English

Low-Scaling algorithms for $GW$ and constrained random phase approximation using symmetry-adapted interpolative separable density fitting

Materials Science 2024-01-24 v1 Chemical Physics Computational Physics

Abstract

We present low-scaling algorithms for GWGW and constrained random phase approximation based on a symmetry-adapted interpolative separable density fitting (ISDF) procedure that incorporates the space-group symmetries of crystalline systems. The resulting formulations scale cubically with respect to system sizes and linearly with the number of k\mathbf{k}-points, regardless of the choice of single-particle basis and whether a quasiparticle approximation is employed. We validate these methods through comparisons with published literature and demonstrate their efficiency in treating large-scale systems through the construction of downfolded many-body Hamiltonians for carbon dimer defects embedded in hexagonal boron nitride supercells. Our work highlights the efficiency and general applicability of ISDF in the context of large-scale many-body calculations with k\mathbf{k}-point sampling beyond density functional theory.

Keywords

Cite

@article{arxiv.2401.12308,
  title  = {Low-Scaling algorithms for $GW$ and constrained random phase approximation using symmetry-adapted interpolative separable density fitting},
  author = {Chia-Nan Yeh and Miguel A. Morales},
  journal= {arXiv preprint arXiv:2401.12308},
  year   = {2024}
}

Comments

16 pages, 5 figures, 4 tables

R2 v1 2026-06-28T14:24:02.570Z