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Four-center two-electron Coulomb integrals routinely appear in electronic structure algorithms. The resolution-of-the-identity (RI) is a popular technique to reduce the computational cost for the numerical evaluation of these integrals in…

Chemical Physics · Physics 2024-01-17 Francisco A. Delesma , Moritz Leucke , Dorothea Golze , Patrick Rinke

Similar to other electron correlation methods, many-body perturbation theory methods based on Green functions, such as the so-called $GW$ approximation, suffer from the usual slow convergence of energetic properties with respect to the size…

$GW$ is an accurate method for computing electron addition and removal energies of molecules and solids. In a conventional $GW$ implementation, however, its computational cost is $O(N^4)$ in the system size $N$, which prohibits its…

Chemical Physics · Physics 2021-03-22 Jan Wilhelm , Patrick Seewald , Dorothea Golze

We present an implementation of the GW approximation for the electronic self-energy within the full-potential linearized augmented-plane-wave (FLAPW) method. The algorithm uses an all-electron mixed product basis for the representation of…

Materials Science · Physics 2010-11-15 Christoph Friedrich , Stefan Blügel , Arno Schindlmayr

GW approximation is one of the most popular parameter-free many-body methods that goes beyond the limitations of the standard density functional theory (DFT) to determine the excitation spectra for moderately correlated materials and in…

Materials Science · Physics 2023-12-12 Kristjan Haule , Subhasish Mandal

A novel Gaussian-Sinc mixed basis set for the calculation of the one-electron electronic structure within a uniform magnetic field in three dimensions is presented. The one-electron system is used to demonstrate the utility of this new…

Computational Physics · Physics 2014-11-12 Jonathan L. Jerke , Young Lee , C. J. Tymczak

We have developed a new type of self-consistent scheme within the $GW$ approximation, which we call quasiparticle self-consistent $GW$ (QS$GW$). We have shown that QS$GW$ rather well describes energy bands for a wide-range of materials,…

Materials Science · Physics 2007-10-05 Takao Kotani , Mark van Schilfgaarde , Sergey V. Faleev

We develop a formalism to calculate the quasi-particle energy within the GW many-body perturbation correction to the density functional theory (DFT). The occupied and virtual orbitals of the Kohn-Sham (KS) Hamiltonian are replaced by…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Daniel Neuhauser , Yi Gao , Christopher Arntsen , Cyrus Karshenas , Eran Rabani , Roi Baer

We have implemented the so called GW approximation (GWA) based on an all-electron full-potential Projector Augmented Wave (PAW) method. For the screening of the Coulomb interaction W we tested three different plasmon-pole dielectric…

Materials Science · Physics 2007-05-23 B. Arnaud , M. Alouani

Excited-state calculations, notably for quasiparticle band structures, are nowadays routinely performed within the GW approximation for the electronic self-energy. Nevertheless, certain numerical approximations and simplifications are still…

We demonstrate that basis sets suitable for electronic structure calculations can be obtained from simple accuracy considerations for the hydrogenic one-electron ions $Y^{(Y-1)+}$ for $Y\in[1,Z]$, necessitating no self-consistent field…

Computational Physics · Physics 2020-04-06 Susi Lehtola

Ab initio GW calculations are a standard method for computing the spectroscopic properties of many materials. The most computationally expensive part in conventional implementations of the method is the generation and summation over the…

Materials Science · Physics 2015-06-11 Jack Deslippe , Georgy Samsonidze , Manish Jain , Marvin L. Cohen , Steven G. Louie

A high-precision numerical calculation is reported for the self-energy correction to the hyperfine splitting and to the bound-electron g factor in hydrogenlike ions with low nuclear charge numbers. The binding nuclear Coulomb field is…

Atomic Physics · Physics 2009-11-13 V. A. Yerokhin , U. D. Jentschura

We present an all-electron, periodic {\GnWn} implementation within the numerical atomic orbital (NAO) basis framework. A localized variant of the resolution-of-the-identity (RI) approximation is employed to significantly reduce the…

Materials Science · Physics 2021-02-03 Xinguo Ren , Florian Merz , Hong Jiang , Yi Yao , Markus Rampp , Hermann Lederer , Volker Blum , Matthias Scheffler

A new implementation of the GW approximation (GWA) based on the all-electron Projector-Augmented-Wave method (PAW) is presented, where the screened Coulomb interaction is computed within the Random Phase Approximation (RPA) instead of the…

Materials Science · Physics 2009-11-10 S. Lebègue , B. Arnaud , M. Alouani , P. E. Bloechl

We present low-scaling algorithms for $GW$ and constrained random phase approximation based on a symmetry-adapted interpolative separable density fitting (ISDF) procedure that incorporates the space-group symmetries of crystalline systems.…

Materials Science · Physics 2024-01-24 Chia-Nan Yeh , Miguel A. Morales

We propose a novel approach to quasiparticle GW calculations which does not require the computation of unoccupied electronic states. In our approach the screened Coulomb interaction is evaluated by solving self-consistent linear-response…

Materials Science · Physics 2015-05-14 Feliciano Giustino , Marvin L. Cohen , Steven G. Louie

We present a quasiparticle self-consistent $GW$ (QSGW) implementation for periodic systems based on crystalline Gaussian basis sets. Our QSGW approach is based on a full-frequency analytic continuation GW scheme with Brillouin zone sampling…

Chemical Physics · Physics 2022-12-21 Jincheng Lei , Tianyu Zhu

Using a novel self-consistent implementation of Hedin's GW perturbation theory we calculate space and energy dependent self-energy for a number of materials. We find it to be local in real space and rapidly convergent on second-- to third--…

Strongly Correlated Electrons · Physics 2012-04-11 N. E. Zein , S. Y. Savrasov , G. Kotliar

In the present work, strong approximation errors are analyzed for both the spatial semi-discretization and the spatio-temporal fully discretization of stochastic wave equations (SWEs) with cubic polynomial nonlinearities and additive…

Numerical Analysis · Mathematics 2024-11-08 Ruisheng Qi , Xiaojie Wang