Related papers: Structures and Properties of Known and Postulated …
The recent observations show that comet C/2016 R2 (Pan-Starrs) has a unique and peculiar composition when compared with several other comets observed at 2.8 au heliocentric distance. Assuming solar resonance fluorescence is the only…
This paper deals with the possible formation of two molecular anions often considered likely components in the physical environments of the Interstellar Medium ( ISM) : $\mathrm{C_2H^-}$ and $\mathrm{NCO^-}$. They are both discussed here by…
Electrostatic interactions involving proteins depend not just on the ionic charges involved but also on their chemical identities. Here we examine the origins of incompletely understood differences in the strength of association of…
The recent past witnesses the growing interdependence between the physics of hadrons, the physics of relativistic heavy-ion collisions, and the physics of compact objects in astrophysics. A notable example is the kaon which plays special…
The increasing detection of new molecules in the interstellar medium (ISM) shows that stereoisomerism is a fundamental contributor to interstellar molecular complexity. This work presents the first comprehensive overview of interstellar…
We derive structural and binding energy trends for twenty amino acids, their dipeptides, and their interactions with the divalent cations Ca$^{2+}$, Ba$^{2+}$, Sr$^{2+}$, Cd$^{2+}$, Pb$^{2+}$, and Hg$^{2+}$. The underlying data set consists…
Interstellar formamide (NH2CHO) has recently attracted significant attention due to its potential role as a molecular building block in the formation of precursor biomolecules relevant for the origin of life. Its formation, whether on the…
Gas-phase chemistry at extreme conditions (low densities and temperatures) is difficult, so the presence of interstellar grains is especially important for the synthesis of molecules that cannot form in the gas phase. Interstellar grains…
We report ALMA observations of the neutral atomic carbon transitions [CI] and multiple CO lines in a sample of $\sim30$ main sequence galaxies at $z\sim1$, including novel information on [CI](2-1) and CO(7-6) for 7 of such normal objects.…
Many molecular species can presumably still be observed in space if they are adequately characterized chemically. In this paper, we suggest that this could be the case of the neutral (C$_4$N$^0$) and anion (C$_4$N$^-$) cyanopropynylidene…
We present an extensive range of quantum calculations for the state-changing rotational dynamics involving two simple molecular anions which are expected to play some role in evolutionary analysis of chemical networks in the Interstellar…
Since molecules are ubiquitous in space, the study of the 'Molecular Universe' could unfold the mystery of the existing Interstellar medium. Star formation is linked to the chemical evolution processes. Thus, an analysis of the formation of…
Context: Diffusion of species on the dust surface is a key process for determining the chemical composition of interstellar ices. On the dust surface, adsorbed species diffuse from one potential well to another and react with other adsorbed…
We present model calculations of ionization fractions for elements in the warm (log T = 4), low-density photoionized interstellar medium (WIM) of the Milky Way. We model the WIM as a combination of overlapping low-excitation H II regions…
Interstellar complex organic molecules (COMs) are commonly observed during star formation, and are proposed to form through radical chemistry in icy grain mantles. Reactions between ions and neutral molecules in ices may provide an…
Computational chemistry plays a relevant role in many astrochemical research fields, either by complementing experimental measurements or by deriving parameters difficult to be reproduced by laboratories. While the role of computational…
Magnetic fields play such roles in star formation as the angular momentum transport in star-forming clouds, thereby controlling circumstellar disc formation and even binary star formation efficiency. The coupling between the magnetic field…
We theoretically analyze the efficiency of a protocol for creating mesoscopic superpositions of ion chains, described in [Phys. Rev. A 84, 063821 (2011)], as a function of the temperature of the crystal. The protocol makes use of…
We analyze the collisional excitation of the 158 micron (1900.5 GHz) fine structure transition of ionized carbon (C+) in terms of line intensities produced by simple cloud models. The single C+ fine structure transition is a very important…
It has been known for half a century that the interstellar medium (ISM) of our Galaxy is structured on scales as small as a few hundred km, more than 10 orders of magnitude smaller than typical ISM structures and energy input scales. In…