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A previous analysis of methanol and formaldehyde towards the Orion Bar concluded that the two molecular species may trace different physical components, methanol the clumpy material, and formaldehyde the interclump medium. To verify this…

Astrophysics of Galaxies · Physics 2015-05-14 S. Leurini , B. Parise , P. Schilke , J. Pety , R. Rolffs

We present the results of an interferometric study of 38 millimeter-wave lines of CH3OH in the region around the water maser source W3(H2O) and a region extending about 30" to the south and west of the hydroxyl maser source W3(OH). The…

Context: Methanol is thought to be mainly formed during the prestellar phase and its deuterated form keeps memory of the conditions at that epoch. Thanks to the unique combination of high angular resolution and sensitivity provided by ALMA,…

We used several data sets from the Plateau de Bure Interferometer to map the dimethyl ether emission in Orion-KL with different arcsec spatial resolutions and different energy levels to compare with our previous methyl formate maps. Our…

Astrophysics of Galaxies · Physics 2015-06-12 N. Brouillet , D. Despois , A. Baudry , T. -C. Peng , C. Favre , A. Wootten , A. J. Remijan , T. L. Wilson , F. Combes , G. Wlodarczak

Our automated reaction discovery program, AutoMeKin, has been utilized to investigate the formation of glycolonitrile (HOCH$_{2}$CN) in the gas phase under the low temperatures of the interstellar medium (ISM). The feasibility of a proposed…

We aim to detect methylamine, CH$_{3}$NH$_{2}$, in a variety of hot cores and use it as a test for the importance of photon-induced chemistry in ice mantles and mobility of radicals. Specifically, CH$_3$NH$_2$ cannot be formed from atom…

Solar and Stellar Astrophysics · Physics 2015-06-23 N. F. W. Ligterink , E. D. Tenenbaum , E. F. van Dishoeck

The study of deuteration in pre-stellar cores is important to understand the physical and chemical initial conditions in the process of star formation. In particular, observations toward pre-stellar cores of methanol and deuterated…

We aim to determine the production rates of several parent and product volatiles and the 12C/13C isotopic carbon ratio in the long-period comet C/2004 Q2 (Machholz), which is likely to originate from the Oort Cloud. The line emission from…

Earth and Planetary Astrophysics · Physics 2012-09-04 M. de Val-Borro , P. Hartogh , C. Jarchow , M. Rengel , G. L. Villanueva , M. Küppers , N. Biver , D. Bockelée-Morvan , J. Crovisier

The recent unexpected detection of terrestrial complex organic molecules in the cold (~ 10 K) gas has cast doubts on the commonly accepted formation mechanisms of these species. Standard gas-phase mechanisms are inefficient and tend to…

Astrophysics of Galaxies · Physics 2016-03-02 Aurore Bacmann , Alexandre Faure

Gas-phase methanol was recently detected in a protoplanetary disk for the first time with ALMA. The peak abundance and distribution of methanol observed in TW Hya differed from that predicted by chemical models. Here, the chemistry of…

Earth and Planetary Astrophysics · Physics 2018-09-12 Catherine Walsh , Shreyas Vissapragada , Harry McGee

We report the first detection of doubly-deuterated methanol (CHD2OH), as well as firm detections of the two singly-deuterated isotopomers of methanol (CH2DOH and CH3OD), towards the solar-type protostar IRAS16293-2422. From the present…

We present the results of James Webb Space Telescope observations of the protostar ST6 in the Large Magellanic Cloud (LMC) with the Medium Resolution Spectrograph of the Mid-Infrared Instrument (4.9-27.9 $\mu$m). Characterized by one-third…

Several complex organic molecules are routinely detected in high abundances towards hot cores and hot corinos. For many of them, their paths of formation in space are uncertain, as gas phase reactions alone seem to be insufficient. In this…

Astrophysics of Galaxies · Physics 2015-05-30 Angela Occhiogrosso , Serena Viti , Paola Modica , Maria Elisabetta Palumbo

During the formation of stars, the accretion of the surrounding material toward the central object is thought to undergo strong luminosity outbursts, followed by long periods of relative quiescence, even at the early stages of star…

Astrophysics of Galaxies · Physics 2016-04-20 Vianney Taquet , Eva Wirström , Steven B. Charnley

The high abundances of Complex Organic Molecules (COMs) with respect to methanol, the most abundant COM, detected towards low-mass protostars, tend to be underpredicted by astrochemical models. This discrepancy might come from the large…

Solar and Stellar Astrophysics · Physics 2015-05-20 Vianney Taquet , Ana López-Sepulcre , Cecilia Ceccarelli , Roberto Neri , Claudine Kahane , Steven B. Charnley

Simple and complex organic molecules (COMs) are observed along different phases of star and planet formation and have been successfully identified in prestellar environments such as dark and translucent clouds. Yet the picture of organic…

In circumstellar gas, the complex organic molecule methanol has been found almost exclusively around young stellar objects, and is thus regarded as a signpost of recent star formation. Here we report the first probable detection of methanol…

We investigate the deuteration of methanol towards the high-mass star forming region NGC 7538-IRS1. We have carried out a multi-transition study of CH$_3$OH, $^{13}$CH$_3$OH and of the deuterated fllavors, CH$_2$DOH and CH$_3$OD, between…

Deuterated methanol is one of the most robust windows astrochemists have on the individual chemical reactions forming deuterium-bearing molecules and the physicochemical history of the regions where they reside. The first-time detection of…

In cold molecular clouds, UV photolysis of icy grain mantles generates radicals that lead to new molecule formation. When radical diffusion is limited by low temperatures, oxygen atom addition and insertion reactions, enabled by photolysis…

Astrophysics of Galaxies · Physics 2025-07-29 Michelle R. Brann , Karin I. Öberg , Mahesh Rajappan