Related papers: Did bio-homochirality arise from spin-polarized el…
Chiral symmetry breaking occurs when a physical or chemical process, with no preference for the production of one or other enantiomer, spontaneously generates a large excess of one of the two enantiomers: (L), left-handed or (D), right…
The selection of a single molecular handedness, or homochirality across all living matter, is a mystery in the origin of life. Frank's seminal model showed in the fifties how chiral symmetry breaking can occur in non-equilibrium chemical…
Chiral-induced spin selectivity (CISS) is a striking phenomenon in which spin-unpolarized electrons become spin-polarized after traversing a chiral medium. Theoretical studies have shown that spin-orbit coupling, geometric chirality, and…
The discovery of the chiral induced spin selectivity effect has provided a novel tool to study how active physical and chemical mechanism may differ in chiral enantiomers, however, the origin of the effect itself is yet an open question. In…
Chirality describes the asymmetry between an object and its mirror image and manifests itself in diverse functionalities across all scales of matter - from molecules and aggregates to thin films and bulk chiral materials. A particularly…
Here we propose a mechanism by which spin polarization can be generated dynamically in chiral molecular systems undergoing photo-induced electron transfer. The proposed mechanism explains how spin polarization emerges in systems where…
Here we review a universal model for chirally induced spin-selectivity (CISS) as a standalone effect occurring in chiral molecules. We tie together the results of forward scattering in the gas phase to the results for photoelectrons in…
The helical distribution of the electronic density in chiral molecules, such as DNA and bacteriorhodopsin, has been suggested to induce a spin-orbit coupling interaction that may lead to the so-called chirality-induced spin selectivity…
Living organisms have some common structures, chemical reactions and molecular structures. The organisms consist of cells with cell division, they have homochirality of protein and carbohydrate units, and metabolism, and genetics, and they…
Chiral-induced spin selectivity (CISS) is a phenomenon in which electron spins are polarized as they are transported through chiral molecules, and the spin polarization depends on the handedness of the chiral molecule. In this study, we…
Conceptualizing planetary habitability depends on understanding how living organisms originated and what features of environments are essential to foster abiogenesis. Estimates of the abundance of life's building blocks are confounded by…
The path toward the emergence of life in our biosphere involved several key events allowing for the persistence, reproduction and evolution of molecular systems. All these processes took place in a given environmental context and required…
Chiral molecules can selectively transport electrons of a particular spin orientation, yet the underlying mechanism remain poorly understood. Here, we present theoretical evidence that electrons propagating through chiral materials with…
We show that a spinor traveling along a one-dimensional helical path develops a spin-orbit coupling as a result of the curvature of the path. We estimate the magnitude of the associated spin polarization and obtain values typical of many…
It has been proposed that spin-polarized cosmic radiation can induce asymmetric changes in helical biopolymers that may account for the emergence of biological homochirality. The parity violation in the weak interaction has direct…
The chirality-induced spin selectivity (CISS) effect has garnered significant interest in the field of molecular spintronics due to its potential for creating spin-polarized electrons without the need for a magnet. Recent studies devoted to…
In chemistry and biochemistry, chirality represents the structural asymmetry characterized by non-superimposable mirror images for a material like DNA. In physics, however, chirality commonly refers to the spin-momentum locking of a…
The functionality of many biological systems depends on reliable electron transfer with minimal heating. Unlike man-made electric circuits, nature realizes electron transport via insulating chiral molecules. Here we include spin into the…
The chiral-induced spin selectivity (CISS) effect, whereby chiral molecules preferentially transmit electrons of one spin orientation, remains one of the most intriguing and debated phenomena at the interface of spintronics, molecular…
Spin-resolved photoelectron spectroscopy (PES) is a major experimental probe of chirality-induced spin selectivity (CISS), yet it remains unclear whether the measured spin polarization reflects molecular chirality itself or the broader…