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The method of McCurdy, Baertschy, and Rescigno, J. Phys. B, 37, R137 (2004) is generalized to obtain a straightforward, surprisingly accurate, and scalable numerical representation for calculating the electronic wave functions of molecules.…

In this paper, we newly formulate and solve the optimal density control problem with Gromov-Wasserstein (GW) terminal cost in discrete-time linear Gaussian systems. Differently from the Wasserstein or Kullback-Leibler distances employed in…

Optimization and Control · Mathematics 2024-05-06 Kohei Morimoto , Kenji Kashima

We present a detailed account of the GW space-time method. The method increases the size of systems whose electronic structure can be studied with a computational implementation of Hedin's GW approximation. At the heart of the method is a…

Condensed Matter · Physics 2009-10-31 M. M. Rieger , L. Steinbeck , I. D. White , H. N. Rojas , R. W. Godby

The Hubbard model is implemented in real-space Green's function calculations of x-ray spectra using an effective self-energy adapted from the LSDA+U method of Anisimov et al. This self-energy consists of an energy-dependent many-pole…

Strongly Correlated Electrons · Physics 2011-07-12 Towfiq Ahmed , J. J. Kas , J. J. Rehr

We propose a scalable scheme to implement quantum computation in graphene nanoribbon. It is shown that electron or hole can be naturally localized in each zigzag region for a graphene nanoribbon with a sequence of Z-shaped structure without…

Quantum Physics · Physics 2015-05-13 Guo-Ping Guo , Zhi-Rong Lin , Xiao-Peng Li , Tao Tu , Guang-Can Guo

The expensive cost of computing exact exchange in periodic systems limits the application range of density functional theory with hybrid functionals. To reduce the computational cost of exact change, we present a range-separated algorithm…

Chemical Physics · Physics 2023-07-26 Qiming Sun

We present the first full-potential method that solves the fully relativistic 4-component Dirac-Kohn-Sham equation for materials in the solid state within the framework of atom-centered Gaussian-type orbitals (GTOs). Our GTO-based method…

Chemical Physics · Physics 2019-05-07 Marius Kadek , Michal Repisky , Kenneth Ruud

The quasiparticle self-consistent QS$GW$ approach incorporates the corrections of the quasiparticle energies from their Kohn-Sham density functional theory (DFT) eigenvalues by means of an energy independent and Hermitian self-energy matrix…

Materials Science · Physics 2022-06-08 Ozan Dernek , Dmitry Skachkov , Walter R. L. Lambrecht , Mark van Schilfgaarde

Electronic structure calculations are mostly carried out with Coulomb potential singularity adapted basis sets like STO or contracted GTO. With other basis or for heavy elements the pseudopotentials may appear as a practical alternative.…

Chemical Physics · Physics 2022-11-14 Tommi Höynälänmaa , Tapio Rantala

The $GW$ approximation has become an important tool for predicting charged excitations of isolated molecules and condensed systems. Its popularity can be attributed to many factors, including a favorable scaling and relatively good…

Chemical Physics · Physics 2023-12-18 Daniel Mejia-Rodriguez

We present GW calculations of molecules, ordered and disordered solids and interfaces, which employ an efficient contour deformation technique for frequency integration, and do not require the explicit evaluation of virtual electronic…

Materials Science · Physics 2015-01-14 Marco Govoni , Giulia Galli

Efficient computer implementations of the GW approximation must approximate a numerically challenging frequency integral; the integral can be performed analytically, but doing so leads to an expensive implementation whose computational cost…

Materials Science · Physics 2021-02-24 Sylvia J. Bintrim , Timothy C. Berkelbach

We present a new kind self-consistent GW approximation (scGW) based on the all-electron, full-potential LMTO method. By iterating the eigenfunctions of the GW Hamiltonian, self-consistency in both the charge density and the quasiparticle…

Condensed Matter · Physics 2009-11-10 Sergey V. Faleev , Mark van Schilfgaarde , Takao Kotani

We present algorithmic and implementation details for the fully self-consistent finite-temperature $GW$ method in Gaussian Bloch orbitals for solids. Our implementation is based on the finite-temperature Green's function formalism in which…

Materials Science · Physics 2022-12-14 Chia-Nan Yeh , Sergei Iskakov , Dominika Zgid , Emanuel Gull

We introduce an alternative route to quasiparticle self-consistent $GW$ calculations ($\mathrm{qs}GW$) on the basis of a Joint Approximate Diagonalization of the one-body $GW$ Green's functions $G(\varepsilon_n^{QP})$ taken at the input…

Materials Science · Physics 2024-12-05 Ivan Duchemin , Xavier Blase

The $GW$ method is widely used for calculating the electronic band structure of materials. The high computational cost of $GW$ algorithms prohibits their application to many systems of interest. We present a periodic, low-scaling and highly…

We present a comparison of various approximations to self-consistency in the GW method, including the one-shot G0W0 method, different quasiparticle self-consistency schemes, and the fully self-consistent GW (scGW) approach. To ensure an…

Strongly Correlated Electrons · Physics 2025-10-17 Gaurav Harsha , Vibin Abraham , Ming Wen , Dominika Zgid

In this paper, we construct an efficient numerical scheme for full-potential electronic structure calculations of periodic systems. In this scheme, the computational domain is decomposed into a set of atomic spheres and an interstitial…

Numerical Analysis · Mathematics 2024-12-20 Xiaoxu Li , Huajie Chen

We present a new, all-electron implementation of the GW approximation and apply it to wurtzite ZnO. Eigenfunctions computed in the local-density approximation (LDA) by the full-potential linearized augmented-plane-wave (LAPW) or the…

Materials Science · Physics 2009-11-07 Manabu Usuda , Noriaki Hamada , Takao Kotani , Mark van Schilfgaarde

The gas of the interacted electrons is usually described within Kohn-Sham approximation by the set of Poisson and Schr\"{o}dinger equations with an effective potential for the single-particle wave functions. The solution of these equations…

Materials Science · Physics 2007-05-23 A. Ya. Shul'man , D. V. Posvyanskii