Electron-induced chemistry in imidazole clusters embedded in helium nanodroplets

Electron-induced chemistry in imidazole (IMI) clusters embedded in helium nanodroplets (with an average size of 2$\times$10$^5$ He atoms) has been investigated with high-resoluton time-of-flight mass spectrometry. The formation of both, negative and positive, ions was monitored as a function of the cluster size n. In both ion spectra a clear series of peaks with IMI cluster sizes up to at least 25 are observed. While the anions are formed by collisions of IMI$_n$ with He$^\star$$^{-}$, the cations are formed through ionization of IMI$_n$ by He$^{+}$ as the measured onset for the cation formation is observed at 24.6 eV (ionization energy of He). The most abundant series of anions are dehydrogenated anions IMI$_{n-1}$(IMI-H)$^{-}$, while other anion series are IMI clusters involving CN and C$_2$H$_4$ moieties. The formation of cations is dominated by the protonated cluster ions IMI$_n$H$^{+}$, while the intensity of parent cluster cations IMI$_n$$^{+}$ is also observed preferentially for the small cluster size n. The observation of series of cluster cations [IMI$_n$CH$_3$]$^{+}$ suggests either CH$_3$$^{+}$ cation to be solvated by n neutral IMI molecules, or the electron-induced chemistry has led to the formation of protonated methyl-imidazole solvated by (n-1) neutral IMI molecules.