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The self-screening error in electronic structure theory is the part of the self-interaction error that would remain within the $GW$ approximation if the exact dynamically screened Coulomb interaction, $W$, were used, causing each electron…

Materials Science · Physics 2021-01-15 Jack Wetherell , Matthew Hodgson , Rex Godby

We present a subspace projection technique to conduct large-scale Kohn-Sham density functional theory calculations using spectral finite-element discretization. The proposed method treats both metallic and insulating materials in a single…

Computational Physics · Physics 2015-10-26 Phani Motamarri , Vikram Gavini

Quasiparticle (QP) excitations are extremely important for understanding and predicting charge transfer and transport in molecules, nanostructures and extended systems. Since density functional theory (DFT) within the Kohn-Sham (KS)…

Chemical Physics · Physics 2017-07-18 Vojtech Vlcek , Eran Rabani , Daniel Neuhauser , Roi Baer

Full-potential electronic structure calculations for periodic systems retain the Coulomb singularity at the nuclei, which induces cusp behavior of the orbitals near the nuclei while leaving the interstitial region smooth. This multiscale…

Numerical Analysis · Mathematics 2026-05-26 Baowei Lai , Xucheng Meng , Xiaoxu Li

Exploratory variational pseudopotential density functional calculations are performed for the electronic properties of many-electron systems in the 3D cartesian coordinate grid (CCG). The atom-centered localized gaussian basis set,…

Chemical Physics · Physics 2015-05-18 Amlan K Roy

The GW approximation for the electronic self-energy is an important tool for the quantitative prediction of excited states in solids, but its mathematical exploration is hampered by the fact that it must, in general, be evaluated…

Materials Science · Physics 2013-02-27 Arno Schindlmayr

We present an efficient \textit{ab initio} method for calculating the electronic structure and total energy of strongly correlated electron systems. The method extends the traditional Gutzwiller approximation for one-particle operators to…

Strongly Correlated Electrons · Physics 2014-07-01 Y. X. Yao , J. Liu , C. Liu , W. C. Lu , C. Z. Wang , K. M. Ho

Chu et al. recently reported extensive results of local density approximation (LDA) and of four (4) different Green function and dressed Coulomb (GW) approximation calculations of electronic properties of several semiconductors and…

Materials Science · Physics 2016-10-18 Diola Bagayoko , Yacouba Issa Diakite , Lashounda Franklin

The GW approximation is widely used for reliable and accurate modeling of single-particle excitations. It also serves as a starting point for many theoretical methods, such as its use in the Bethe-Salpeter equation (BSE) and dynamical…

Computational Physics · Physics 2024-03-25 Weiwei Gao , Zhao Tang , Jijun Zhao , James R. Chelikowsky

We present an all-electron, four-component relativistic implementation of electric field gradients (EFGs) at the nuclei using Gaussian-type orbitals and periodic boundary conditions. This allows us to include relativistic effects…

Other Condensed Matter · Physics 2024-05-17 Marc Joosten , Michal Repisky , Marius Kadek , Pekka Pyykkö , Kenneth Ruud

We implement the GW space-time method at finite temperatures, in which the Green's function G and the screened Coulomb interaction W are represented in the real space on a suitable mesh and in imaginary time in terms of Chebyshev…

Materials Science · Physics 2025-11-11 Sam Azadi , Arkadiy Davydov , Evgeny Kozik

Numerical calculations of the electron self-energy without any expansion in the binding nuclear field are required in order to match the rapidly advancing precision of experimental spectroscopy. For the lightest elements, particularly…

Atomic Physics · Physics 2025-02-20 V. A. Yerokhin , Z. Harman , C. H. Keitel

The $GW$ approximation is a widely used method for computing electron addition and removal energies of molecules and solids. The computational effort of conventional $GW$ algorithms increases as $O(N^4)$ with the system size $N$, hindering…

Chemical Physics · Physics 2024-09-12 Mia Schambeck , Dorothea Golze , Jan Wilhelm

Parameter estimation (PE) for compact binary coalescence (CBC) events observed by gravitational wave (GW) laser interferometers is a core task in GW astrophysics. We present a method to compute the posterior distribution efficiently without…

General Relativity and Quantum Cosmology · Physics 2025-09-09 Jonathan Mushkin , Javier Roulet , Barak Zackay , Tejaswi Venumadhav , Oryna Ivashtenko , Digvijay Wadekar , Ajit Kumar Mehta , Matias Zaldarriaga

We introduce a mixed density fitting scheme that uses both a Gaussian and a plane-wave fitting basis to accurately evaluate electron repulsion integrals in crystalline systems. We use this scheme to enable efficient all-electron Gaussian…

Chemical Physics · Physics 2017-11-22 Qiming Sun , Timothy C. Berkelbach , James D. McClain , Garnet Kin-Lic Chan

We present for static density functional theory and time-dependent density functional theory calculations an all-electron method which employs high-order hierarchical finite element bases. Our mesh generation scheme, in which structured…

Materials Science · Physics 2009-08-06 Lauri Lehtovaara , Ville Havu , Martti Puska

In this work we include electron-electron interaction beyond Hartree-Fock level in our non-equilibrium Green's function approach by a crude form of GW through the Single Plasmon Pole Approximation. This is achieved by treating all…

Mesoscale and Nanoscale Physics · Physics 2016-05-02 David O. Winge , Martin Franckié , Claudio Verdozzi , Andreas Wacker , Mauro F. Pereira

We present a code implementing the linearized self-consistent quasiparticle GW method (scQPGW) in the LAPW basis. Our approach is based on the linearization of the self-energy around zero frequency which differs it from the existing…

Materials Science · Physics 2017-09-13 Andrey L. Kutepov , Viktor S. Oudovenko , Gabriel Kotliar

The $GW$ method for calculating quasi-particle energies of solids commonly begin from a DFT Hamiltonian and Kohn-Sham orbitals in a plane wave basis. Screening of the coulomb interaction is implemented using the inverse dielectric function…

Materials Science · Physics 2026-05-20 Charles H. Patterson

We present a formulation of relativistic self-consistent $GW$ for solids based on the exact two-component formalism with one-electron approximation (X2C1e) and non-relativistic Coulomb interactions. Our theory allows us to study scalar…

Strongly Correlated Electrons · Physics 2022-08-31 Chia-Nan Yeh , Avijit Shee , Qiming Sun , Emanuel Gull , Dominika Zgid