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The electron affinity (EA) of superheavy element Og is calculated by the use of the relativistic Fock-space coupled cluster (FSCC) and configuration interaction methods. The FSCC cluster operator expansion included single, double, and…

Atoms coupled to cavities provide an exciting playground for the study of fundamental interactions of atoms mediated through a common channel. Many of the applications of cavity-QED and cold-atom experiments more broadly, suffer from…

We formulate and analyze in detail the ground state quantum electrodynamical density functional theory (QEDFT) for a generalized Dicke model describing a collection of $N$ tight-binding dimers minimally coupled to a cavity photon mode. This…

Mesoscale and Nanoscale Physics · Physics 2023-10-03 A. Kudlis , D. Novokreschenov , I. Iorsh , I. V. Tokatly

We investigate theoretically the model of a cavity-quantum-electrodynamics (QED) system that consists of two two-level atoms coupled to a single-mode cavity in the weak coupling regime, where the system is driven by quantum light. The…

Quantum Physics · Physics 2018-11-21 Qian Bin , Xin-You Lü , Shang-Wu Bin , Ying Wu

We present a detailed derivation and discussion of cavity Born-Oppenheimer coupled cluster (CBO-CC) theory and address cavity-modified electron correlation in the vibrational strong coupling regime. Methodologically, we combine the recently…

Chemical Physics · Physics 2025-12-02 Eric W. Fischer

In the field of polaritonic chemistry, strong light-matter interactions are used to alter a chemical reaction inside an optical cavity. To explain and understand these processes, the development of reliable theoretical models is essential.…

Chemical Physics · Physics 2021-06-21 Fabijan Pavošević , Johannes Flick

By analyzing the many-body problem for non-relativistic electrons strongly coupled to photon modes of a microcavity I derive the exact momentum/force balance equation for cavity quantum electrodynamics. Implications of this equation for the…

Mesoscale and Nanoscale Physics · Physics 2018-12-14 I. V. Tokatly

The physical reasons in favour of a two dimensional topological model of quantum electrodynamics are discussed. It is shown that in accord with this model there is a new uncertainty relation for photon which is compatible with QED.

Mesoscale and Nanoscale Physics · Physics 2007-05-23 F. Ghaboussi

In cavity quantum electrodynamics (QED), light-matter interaction is probed at its most fundamental level, where individual atoms are coupled to single photons stored in three-dimensional cavities. This unique possibility to experimentally…

Mesoscale and Nanoscale Physics · Physics 2010-10-05 T. Niemczyk , F. Deppe , H. Huebl , E. P. Menzel , F. Hocke , M. J. Schwarz , J. J. Garcia-Ripoll , D. Zueco , T. Hümmer , E. Solano , A. Marx , R. Gross

Adiabatic mixed quantum/classical molecular dynamics simulations were used to generate snapshots of the hydrated electron (e-) in liquid water at 300 K. Water cluster anions that include two complete solvation shells centered on the e- were…

Data Analysis, Statistics and Probability · Physics 2016-09-28 Ilya A. Shkrob , William J. Glover , Ross E. Larsen , Benjamin J. Schwartz

In this article, we present a unified reciprocal quantum electrodynamics (QED) formulation of quantum light-matter interaction. For electron-light interactions, we bridge the underlying theories of Photon-Induced Near-field Electron…

Quantum Physics · Physics 2019-04-12 Yiming Pan , Avraham Gover

We demonstrate the effects of cavity quantum electrodynamics for a quantum dot coupled to a photonic molecule, consisting of a pair of coupled photonic crystal cavities. We show anti-crossing between the quantum dot and the two super-modes…

Mesoscale and Nanoscale Physics · Physics 2012-07-30 Arka Majumdar , Armand Rundquist , Michal Bajcsy , Jelena Vučković

We present a medium-dependent quantum optics approach to describe the influence of electron-acoustic phonon coupling on the emission spectra of a strongly coupled quantum-dot cavity system. Using a canonical Hamiltonian for light…

Mesoscale and Nanoscale Physics · Physics 2011-05-03 S. Hughes , P. Yao , F. Milde , A. Knorr , D. Dalacu , K. Mnaymneh , V. Sazonova , P. J. Poole , G. C. Aers , J. Lapointe , R. Cheriton , R. L. Williams

We introduce an electron-photon exchange-correlation functional for quantum electrodynamical density-functional theory (QEDFT). The approach, photon MBD (pMBD), is inspired by the many-body dispersion (MBD) method for weak intermolecular…

Chemical Physics · Physics 2025-12-23 Cankut Tasci , Leonardo A. Cunha , Johannes Flick

Simulations of laser-induced electron dynamics in a molecular system are performed using time-dependent (TD) equation-of-motion (EOM) coupled-cluster (CC) theory. The target system has been chosen to highlight potential shortcomings of…

Chemical Physics · Physics 2023-08-09 Stephen H. Yuwono , Brandon C. Cooper , Tianyuan Zhang , Xiaosong Li , A. Eugene DePrince

Stability and instability of quantum evolution are studied in the interaction between a two-level atom with photon recoil and a quantized field mode in an ideal cavity, the basic model of cavity quantum electrodynamics (QED). It is shown…

Quantum Physics · Physics 2009-11-11 S. V. Prants , M. Yu. Uleysky , V. Yu. Argonov

The emerging field of strongly coupled light-matter systems has drawn significant attention in recent years due to the prospect of altering physical and chemical properties of molecules and materials. Because this emerging field draws on…

Quantum Physics · Physics 2024-01-10 Mark Kamper Svendsen , Kristian Sommer Thygesen , Angel Rubio , Johannes Flick

We describe here the coherent formulation of electromagnetism in the non-relativistic quantum-mechanical many-body theory of interacting charged particles. We use the mathematical frame of the field theory and its quantization in the spirit…

Quantum Physics · Physics 2022-08-01 Ladislaus Alexander Bányai , Mircea Bundaru

Perturbative approaches are methods to efficiently tackle many-body problems, offering both intuitive insights and analysis of correlation effects. However, their application to systems where light and matter are strongly coupled is…

Chemical Physics · Physics 2025-03-07 Yassir El Moutaoukal , Rosario R. Riso , Matteo Castagnola , Enrico Ronca , Henrik Koch

The study of light-matter interaction has seen a resurgence in recent years, stimulated by highly controllable, precise, and modular experiments in cavity quantum electrodynamics (QED). The achievement of strong coupling, where the coupling…