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We present a comprehensive experimental study of magnetization and magnetocaloric effect (MCE) in double perovskite (DP) materials $R_2$NiMnO$_6$ with $R =$ Pr, Nd, Sm, Gd, Tb, and Dy. While a paramagnetic to ferromagnetic transition, with…

Strongly Correlated Electrons · Physics 2021-12-30 Anzar Ali , Kanika Pasrija , Gyaneshwar Sharma , Sanjeev Kumar , Yogesh Singh

The layered perovskite compounds are interesting due to their intriguing physical properties. In this article we report the structural, magnetic and dielectric properties of LnBaCuFeO5 (Ln=Nd, Eu, Gd, Ho and Yb). The structural parameters…

Materials Science · Physics 2019-06-19 Surender Lal , K. Mukherjee , C. S. Yadav

Materials exhibiting electronic inhomogeneities at the nanometer scale have enormous potential for applications. Magnetic polarons are one such type of inhomogeneity which link the electronic, magnetic and lattice degrees of freedom in…

We present a study of the dielectric, structural, and magnetic properties of the multiferroic or linear magnetoelectric substitution series [(NH$_4$)$_{1-x}$K$_x$]$_2$[FeCl$_5$(H$_2$O)]. Pyroelectric currents, magnetic susceptibilities, and…

A new series of cubic double perovskites Ba$_2R_{2/3}$TeO$_6$ ($R$ = Y, La, Pr, Nd, Sm-Lu) was synthesized via solid state reaction. The $R^{3+}$ and Te$^{6+}$ ions are ordered on alternating octahedral sites, with the rare earth sites 2/3…

Materials Science · Physics 2019-03-14 Tai Kong , Robert J. Cava

We report first-principles calculations for one of the few materials that is believed to be a ferroelectric ferromagnet, Bi$_2$NiMnO$_6$. Our calculations show that, contrary to what it has been reported so far, bulk Bi$_2$NiMnO$_6$ does…

Materials Science · Physics 2017-03-01 Oswaldo Diéguez , Jorge Íñiguez

We use first-principles density functional theory-based calculations to investigate structural instabilities in the high symmetry cubic perovskite structure of rare-earth (R $=$ La, Y, Lu) and Bi-based biferroic chromites, focusing on…

Materials Science · Physics 2009-11-13 Nirat Ray , Umesh V. Waghmare

We present results of an {\it ab initio} density functional theory study of three bismuth-based multiferroics, BiFeO$_{3}$, Bi$_{2}$FeCrO$_{6}$, and BiCrO$_{3}$. We disuss differences in the crystal and electronic structure of the three…

Materials Science · Physics 2007-05-23 Pio Baettig , Claude Ederer , Nicola A. Spaldin

The orthovanadate DyVO3 crystal, known to exhibit multiple structural, spin and orbital ordering transitions, is presently investigated on the basis of magnetization, heat capacity, resistivity, dielectric and polarization measurements. Our…

Strongly Correlated Electrons · Physics 2014-07-24 Q. Zhang , K. Singh , C. Simon , L. D. Tung , G. Balakrishnan , V. Hardy

Materials with a 5d4 electronic configuration are generally considered to have a nonmagnetic ground state (J=0). Interestingly, Sr2YIrO6 (Ir5+ having 5d4 electronic configuration) was recently reported to exhibit long-range magnetic order…

Electric and magnetic properties of multiferroic GdMn2O5 in external magnetic fields were investigated to map out the magnetoelectric phases in this material. Due to strong magnetoelectric coupling, the dielectric permittivity is highly…

In a cubic environment, the ground state of spin-orbit coupled $5d^2$ ions is a non-Kramers $E_g$ doublet, which hosts quadrupole and octupole moments. A series of $5d^2$ osmium double perovskites Ba$_2M$OsO$_6$ (M = Mg, Ca, Zn, Cd) have…

Strongly Correlated Electrons · Physics 2023-08-14 Ahmed Rayyan , Xiaoyu Liu , Hae-Young Kee

We report on the microwave, terahertz (THz), infrared and Raman spectroscopic studies of $BiMn_{7}O_{12}$ ceramics, shedding more light into the nature of two structural phase transitions and their possible relation with ferroelectricity in…

Materials Science · Physics 2024-01-08 A. Maia , M. Kempa , V. Bovtun , R. Vilarinho , C. Kadlec , J. Agostinho Moreira , A. A. Belik , P. Proschek , S. Kamba

Two-dimensional (2D) transition-metal oxide perovskites greatly expand the field of available 2D multifunctional material systems. Here, based on density functional theory calculations, we predicted the presence of ferromagnetism orders…

Materials Science · Physics 2021-06-01 Shaowen Xu , Fanhao Jia , Guodong Zhao , Tao Hu , Shunbo Hu , Wei Ren

The complex perovskite Ba2CoTeO6 (BCTO) has been synthesised, and the crystal structure and magnetic properties have been investigated using a combination of X-ray and neutron powder diffraction, electron microscopy and dielectric,…

Materials Science · Physics 2010-12-01 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , C. Ritter

We report an unusual magnetic ground state in single-crystal, double-perovskite Ba2YIrO6 and Sr doped Ba2YIrO6 with Ir5+(5d4) ions. Long-range magnetic order below 1.7 K is confirmed by DC magnetization, AC magnetic susceptibility and heat…

Strongly Correlated Electrons · Physics 2017-09-01 J. Terizc , H. Zheng , Feng Ye , H. D. Zhao , P. Schlottmann , L. De Long , G. Cao

Oxide double perovskites wherein octahedra formed by both 3d elements and sp-based heavy elements give rise to unconventional magnetic ordering and correlated quantum phenomena crucial for futuristic applications. Here, by carrying out…

Strongly Correlated Electrons · Physics 2021-03-30 J. Khatua , T. Arh , Shashi B. Mishra , H. Luetkens , A. Zorko , B. Sana , M. S. Ramachandra Rao , B. R. K. Nanda , P. Khuntia

We report a comprehensive investigation of the triple perovskite iridate Ba$_{3}$CoIr$_{2}$O$_{9}$. Stabilizing in the hexagonal $P6_{3}/mmc$ symmetry at room temperature, this system transforms to a monoclinic $C2/c$ symmetry at the…

Strongly Correlated Electrons · Physics 2021-02-03 Charu Garg , Deepak Roy , Martin Lonsky , Pascal Manuel , Antonio Cervellino , Jens Müller , Mukul Kabir , Sunil Nair

Two-dimensional (2D) magnets have broad application prospects in the spintronics, but how to effectively control them with a small electric field is still an issue. Here we propose that 2D magnets can be efficiently controlled in a…

Mesoscale and Nanoscale Physics · Physics 2022-02-01 Ping Li , Xue-Song Zhou , Zhi-Xin Guo

It is of great interest to design and make materials in which ferroelectric polarisation is coupled to other order parameters such as lattice, magnetic and electronic instabilities. Such materials will be invaluable in next-generation data…

Strongly Correlated Electrons · Physics 2018-05-09 Wei-Tin Chen , Chin-Wei Wang , Hung-Cheng Wu , Fang-Cheng Chou , Hung-Duen Yang , Arkadiy Simonov , Mark S. Senn