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We describe the relationship between the GW approximation and various equation-of-motion (EOM) coupled-cluster (CC) theories. We demonstrate the exact equivalence of the G$_0$W$_0$ approximation and the propagator theory for an…

Chemical Physics · Physics 2023-04-12 Johannes Tölle , Garnet Kin-Lic Chan

We report the implementation of 4-component spinor relativistic equation-of-motion coupledcluster method within the single- and double- excitation approximation to calculate ionization potential (EOM-CCSD) of molecules. We have applied this…

Chemical Physics · Physics 2015-02-25 Himadri Pathak , Sudip Sasmal , Malaya K. Nayak , Nayana Vaval , Sourav Pal

Cavity quantum electrodynamics (cavity QED) describes the coherent interaction between matter and an electromagnetic field confined within a resonator structure, and is providing a useful platform for developing concepts in quantum…

Quantum-electrodynamical density-functional theory (QEDFT) provides a first-principles framework for describing materials coupled to quantized electromagnetic fields. While QEDFT has successfully captured cavity-induced modifications of…

Materials Science · Physics 2026-03-26 Benshu Fan , I-Te Lu , Michael Ruggenthaler , Angel Rubio

In this article, we review the principles of macroscopic quantum electrodynamics and discuss a variety of applications of this theory to medium-assisted atom-field coupling and dispersion forces. The theory generalises the standard mode…

Quantum Physics · Physics 2009-03-02 Stefan Scheel , Stefan Yoshi Buhmann

In this paper, we report on the implementation of the EOM spin-flip (SF), ionization-potential (IP) and electron-affinity (EA) coupled cluster singles doubles (CCSD) methods for atoms and molecules in strong magnetic fields for energies as…

Chemical Physics · Physics 2025-10-08 Marios-Petros Kitsaras , Florian Hampe , Lena Reimund , Stella Stopkowicz

Collective strong coupling of molecular ensembles to optical cavities opens a route to modifying matter through genuinely collective electronic correlations. Yet even in the absence of a cavity, Coulomb correlations are notoriously…

Quantum Physics · Physics 2026-05-05 Dominik Sidler , Michael Ruggenthaler , Angel Rubio

The emergent field of cavity quantum materials bridges collective many-body phenomena in solid-state platforms with strong light-matter coupling in cavity quantum electrodynamics (cavity QED). This brief review provides an overview of the…

Quantum Physics · Physics 2022-03-04 Frank Schlawin , Dante M. Kennes , Michael A. Sentef

The Quantum-Electrodynamical Time-Dependent Density Functional Theory (QED-TDDFT) equations are solved by time propagating the wave function on a tensor product of a Fock-space and real-space grid. Applications for molecules in cavities…

Quantum Physics · Physics 2022-11-30 Justin Malave , Alexander Ahrens , Daniel Pitagora , Cody Covington , Kálmán Varga

Coupled-cluster (CC) theory and Green's function many-body perturbation theory (MBPT) have long evolved as distinct yet complementary frameworks for describing electronic correlation. While CC methods employ exponential wavefunction…

A reduced-density-matrix (RDM)-based approach to {\em ab initio} cavity quantum electrodynamics (QED) is developed. The expectation value of the Pauli-Fierz Hamiltonian is expressed in terms of one- and two-body electronic and photonic…

Chemical Physics · Physics 2022-11-23 Joel D. Mallory , A. Eugene DePrince

Cavity quantum electrodynamics (QED) studies the interaction between a quantum emitter and a single radiation-field mode. When an atom is in strong coupling with a cavity mode1,2, it is possible to realize key quantum information processing…

Quantum Physics · Physics 2009-11-13 K. Hennessy , A. Badolato , M. Winger , D. Gerace , M. Atature , S. Gulde , S. Falt , E. L. Hu , A. Imamoglu

We have studied theoretically the Kondo effect in the quantum dot(QD) within the whole range of temperature by using the equation-of-motion(EOM) technique based on the non-equilibrium Green function formalism. We have taken the finiteness…

Strongly Correlated Electrons · Physics 2012-09-12 Kuk-Chol Ri , Chol-Won Ri , Gum-Hyok Jong

Understanding physical properties of quantum emitters strongly interacting with quantized electromagnetic modes is one of the primary goals in the emergent field of waveguide quantum electrodynamics (QED). When the light-matter coupling…

Quantum Physics · Physics 2023-05-30 Yuto Ashida , Takeru Yokota , Atac Imamoglu , Eugene Demler

We present our computational implementation of the equation-of-motion (EOM) coupled-cluster (CC) singles, doubles, and triples (SDT) method for computing doubly ionized (DIP) and two-electron attached (DEA) states within Q-CHEM. These…

Chemical Physics · Physics 2025-01-14 Manisha , Prashant Uday Manohar , Anna I Krylov

Electronic resonances are metastable states with finite lifetimes, encountered in processes such as photodetachment, electron transmission, and Auger decay. Resonances appear in Hermitian quantum mechanics as increased density of states in…

Chemical Physics · Physics 2025-11-10 Cansu Utku , Garrette Pauley Paran , Thomas-C. Jagau

Cavity quantum electrodynamics (cavity QED) enables the control of light-matter interactions at the single-photon level, rendering it a key component of many quantum technologies. Its practical realization, however, is complex since it…

Quantum Physics · Physics 2024-09-25 David Castells-Graells , J. Ignacio Cirac , Dominik S. Wild

The double electron attachment (DEA) and double ionization potential (DIP) equation-of-motion coupled-cluster (EOMCC) methods including up to 4-particle-2-hole (4$p$-2$h$) and 4-hole-2-particle (4$h$-2$p$) excitations on top of…

Chemical Physics · Physics 2026-05-21 Jun Shen , Karthik Gururangan , Piotr Piecuch

Quantum embedding theories are promising approaches to investigate strongly-correlated electronic states of active regions of large-scale molecular or condensed systems. Notable examples are spin defects in semiconductors and insulators. We…

Materials Science · Physics 2021-12-14 He Ma , Nan Sheng , Marco Govoni , Giulia Galli

We present a diagrammatic notation to derive the quantum-electrodynamic coupled cluster (QED-CC) equations needed for the description for polaritonic ground and excited states. Our presented notation is a generalization of the existing…

Chemical Physics · Physics 2024-07-02 Laurenz Monzel , Stella Stopkowicz