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The coexistence of ferroelectric and ferromagnetic properties at room temperature is very rarely observed. We have been successful in converting ferroelectric PbTiO3 into a magnetoelectric material by partly substituting Fe at the Ti site.…

Materials Science · Physics 2009-11-11 V. R. Palkar , S. K. Malik

Structural, magnetic and electric properties of a metal-ordered perovskite YBaMn2O6 have been studied by means of powder X-ray diffraction, DSC, magnetic susceptibility, and electric resistivity. It is found that this material undergoes a…

Strongly Correlated Electrons · Physics 2009-11-07 T. Nakajima , H. Kageyama , Y. Ueda

We present a first-principles study of ferroelectric domain walls (FE-DWs) in multiferroic BiFeO$_3$ (BFO), a material in which the FE order parameter coexists with anti-ferrodistortive (AFD) modes involving rotations of the O$_6$…

Materials Science · Physics 2015-06-12 Oswaldo Diéguez , Pablo Aguado-Puente , Javier Junquera , Jorge Íñiguez

In this article, we perform the symmetry analysis of perovskite-based multiferroics: bismuth ferrite (BiFeO3)-like, orthochromites (RCrO3), and Ruddlesden-Popper perovskites (Ca3Mn2O7-like), being the typical representatives of…

Materials Science · Physics 2022-01-26 Zukhra Gareeva , Anatoly Zvezdin , Konstantin Zvezdin , Xiang Ming Chen

Two dimensional multiferroics inherit prominent physical properties from both low dimensional materials and magnetoelectric materials, and can go beyond their three dimensional counterparts for their unique structures. Here, based on…

Materials Science · Physics 2021-09-29 Mingyu Zhao , Jun Chen , Shan-Shan Wang , Ming An , Shuai Dong

The layered perovskite YBaCuFeO5 (YBCFO) is considered one of the best candidates to high-temperature chiral multiferroics with strong magnetoelectric coupling. In RBaCuFeO5 perovskites (R: rare-earth or Y) A-site cations are fully ordered…

Materials Science · Physics 2021-03-10 X. Zhang , A. Romaguera , O. Fabelo , F. Fauth , J. Herrero-Martín , J. L. García-Muñoz

From magnetic susceptibility, dielectric permittivity, electric polarization and specific heat measurements, we discover spin-induced ferroelectricity and magnetoelectric coupling in Mn3TeO6 and observe two successive magnetic transitions…

Materials Science · Physics 2015-12-01 L. Zhao , Z. Hu , C. Y. Kuo , T. -W. Pi , M. -K. Wu , L. H. Tjeng , A. C. Komarek

We consider a model of the double perovskite Ba2FeReO6, a room temperature ferrimagnet with correlated and spin-orbit coupled Re t2g electrons moving in the background of Fe moments stabilized by Hund's coupling. We show that for such 3d/5d…

Strongly Correlated Electrons · Physics 2015-06-16 A. M. Cook , A. Paramekanti

Magnetic and dielectric properties on a polycrystalline La0.7Bi0.3CrO3 have been investigated. A canted antiferromagnetic (CAF) phase transition giving weak ferromagnetism at TN = 230K has been observed. M-H at 10K shows non-saturating…

Strongly Correlated Electrons · Physics 2014-03-17 Aga Shahee , Dhirendra kumar , N. P. Lalla

Ferroics, characterized by a broken symmetry state with nonzero elastic, polar, or magnetic order parameters $\vec{u}$, are recognized platforms for staging and manipulating topologically-protected structures as well as for detecting…

Materials Science · Physics 2018-10-31 Antonio B. Mei , Ramamoorthy Ramesh , Darrell G. Schlom

Titanates with the perovskite structure, including ferroelectrics (e.g., BaTiO$_3$) and ferromagnetic ones (e.g., YTiO$_3$), are important functional materials. Recent theoretical studies predicted multiferroic states in strained EuTiO$_3$…

Materials Science · Physics 2015-12-14 Ming An , Huimin Zhang , Yakui Weng , Yang Zhang , Shuai Dong

The Half-Metallic Ferromagnetic behavior of some double perovskites attracts much interest. In this work, we studied the magnetic behavior of the double perovskite Pb2FeReO6. The magnetic atoms are Fe and Re and have the spins S=5/2 and…

Materials Science · Physics 2020-02-20 S. Mtougui , S. Idrissi , H. Labrim , N. El Mekkaoui , I. El Housni , S. Ziti , R. Khalladi , L. Bahmad

The symmetry properties, order parameters, and magnetoelectric phase diagrams of multiferroics are discussed. After brief reviews of Ni$_3$V$_2$O$_8$, TbMnO$_3$, and RbFe(MoO$_4$)$_2$, we present a detailed analysis of RMn$_2$O$_5$ (with…

Materials Science · Physics 2009-11-13 A. B. Harris , Amnon Aharony , O. Entin-Wohlman

Recent experimental and theoretical work has shown that the double perovskite NaLaMnWO$_6$ exhibits antiferromagnetic ordering owing to the Mn $d$ states, and computational studies further predict it to exhibit a spontaneous electric…

Materials Science · Physics 2015-11-18 Joshua Young , Alessandro Stroppa , Silvia Picozzi , James M. Rondinelli

Localized $5d^2$ electrons in a cubic crystal field possess multipoles such as electric quadrupoles and magnetic octupoles. We studied the cubic double perovskite Ba$_2$CaOsO$_6$ containing the Os$^{6+}$ ($5d^2$) ions, which exhibits a…

Double perovskite compounds containing 5d transition metal elements have been extensively studied as platforms for multipolar order phenomena stemming from spin-orbit-entangled 5d electrons. In this study, we examine the interplay between…

Strongly Correlated Electrons · Physics 2025-04-02 Koki Shibuya , Daigorou Hirai , Koshi Takenaka

In this contribution to the special issue on multiferroics we focus on multiferroicity driven by different forms of charge ordering. We will present the generic mechanisms by which charge ordering can induce ferroelectricity in magnetic…

Materials Science · Physics 2011-07-22 Jeroen van den Brink , Daniel I. Khomskii

Perovskite manganites with small A-site ions, as the first and canonical branch of type-II multiferroics, are ideal systems to exhibit magnetism-induced ferroelectricity. Despite their established magnetoelectric phase diagrams under low…

Materials Science · Physics 2026-01-15 Ming Yang , Jun Chen , Junfeng Wang , Chao Dong , Chengliang Lu , Gang Xu , Jinguang Cheng , Jianshi Zhou , Shuai Dong

The coexistence of multiple ferroic orders, i.e. multiferroicity, is a scarce property to be found in materials. Historically, this state has been found mainly in 3-dimensional complex oxides, but so far this state has still been elusive…

Double perovskites of the form A_2BB'O_6 usually involve a transition metal ion, B, with a large magnetic moment, and a non magnetic ion B'. While many double perovskites are ferromagnetic, studies on the underlying model reveal the…

Strongly Correlated Electrons · Physics 2013-02-07 Rajarshi Tiwari , Pinaki Majumdar