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We have grown single crystals of multiferroic double-perovskite Lu2CoMnO6 and studied the directional dependence of their magnetic and dielectric properties. The ferromagnetic order emerges below TC ~ 48K along the crystallographic c axis.…

Strongly Correlated Electrons · Physics 2014-03-26 N. Lee , H. Y. Choi , Y. J. Jo , M. S. Seo , S. Y. Park , Y. J. Choi

A new type of multiferroicity was experimentally discovered in 2003 in a perovskite manganite TbMnO$_3$ where its ferroelectricity is induced by cycloidally ordered Mn spins. Susequently, such spin-cycloid multiferroic phase was also…

Strongly Correlated Electrons · Physics 2025-02-14 Masahito Mochizuki

While nature provides a plethora of perovskite materials, only a few exhibits large ferroelectricity and possibly multiferroicity. The majority of perovskite materials have the non-polar CaTiO$_3$(CTO)structure, limiting the scope of their…

Materials Science · Physics 2022-05-25 Hongwei Wang , Fujie Tang , Massimiliano Stengel , Hongjun Xiang , Qi An , Tony Low , Xifan Wu

Due of its polymorphism, Mn$_2$FeSbO$_6$ can be synthesized at high pressures and temperatures as a ferrimagnetic ilmenite or an antiferromagnetic perovskite. The structural phase transformation is discussed in detail, and magnetic…

Strongly Correlated Electrons · Physics 2013-01-08 R. Mathieu , S. A. Ivanov , I. V. Solovyev , G. V. Bazuev , P. Anil Kumar , P. Lazor , P. Nordblad

In ABO3 perovskites, oxygen octahedron rotations are common structural distortions that can promote large ferroelectricity in BiFeO3 with an R3c structure [1], but suppress ferroelectricity in CaTiO3 with a Pbnm symmetry [2]. For many…

Materials Science · Physics 2016-04-05 Hongwei Wang , Jianguo Wen , Dean J. Miller , Qibin Zhou , Mohan Chen , Ho Nyung Lee , Karin M. Rabe , Xifan Wu

The emergence of altermagnets establishes a new paradigm for multiferroics. Unlike conventional multiferroics relying on direct magnetoelectric coupling, multiferroic altermagnets host a crystal-symmetry-mediated magnetoelectric interaction…

Materials Science · Physics 2026-01-12 Zhou Cui , Ziye Zhu , Xunkai Duan , Bowen Hao , Xianzhang Chen , Jiayong Zhang , Tong Zhou

A theoretical description of the sequence of magnetic phases in Co3TeO6 is presented. The strongly first-order character of the transition to the commensurate multiferroic ground state, induced by coupled order parameters corresponding to…

Strongly Correlated Electrons · Physics 2012-07-06 Pierre Tolédano , Vera Carolus , Matthias Hudl , Thomas Lottermoser , Dmitry D. Khalyavin , Sergey A. Ivanov , Manfred Fiebig

Given the paucity of single phase multiferroic materials (with large ferromagnetic moment), composite systems seem an attractive solution in the quest to realize magnetoelectric cou-pling between ferromagnetic and ferroelectric order…

Mesoscale and Nanoscale Physics · Physics 2014-09-15 P. Jain , Q. Wang , M. Roldan , A. Glavic , V. Lauter , C. Urban , Z. Bi , T. Ahmed , J. Zhu , M. Varela , Q. Jia , M. R. Fitzsimmons

Our measured dielectric constant and mechanical response of multiferroic BiFeO3 indicate four phase transitions below room temperature. Features correlate with those reported at 50K (from a peak in the zero-field-cooled magnetic…

Materials Science · Physics 2008-06-23 S. A. T. Redfern , C. Wang , J. W. Hong , G. Catalan , J. F. Scott

By means of magnetic, specific heat and pyroelectric measurements, we report on magnetic ferroelectricity in the quadruple perovskite \namno, characterized by a canted antiferromagnetic (AFM) CE structure. Surprisingly, ferroelectricity is…

Using first-principles calculations, we predict that tunable ferroelectricity can be realized in oxide perovskites with the Grenier structure and ordered oxygen vacancies. Specifically, we show that $R_{1/3}A_{2/3}\mathrm{FeO}_{2.67}$…

Materials Science · Physics 2023-07-12 Yongjin Shin , Giulia Galli

We report on the synthesis and characterization of BiFe0.5Mn0.5O3, a potential type-I multiferroic compound displaying temperature induced magnetization reversal. Bulk samples were obtained by means of solid state reaction carried out under…

Magnetic phase transitions in multiferroic bismuth ferrite (BiFeO3) induced by magnetic field, epitaxial strain, and composition modification are considered. These transitions from a spatially modulated spin spiral state to a homogenous…

Strongly Correlated Electrons · Physics 2008-12-28 A. M. Kadomtseva , Yu. F. Popov , A. P. Pyatakov , G. P. Vorob'ev , A. K. Zvezdin , D. Viehland

Interaction between dipoles often emerges intriguing physical phenomena, such as exchange bias in the magnetic heterostructures and magnetoelectric effect in multiferroics, which lead to advances in multifunctional heterostructures.…

The design of novel multiferroic ABO$_3$ perovskites is complicated by the presence of necessary magnetic cations and ubiquitous antiferrodistortive modes, both of which suppress polar distortions. Using first-principles simulations, we…

Materials Science · Physics 2024-06-10 Cameron A. M. Scott , Nicholas C. Bristowe

In this work, we report the synthesis and investigation of structural, electronic, and magnetic properties of La$_{1.5}$Ca$_{0.5}$(Co$_{0.5}$Fe$_{0.5}$)IrO$_6$. Our polycrystalline sample forms as a single-phase double perovskite in…

Good quality and fine grain Bi6Fe2Ti3O18 magnetic ferroelectric films with single-phase layered perovskite structure have been successfully prepared via metal organic decomposition (MOD) method. Results of low-temperature magnetocapacitance…

Materials Science · Physics 2007-05-23 J. Lu , L. J. Qiao , X. Q. Ma , W. Y. Chu

Multiferroicity and magnetodielectric coupling in metal-organic-frameworks (MOFs) is rare and so far restricted mainly to formate-based systems with perovskite structure. In the course of this work we designed a tetragonal framework…

Materials Science · Physics 2017-10-31 Tathamay Basu , A. Jesche , B. Bredenkotter , M. Grzywa , D. Denysenko , D. Volkmer , A. Loidl , S. Krohns

Using the theory of symmetry and the microscopic model we predicted the possibility of a linear roto-antiferromagnetic effect in the perovskites with structural antiferrodistortive and antiferromagnetic long-range ordering and found the…

Room-temperature ferrimagnetism was discovered for the anti-site-disordered perovskite Ca2MnOsO6 with Tc = 305 K. Ca2MnOsO6 crystallizes into an orthorhombic structure with a space group of Pnma, in which Mn and Os share the…

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