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The rapidly developing and converging fields of polaritonic chemistry and quantum optics necessitate a unified approach to predict strongly-correlated light-matter interactions with atomic-scale resolution. Combining concepts from both…

Quantum Physics · Physics 2018-09-19 Johannes Flick , Prineha Narang

Cavity quantum electrodynamics (QED) studies the interaction between light and matter at the single quantum level and has played a central role in quantum science and technology. Combining the idea of cavity QED with moir\'e materials, we…

Strongly Correlated Electrons · Physics 2024-06-14 Kanta Masuki , Yuto Ashida

Quantum Chromodynamics (QCD) is the fundamental theory of strong interactions. It describes the behavior of quarks and gluons which are the smallest known constituents of nuclear matter. The difficulties in solving the theory at low…

High Energy Physics - Phenomenology · Physics 2009-12-22 Theodor Brasoveanu , Dmitri Kharzeev , Mauricio Martinez

Coupled quantum electrodynamics (QED) cavities have been recently proposed as new systems to simulate a variety of equilibrium and non-equilibrium many-body phenomena. We present a brief review of their main properties together with a…

Strongly Correlated Electrons · Physics 2010-05-04 Andrea Tomadin , Rosario Fazio

The open-shell reference relativistic equation-of-motion coupled-cluster method within its four-component description is successfully implemented with the consideration of single- and double- excitation approximation. The one-body and…

Atomic Physics · Physics 2016-09-21 Himadri Pathak , Sudip Sasmal , Malaya K. Nayak , Nayana Vaval , Sourav Pal

A major trend within the field of cavity QED is to boost the interaction strength between the cavity field and the atomic internal degrees of freedom of the trapped atom by decreasing the mode volume of the cavity. In such systems, it is…

Quantum Physics · Physics 2018-08-29 Lukas Neumeier , Darrick E. Chang

The relativistic theory for the electric dipole moment (EDM) of paramagnetic atoms arising from the electric dipole moment of the electron is presented. A novel approach using the relativistic coupled-cluster method that incorporates the…

Chemical Physics · Physics 2009-05-01 Debashis Mukherjee , B. K. Sahoo , H. S. Nataraj , B. P. Das

Strong coupling between molecular excitations and quantized electromagnetic fields in optical cavities provides a powerful means to control the physical and chemical properties of molecular systems. Here, we study electron transfer (ET)…

Chemical Physics · Physics 2026-03-02 Takumi Hidaka , Tomohiro Fukushima , Nguyen Thanh Phuc

We present the theoretical derivation and numerical implementation of the linear response equations for relativistic quantum electrodynamical density functional theory (QEDFT). In contrast to previous works based on the Pauli-Fierz…

Chemical Physics · Physics 2024-07-09 Lukas Konecny , Valeriia P. Kosheleva , Heiko Appel , Michael Ruggenthaler , Angel Rubio

Quantum light-matter systems at strong coupling are notoriously challenging to analyze due to the need to include states with many excitations in every coupled mode. We propose a nonperturbative approach to analyze light-matter correlations…

Mesoscale and Nanoscale Physics · Physics 2021-04-15 Yuto Ashida , Atac Imamoglu , Eugene Demler

We describe a qualitatively new regime of cavity quantum electrodynamics, the super strong coupling regime. This regime is characterized by atom-field coupling strengths of the order of the free spectral range of the cavity, resulting in a…

Quantum Physics · Physics 2009-11-13 D. Meiser , P. Meystre

A comprehensive theoretical understanding of electron-photon correlation is essential for describing the reshaping of molecular orbitals in quantum electrodynamics (QED) environments. The strong coupling QED Hartree-Fock (SC-QED-HF) theory…

Chemical Physics · Physics 2024-09-04 Yassir El Moutaoukal , Rosario R. Riso , Matteo Castagnola , Henrik Koch

A relativistic density-functional theory based on a Fock-space effective quantum-electrodynamics (QED) Hamiltonian using the Coulomb or Coulomb-Breit two-particle interaction is developed. This effective QED theory properly includes the…

Chemical Physics · Physics 2021-05-03 Julien Toulouse

Waveguide QED with cold atoms provides a potent platform for the study of non-equilibrium, many-body, and open-system quantum dynamics. Even with weak coupling and strong photon loss, the collective enhancement of light-atom interactions…

In cavity quantum electrodynamics (QED), photons leaving the cavity can be irreversibly lost or reused as a power source. This dichotomy is reflected in two different thermodynamic bookkeepings of the light field, both corresponding to…

Quantum Physics · Physics 2026-02-09 Marcelo Janovitch , Sander Stammbach , Matteo Brunelli , Patrick P. Potts

Since its inception, research of cavity quantum electrodynamics (CQED) has extended our understanding of light-matter interactions and our ability to utilize them. Thus far, all the work in this field has been focused on light interacting…

Strong coupling between an atom and an electromagnetic resonator is an important condition in cavity quantum electrodynamics (QED). While strong coupling in various physical systems has been achieved so far, it remained elusive for single…

Quantum Physics · Physics 2020-01-22 Hiroki Takahashi , Ezra Kassa , Costas Christoforou , Matthias Keller

Chemical and photochemical reactivity, as well as supramolecular organization and several other molecular properties, can be modified by strong interactions between light and matter. Theoretical studies of these phenomena require the…

Chemical Physics · Physics 2023-11-03 Sara Angelico , Tor S. Haugland , Enrico Ronca , Henrik Koch

The ultimate goal of electronic structure calculations is to make the left and right hand sides of the titled ``equation'' as close as possible. This requires high-precision treatment of relativistic, correlation, and quantum…

Chemical Physics · Physics 2022-10-10 Wenjian Liu

A subsystem approach for obtaining electron binding energies in the valence region and apply it to the case of halide ions (X$^-$, X = F-At) in water. This approach is based on electronic structure calculations combining the relativistic…

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