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Methane is typically thought to be formed in the solid state on the surface of cold interstellar icy grain mantles via the successive atomic hydrogenation of a carbon atom. In the current work we investigate the potential role of molecular…

Astrophysics of Galaxies · Physics 2022-04-06 Thanja Lamberts , Gleb Fedoseev , Marc van Hemert , Danna Qasim , Ko-Ju Chuang , Julia C. Santos , Harold Linnartz

Hydrogenation reactions of CO in inter- and circumstellar ices are regarded as an important starting point in the formation of more complex species. Previous laboratory measurements by two groups on the hydrogenation of CO ices resulted in…

Solar and Stellar Astrophysics · Physics 2009-06-15 G. W. Fuchs , H. M. Cuppen , S. Ioppolo , C. Romanzin , S. E. Bisschop , S. Andersson , E. F. van Dishoeck , H. Linnartz

Methanol (CH$_{3}$OH) is a key complex organic molecule (COM) in the interstellar medium, widely used as a tracer of dense gas and hot molecular cores (HMCs). Using high-resolution ALMA observations from the ATOMS survey, we investigate the…

We present the observational result of a glycine precursor, methylamine (CH$_3$NH$_2$), together with methanol (CH$_3$OH) and methanimine (CH$_2$NH) towards high-mass star-forming regions, NGC6334I, G10.47+0.03, G31.41+0.3, and W51~e1/e2…

Solar and Stellar Astrophysics · Physics 2019-09-04 Taiki Suzuki , Liton Majumdar , Kazuki Tokuda , Harumi Minamoto , Masatoshi Ohishi , Masao Saito , Tomoya Hirota , Hideko Nomura , Yoko Oya

Ethanol (CH$_3$CH$_2$OH) is a relatively common molecule, often found in star forming regions. Recent studies suggest that it could be a parent molecule of several so-called interstellar complex organic molecules (iCOMs). Yet, the formation…

Mono-deuterated methanol is thought to form during the prestellar core stage of star formation. Observed variations in the CH2DOH/CH3OD ratio suggest that its formation is strongly dependent on the surrounding cloud conditions. Thus, it is…

Astrophysics of Galaxies · Physics 2022-04-05 Beatrice M. Kulterer , Maria N. Drozdovskaya , Stefano Antonellini , Catherine Walsh , Tom J. Millar

Methanol is the most complex molecule securely identified in interstellar ices and is a key chemical species for understanding chemical complexity in astrophysical environments. Important aspects of the methanol ice photochemistry are still…

Astrophysics of Galaxies · Physics 2023-05-10 W. R. M. Rocha , P. Woitke , S. Pilling , W. -F. Thi , J. K. Jørgensen , L. E. Kristensen , G. Perotti , I. Kamp

Methanol (CH$_3$OH) is at the root of organic ice chemistry in protoplanetary disks. However, its weak emission has made detections difficult. To date, gas-phase CH$_3$OH has been detected in only one Class II disk, TW Hya. We use the…

Solar and Stellar Astrophysics · Physics 2019-03-20 M. T. Carney , M. R. Hogerheijde , V. V. Guzmán , C. Walsh , K. I. Öberg , E. C. Fayolle , L. I. Cleeves , J. M. Carpenter , C. Qi

1-propanol (CH3CH2CH2OH) is a three carbon-bearing representative of primary linear alcohols that may have its origin in the cold dark cores in interstellar space. To test this, we investigated in the laboratory whether 1-propanol ice can…

Solar and Stellar Astrophysics · Physics 2019-06-26 D. Qasim , G. Fedoseev , K. -J. Chuang , V. Taquet , T. Lamberts , J. He , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

The relative abundances of singly-deuterated methanol isotopologues, [CH$_{2}$DOH]/[CH$_{3}$OD], in star-forming regions deviate from the statistically expected ratio of 3. In Orion KL, the nearest high-mass star-forming region to Earth,…

Astrophysics of Galaxies · Physics 2022-10-12 Olivia H. Wilkins , Geoffrey A. Blake

The outer Galaxy is an environment with metallicity lower than the Solar one and, because of this, the formation and survival of molecules in star-forming regions located in the inner and outer Galaxy is expected to be different. To gain…

The presence of methyl alcohol or methanol (CH$_3$OH) in several astrophysical environments has been characterized by its high abundance that depends on both the production rate and the destruction rate. In the present work, the…

Astrophysics · Physics 2008-11-26 S. Pilling , R. Neves , A. C. F. Santos , H. M. Boechat-Roberty

This study focuses on the formation of two molecules of astrobiological importance - glycolaldehyde (HC(O)CH2OH) and ethylene glycol (H2C(OH)CH2OH) - by surface hydrogenation of CO molecules. Our experiments aim at simulating the CO…

Astrophysics of Galaxies · Physics 2017-05-26 Gleb Fedoseev , Herma M. Cuppen , Sergio Ioppolo , Thanja Lamberts , Harold Linnartz

Quantifying the composition of the material in protoplanetary disks is paramount to determining the potential for exoplanetary systems to produce and support habitable environments. A key complex organic molecule (COM) to detect is methanol…

The inheritance of material across the star and planet formation process is traced by deuterium fractionation. We report here the first detection of doubly deuterated methanol towards pre-stellar cores. We study the deuterium fractionation…

Astrophysics of Galaxies · Physics 2023-01-11 Yuxin Lin , Silvia Spezzano , Paola Caselli

Astrophysical observations show complex organic molecules (COMs) in the gas phase of protoplanetary disks. X-rays emitted from the central young stellar object (YSO) that irradiate interstellar ices in the disk, followed by the ejection of…

Earth and Planetary Astrophysics · Physics 2021-02-22 R. Basalgète , R. Dupuy , G. Féraud , C. Romanzin , L. Philippe , X. Michaut , J. Michoud , L. Amiaud , A. Lafosse , J. -H. Fillion , M. Bertin

Complex organic molecules (COMs) have been identified in different environments in star- forming regions. Laboratory studies show that COMs form in the solid state, on icy grains, typically following a non-energetic (atom-addition) or…

Astrophysics of Galaxies · Physics 2017-05-23 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Water in outflows from protostars originates either as a result of gas-phase synthesis from atomic oxygen at T > 200 K, or from sputtered ice mantles containing water ice. We aim to quantify the contribution of the two mechanisms that lead…

Astrophysics of Galaxies · Physics 2015-06-18 Aleksi N. Suutarinen , Lars E. Kristensen , Joseph C. Mottram , Helen J. Fraser , Ewine F. van Dishoeck

We report the first detection of triply-deuterated methanol, with 12 observed transitions, towards the low-mass protostar IRAS 16293-2422, as well as multifrequency observations of 13CH3OH, used to derive the column density of the main…

Astrophysics · Physics 2007-05-23 B. Parise , A. Castets , E. Herbst , E. Caux , C. Ceccarelli , I. Mukhopadhyay , A. G. G. M. Tielens

Methanol and formaldehyde are two simple organic molecules that are ubiquitously detected in the interstellar medium. An origin in the solid phase and a subsequent nonthermal desorption into the gas phase is often invoked to explain their…

Astrophysics of Galaxies · Physics 2016-04-20 R. Martín-Doménech , G. M. Muñoz Caro , G. A. Cruz-Díaz