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A novel optical method for distinguishing chiral molecules is proposed and validated within a quantum simulator employing a trapped-ion qudit. This approach correlates the sign disparity of the dipole moment of chiral molecules with…

Quantum Physics · Physics 2024-03-11 Teng Liu , Fa Zhao , Pengfei Lu , Qifeng Lao , Min Ding , Ji Bian , Feng Zhu , Le Luo

We present the first analytic-derivative-based formulation of vibrational circular dichroism (VCD) atomic axial tensors for second-order Moller-Plesset (MP2) perturbation theory. We compare our implementation to our recently reported…

Chemical Physics · Physics 2025-01-14 Brendan M. Shumberger , Kirk C. Pearce , T. Daniel Crawford

Chiroptical techniques for detecting and characterizing the chirality of matter and artificial nanostructures are traditionally based on their interaction with chiral light, typically circularly-polarized fields propagating in free space.…

We perform a theoretical and numerical study of the optical properties of both direct and inverse three-dimensional (3D) chiral woodpile structures, and a corresponding chiral Bragg stack. We compute transmission spectra in the helical…

Using a model methane-like chiral system, we theoretically demonstrate a possibility to access photoelectron circular dichroism (PECD) by a single experiment with two overlapping laser pulses of carrier frequencies $\omega$ and $2\omega$,…

Atomic and Molecular Clusters · Physics 2018-12-20 Philipp V. Demekhin , Anton N. Artemyev , Alexander Kastner , Thomas Baumert

The identification of a universal biosignature that could be sensed remotely is critical to the prospects for success in the search for life elsewhere in the universe. A candidate universal biosignature is homochirality, which is likely to…

Molecular chirality detection and enantiomer discrimination are very important issues for many areas of science and technology, prompting intensive investigations via optical methods. However, these methods are hindered by the intrinsically…

Distinguishing between the left- and right-handed versions of a chiral molecule (enantiomers) is vital, but also inherently difficult. Traditional optical methods using elliptically or circularly polarized light rely on weak linear effects…

Optics · Physics 2022-06-08 Laura Rego , David Ayuso

LCD codes are linear codes with important cryptographic applications. Recently, a method has been presented to transform any linear code into an LCD code with the same parameters when it is supported on a finite field with cardinality…

Information Theory · Computer Science 2019-11-25 Carlos Galindo , Olav Geil , Fernando Hernando , Diego Ruano

Particular advantages of chiral molecules for direct detection of the time-dependence of pseudoscalar and the timelike-component of pseudovector cosmic fields are highlighted. Such fields are invoked in different models for cold dark matter…

High Energy Physics - Phenomenology · Physics 2020-09-23 Konstantin Gaul , Mikhail G. Kozlov , Timur A. Isaev , Robert Berger

We present an implementation of the B term of Magnetic Circular Dichroism within the Algebraic Diagrammatic Construction (ADC) scheme of the polarization propagator and its Intermediate State Representation. As illustrative results, the MCD…

Dichroic tomography is a 3D imaging technique in which the polarization of the incident beam is used to induce contrast due to the magnetization or orientation of a sample. The aim is to reconstruct not only the optical density but the…

Instrumentation and Detectors · Physics 2022-05-11 Matthew A. Marcus

Circular dichroism is widely used for characterizing organic and biological materials, but measurements at a single molecule level are challenging because differences in absorption for opposite helicities are small. Here we show that…

Mesoscale and Nanoscale Physics · Physics 2014-01-23 A. Yokoyama , M. Yoshida , A. Ishii , Y. K. Kato

We introduce a matrix method and we derive a formula for phase retardation effects in plasmonic systems. We analyze the circular dichroic response (CD) of two orthogonal Au nanorods in detail and we show that, although, theoretically,…

Optics · Physics 2020-11-30 M. A. Kuntman , E. Kuntman

Chirality is probably the most mysterious among all symmetry transformations. Very readily broken in biological systems, it is practically absent in naturally occurring inorganic materials and is very challenging to create artificially.…

We have extended the origin-invariant length gauge (LG(OI)) approach -- originally developed by Caricato and co-workers for optical rotation (OR) and electronic circular dichroism (ECD) -- to vibrational circular dichroism (VCD). This…

Chemical Physics · Physics 2026-01-06 Brendan M. Shumberger , James R. Cheeseman , Marco Caricato , T. Daniel Crawford

We describe the development of a broadband magneto-optical spectrometer with femtosecond temporal resolution. The absorption spectrometer is based on a white-light supercontinuum (ca. 320 - 750 nm) using shot-to-shot temporal and spectral…

Optics · Physics 2021-11-24 Jake Sutcliffe , J. Olof Johansson

Neural decoders were introduced as a generalization of the classic Belief Propagation (BP) decoding algorithms, where the Trellis graph in the BP algorithm is viewed as a neural network, and the weights in the Trellis graph are optimized by…

Information Theory · Computer Science 2021-05-13 Xiangyu Chen , Min Ye

The linear band crossings of 3D Dirac and Weyl semimetals are characterized by a charge chirality, the parallel or anti-parallel locking of electron spin to its momentum. Such materials are believed to exhibit a ${\bf E} \cdot {\bf B}$…

Materials Science · Physics 2021-06-01 Bing Cheng , Timo Schumann , Susanne Stemmer , N. P. Armitage

We propose a highly efficient atomically-resolved mode of electron magnetic chiral dichroism. This method exploits the recently introduced orbital angular momentum spectrometer to analyze the inelastically scattered electrons allowing for…

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