the associated Feshbach molecules by photoassociation. The extremely small transition…

Atomic Physics · Physics 2016-02-01 Shintaro Taie , Shunsuke Watanabe , Tomohiro Ichinose , Yoshiro Takahashi

We have observed 28 heteronuclear Feshbach resonances in 10 spin combinations of the hyperfine ground states of a 40K 87Rb mixture. The measurements were performed by observing the loss rates from an atomic mixture at magnetic fields…

Other Condensed Matter · Physics 2007-08-23 C. Klempt , T. Henninger , O. Topic , J. Will , W. Ertmer , E. Tiemann , J. Arlt

We consider a method of sub-wavelength superlocalization and patterning of atomic matter waves via a two dimensional stimulated Raman adiabatic passage (2D STIRAP) process. An atom initially prepared in its ground level interacts with a…

We report the production of ultracold 7Li85Rb molecules by photoassociation (PA) below the Li (2s 2S1/2) + Rb (5p 2P1/2) asymptote. We perform PA spectroscopy in a dual-species 7Li-85Rb magneto-optical trap (MOT) and detect the PA…

Atomic Physics · Physics 2014-05-06 Sourav Dutta , D. S. Elliott , Yong P. Chen

STImulated Raman Adiabatic Passage (STIRAP) is a powerful technique for robust state transfer capabilities in quantum systems. This method, however encounters challenges for its implementation as a gate in qubit-subspace due to its…

Quantum Physics · Physics 2025-01-28 Ujjawal Singhal , Harsh Vardhan Upadhyay , Irshad Ahmad , Vibhor Singh

The process of stimulated Raman adiabatic passage (STIRAP) provides a possible route for the generation of a coherent molecular Bose-Einstein condensate (BEC) from an atomic BEC. We analyze this process in a three-dimensional mean-field…

Statistical Mechanics · Physics 2009-11-07 P. D. Drummond , K. V. Kheruntsyan , D. J. Heinzen , R. H. Wynar

We report coherent association of atoms into a single weakly bound NaCs molecule in an optical tweezer through an optical Raman transition. The Raman technique uses a deeply bound electronic excited intermediate state to achieve a large…

Starting from weakly bound Feshbach molecules, we demonstrate a two-photon pathway to the dipolar ground state of bi-alkali molecules that involves only singlet-to-singlet optical transitions. This pathway eliminates the search for a…

Chainwise stimulated Raman adiabatic passage (C-STIRAP) in M-type molecular system is a good alternative in creating ultracold deeply-bound molecules when the typical STIRAP in {\Lambda}-type system does not work due to weak Frank-Condon…

Quantum Physics · Physics 2024-08-06 Jiahui Zhang , Li Deng , Yueping Niu , Shangqing Gong

We have produced ultracold, polar RbCs* molecules via photoassociation in a laser-cooled mixture of Rb and Cs atoms. Using a model of the RbCs* molecular interaction which reproduces the observed rovibrational structure, we infer decay…

Atomic Physics · Physics 2009-11-10 Andrew J. Kerman , Jeremy M. Sage , Sunil Sainis , David DeMille , Thomas Bergeman

We spectroscopically investigate the hyperfine, rotational and Zeeman structure of the vibrational levels $\text{v}'=0$, $7$, $13$ within the electronically excited $c^3\Sigma_g^+$ state of $^{87}\text{Rb}_2$ for magnetic fields of up to…

Rydberg molecules, often exemplified by long-range "trilobite" molecules, are a subject of much recent interest at high principal quantum number $n$. States that use the same bonding mechanism can exist at much lower $n$ and less-extreme…

Atomic Physics · Physics 2017-05-01 R. A. Carollo , J. L. Carini , E. E. Eyler , P. L. Gould , W. C. Stwalley

We investigate the possibility of forming deeply bound ultracold RbCs molecules by a two-color photoassociation experiment. We compare the results with those for Rb_2 in order to understand the characteristic differences between…

Atomic Physics · Physics 2010-06-16 Subhas Ghosal , Richard J. Doyle , Christiane P. Koch , Jeremy M. Hutson

We investigated transition strengths from ultracold weakly bound 41K87Rb molecules produced via the photoassociation of laser-cooled atoms. An accurate potential energy curve of the excited state (3)1Sigma+ was constructed by carrying out…

Atomic Physics · Physics 2015-05-20 K. Aikawa , D. Akamatsu , M. Hayashi , J. Kobayashi , M. Ueda , S. Inouye

Many experimental platforms for quantum science depend on state control via laser fields. Frequently, however, the control fidelity is limited by optical phase noise. This is exacerbated in stabilized laser systems where high-frequency…

Stimulated Raman Adiabatic Passage (STIRAP) and its variants, such as multi-state chainwise-STIRAP allow efficiently transferring the populations in multi-state system and have been widely used to prepare ultracold deeply-bound molecules.…

Quantum Physics · Physics 2024-07-30 Jiahui Zhang