English

Diagrams and symmetry in polaritonic coupled cluster theory

Chemical Physics 2024-07-02 v1

Abstract

We present a diagrammatic notation to derive the quantum-electrodynamic coupled cluster (QED-CC) equations needed for the description for polaritonic ground and excited states. Our presented notation is a generalization of the existing diagrammatic notation of standard electronic coupled-cluster theory. Further, we discuss point-group symmetry inside a cavity and its exploitation within a QED-CC code for efficiency and the targeted treatment of excited states.

Keywords

Cite

@article{arxiv.2407.00757,
  title  = {Diagrams and symmetry in polaritonic coupled cluster theory},
  author = {Laurenz Monzel and Stella Stopkowicz},
  journal= {arXiv preprint arXiv:2407.00757},
  year   = {2024}
}