Related papers: Structures and Properties of Known and Postulated …
With the chemical reaction rate database UMIST95 (Millar et al. 1997) we analyze how uncertainties in rate constants of gas-phase chemical reactions influence the modelling of molecular abundances in the interstellar medium. Random…
We present a method for generating cold neutral atoms via charge exchange reactions between trapped ions and Rydberg positronium. The high charge exchange reaction cross section leads to efficient neutralisation of the ions and since the…
Even though water is the main constituent in interstellar icy mantles, its chemical origin is not well understood. Three different formation routes have been proposed following hydrogenation of O, O2, or O3, but experimental evidence is…
Electron-induced chemistry in imidazole (IMI) clusters embedded in helium nanodroplets (with an average size of 2$\times$10$^5$ He atoms) has been investigated with high-resoluton time-of-flight mass spectrometry. The formation of both,…
The time-dependent rate coefficients for the charge exchange reaction C+ + Si -> C + Si+ for doublet and quartet states have been determined with ab initio quantum calculations coupled with a non-adiabatic transition model based on a simple…
Cold dense cores are unique among the structures found in the interstellar medium (ISM), as they harbor a rich chemical inventory, including complex organic molecules (COMs), which will be inherited by future evolutionary stages. These…
This review paper summarizes the state-of-the-art in laboratory based interstellar ice chemistry. The focus is on atom addition reactions, illustrating how water, carbon dioxide and methanol can form in the solid state at astronomically…
An overview is given of the chemical processes that occur in primordial systems under the influence of radiation, metal abundances and dust surface reactions. It is found that radiative feedback effects differ for UV and X-ray photons at…
We report on the first detection of C3N- and C5N- towards the cold dark core TMC-1 in the Taurus region, using the Yebes 40 m telescope. The observed C3N/C3N- and C5N/C5N- abundance ratios are 140 and 2, respectively; that is similar to…
Hybrid atom-ion systems are a rich and powerful platform for studying chemical reactions, as they feature both excellent control over the electronic state preparation and readout as well as a versatile tunability over the scattering energy,…
Open star clusters are the essential building blocks of the Galactic disk; "strong chemical tagging" - the premise that all star clusters can be reconstructed given chemistry information alone - is a driving force behind many current and…
We use the recent detection of He II absorption at $z=2.2-2.6$ in the line of sight of the quasar HS1700+64 to put bounds on the sources of ionization. We find that given the uncertainty in $\tauhgp$ and the model of absorption in the…
This paper presents the first substantial study of the chemistry of the envelopes around a sample of 18 low-mass pre- and protostellar objects for which physical properties have previously been derived from radiative transfer modeling of…
Motivated to explore the dynamical mechanism of multi-fragmentation phase transition and expand our knowledge on the deterministic chaos in nonlinear dynamic process, we study systematically the nonlinear dynamical behaviors of heavy ion…
Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have…
The recent past witnesses the growing interdependence between the physics of hadrons, the physics of relativistic heavy-ion collisions, and the physics of compact objects in astrophysics. A notable example is the kaon which plays special…
C$^+$ is a critical constituent of many regions of the interstellar medium, as it can be a major reservoir of carbon and, under a wide range of conditions, the dominant gas coolant. Emission from its 158$\mu$m fine structure line is used to…
The collisions between high-energy ions and solids can result in significant physical and chemical changes to the material. These effects are potentially important for better understanding the chemistry of interstellar and planetary bodies,…
This article is devoted to investigation of cation self-diffusion mechanisms, taking place in UO2, UO2+x, and UO2-x crystals simulated under periodic (PBC) and isolated (IBC) boundary conditions using the method of molecular dynamics in the…
Complex plasma mixtures with three or more components are often encountered in astrophysics or in inertial confinement fusion (ICF) experiments. For mixtures containing species with large differences in atomic number Z, the modeling needs…