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We show that the symmetry of the spin zigzag chain E phase of the orthorhombic perovskite manganites and nickelates allows for the existence of a finite ferroelectric polarization. The proposed microscopic mechanism is independent of…

Strongly Correlated Electrons · Physics 2007-05-23 I. A. Sergienko , C. Sen , E. Dagotto

Nowadays, designing and searching for materials with multiple functional characteristics are the key to achieving high-performance electronic devices. Among many candidates, two-dimensional multiferroic materials have great potential to be…

Materials Science · Physics 2020-11-03 Hai-Peng You , Ning Ding , Jun Chen , Shuai Dong

The layered perovskites $R$Cr(BO$_3$)$_2$ ($R$ = Y and Ho) with magnetic triangular lattices were studied by performing ac/dc susceptibility, specific heat, elastic and inelastic neutron scattering, and dielectric constant measurements. The…

Materials Science · Physics 2017-09-13 R. Sinclair , H. D. Zhou , M. Lee , E. S. Choi , G. Li , T. Hong , S. Calder

Magnetic structures and the relationship between spin and charge-orbital orderings of an A-site ordered double-perovskite manganite SmBaMn2O6, an anticipated multiferroic material, were investigated by means of neutron diffraction. The spin…

Strongly Correlated Electrons · Physics 2021-07-14 Ryoji Kiyanagi , Shigeki Yamada , Hiroshi Aoki , Hajime Sagayama , Taketo Moyoshi , Akiko Nakao , Takahisa Arima

Recent dielectric and magnetic studies of (Ca0.5Mn1.5)MnWO6 ceramics [A.A. Belik, Chem. Mater. 36, 7604 (2024)] have classified this material as a rare hybrid multiferroic, with both antiferromagnetic and (anti)ferroelectric ordering…

First-principles calculations are presented for the layered perovskite Ca$_3$Mn$_2$O$_7$. The results reveal a rich set of coupled structural, magnetic and polar domains in which oxygen octahedron rotations induce ferroelectricity,…

Materials Science · Physics 2010-12-21 Nicole A. Benedek , Craig J. Fennie

Several families of layered perovskite oxide ferroelectrics exhibit a coupling between polarization and structural order parameters, such as octahedral rotation distortions. This coupling provides opportunities for novel electric…

Materials Science · Physics 2023-03-08 Nabaraj Pokhrel , Elizabeth A. Nowadnick

We predict through our first-principles calculations that four double perovskite oxides of Bi2ABO6 (AB = FeMo, MnMo, MnOs, CrOs) are half-metallic ferrimagnets. Our calculated results shows that the four optimized structures have negative…

Materials Science · Physics 2013-01-31 Si-Da Li , Peng Chen , Bang-Gui Liu

The magnetic properties of the double perovskite oxide $Sr_{2}$FeMo$O_{6}$ are analyzed using a mixed-spin Ising model with spins $\left( \frac{1}{2},\frac{5}{2}\right) $ in the presence of a random crystal field $\Delta$ and exchange…

Statistical Mechanics · Physics 2025-03-10 Said Khaireddine , Redouane Assad , Mohammed El Falaki , Rachid Ahl Lamara , Lalla Btissam Drissi

We report the multiferroic behaviour of MnWO$_4$, a magnetic oxide with monoclinic crystal structure and spiral long-range magnetic order. Based upon recent theoretical predictions MnWO$_4$ should exhibit ferroelectric polarization…

Strongly Correlated Electrons · Physics 2007-05-23 O. Heyer , N. Hollmann , I. Klassen , S. Jodlauk , L. Bohaty , P. Becker , J. A. Mydosh , T. Lorenz , D. Khomskii

Magnetoelectric multiferroics in which ferroelectricity and magnetism coexist have attracted extensive attention because they provide great opportunities for the mutual control of electric polarization by magnetic fields and magnetization…

Materials Science · Physics 2013-04-25 Fen Wang , Tao Zou , Li-Qin Yan , Yi Liu , Young Sun

The magnetic order, spin dynamics, and crystal structure of the multiferroic Sr0.56Ba0.44MnO3 have been investigated using neutron and x-ray scattering. Ferroelectricity develops at TC=305 K with a polarization of 4.2 microC/cm2 associated…

Multiferroics have received intense attention due to their great application potential in multi-state information storage devices and new types of sensors. Coupling among ferroic orders such as ferroelectricity, (anti-)ferromagnetism,…

A comparative study of the dielectric properties and electric polarization of multiferroics GdMn2O5 and Gd0.8Ce0.2Mn2O5 has been carried out in the temperature range from 5 up to 300 K. The polarization properties in the ferroelectric state…

Materials Science · Physics 2018-04-18 V. A. Sanina , B. Kh. Khannanov , E. I. Golovenchits , M. P. Shcheglov

Conventional perovskite-type ferroelectrics are based on octahedral units of oxygen, and often comprise toxic Pb to achieve robust ferroelectricity. Here, we report the ferroelectricity in a silicate-based compound, Bi2SiO5 (BSO), induced…

In this work multiferroic thin films of Bi containing perovskite oxides are discussed, where the driving force for ferroelectricity are the Bi3+ lone-pair electrons. First, a brief introduction of Bi containing multiferroic perovskite…

Strongly Correlated Electrons · Physics 2014-02-11 Rainer Schmidt , Eric Langenberg , Jofre Ventura , Manuel Varela

There have been a large number of papers on bismuth ferrite (BiFeO3) over the past few years, trying to exploit its room-temperature magnetoelectric multiferroic properties. Although these are attractive, BiFeO3 is not the ideal…

The search for room-temperature magnetocaloric materials for refrigeration has led to investigations of double perovskites. In particular, a puzzle has appeared in the La$_2$MnNiO$_6$, La$_2$MnCoO$_6$ and La$_2$MnFeO$_6$ family of…

Strongly Correlated Electrons · Physics 2019-03-04 C. Gauvin-Ndiaye , T. E. Baker , P. Karan , É. Massé , M. Balli , N. Brahiti , M. A. Eskandari , P. Fournier , A. -M. S. Tremblay , R. Nourafkan

High-temperature electronic materials are in constant demand as the required operational range for various industries increases. Here we design $(A,A^\prime)B_2$O$_6$ perovskite oxides with [111] ``rock salt" $A$-site cation order and…

Materials Science · Physics 2014-06-11 Joshua Young , James M. Rondinelli

The complex perovskite Pb2CoTeO6 (PCTO) has been prepared as polycrystalline powders by solid state reaction route, and the crystal structure and magnetic properties have been investigated using a combination of X-ray and neutron powder…

Materials Science · Physics 2010-12-01 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , C. Ritter