Related papers: Are fulleranes responsible for the 21 micron featu…
Sequential ionization of fullerene cluster ions (C$_{60}$)$_{n}^{+}$ within multiply-charged helium nanodroplets leads to the intriguing phenomenon of forming and stabilizing doubly- and triply-charged fullerene oligomers. Surprisingly, we…
The spectra of fullerenes C60 and C70, higher fullerenes C76, C78 and C84 and hydrogenated fullerenes (fulleranes) were studied in laboratory in the UV and in the visible spectral range and could be used for searching and recognizing these…
The infrared spectra of many galactic and extragalactic objects are dominated by emission features at 3.3, 6.2, 7.7, 8.6 and 11.2 \mu m. The carriers of these features remained a mystery for almost a decade, hence the bands were dubbed the…
Recent experimental reports on the realizations of two-dimensional (2D) networks of the C60-based fullerenes with anisotropic and nanoporous lattices represent a significant advance, and create exciting prospects for the development of a…
Nanoclusters like fullerenes as the unit to build intriguing two-dimensional topological structures is of great challenge. Here we propose three bridged fullerene monolayers and comprehensively investigate the novel fullerene monolayer as…
Correctness of the model representing the fullerene shell C60 as a conducting sphere has been analyzed. The static and dynamical polarizabilities of the molecule C60 have been calculated on the basis of experimental data on the…
The current debate about the nature of the carbonaceous material carrying the infrared (IR) emission spectra of planetary and proto-planetary nebulae, including the broad plateaus, calls for further studies on the interplay between…
Li4C60, one of the best representatives of lithium intercalated fullerides, features a novel type of 2D polymerization. Extensive investigations, including laboratory x-ray and synchrotron radiation diffraction, 13C NMR, MAS and Raman…
We search high-resolution and high-quality VLT/UVES optical spectra of the hot R Coronae Borealis (RCB) star DY Cen for electronic transitions of the C60 molecule and diffuse interstellar bands (DIBs). We report the non-detection of the…
Interstellar graphene could be present in the interstellar medium (ISM), resulting from the photochemical processing of polycyclic aromatic hydrocarbon (PAH) molecules and/or collisional fragmentation of graphitic particles. Indeed, by…
In this study, based on density functional theory (DFT), we propose a new branch of pseudo-fullerenes which contain triple bonds with sp hybridization. We should call these new nanostructures fullerynes, according to IUPAC. We present four…
The formation and evolution mechanism of fullerenes in the planetary nebula or in the interstellar medium are still not understood. Here we present the study on the cluster formation and the relative reactivity of fullerene cations (from…
We report the detection of a broad 22 microns emission feature in the Carina nebula H II region by the Infrared Space Observatory (ISO) Short Wavelength Spectrometer. The feature shape is similar to that of the 22 microns emission feature…
The aromatic infrared Bands (AIBs) dominate the mid-infrared spectra of many galactic and extragalactic sources. These AIBs are generally attributed to fluorescent emission from aromatic molecules. Unified efforts from experimentalists and…
We present a charge distribution-based emission model that calculates the infrared spectrum of fullerenes (C$_{60}$). Analysis of the modelled spectrum of C$_{60}$ in various charge states shows that the relative intensity of the features…
It is well known that collective electronic excitations in fullerene C$_{60}$ are manifested as Mie plasmons, and in graphene (the limiting case of an infinitely large fullerene) collective excitations are of plasmon-polariton type. How the…
In 2015, Campbell et al. (Nature 523, 322) presented spectroscopic laboratory gas phase data for the fullerene cation, C$_{60}^+$, that coincide with reported astronomical spectra of two diffuse interstellar band (DIB) features at 9633 and…
The stronger than expected 21-cm absorption was observed by EDGES recently, and another anomaly of $^8$Be transitions would be signatures of new interactions. These two issues may be related to each other, e.g., pseudoscalar $A$ mediated…
We present medium-resolution (R~700) near-infrared (lambda = 1 - 2.5 micron) spectra of a sample of planetary nebulae (PNe). A narrow slit was used which sampled discrete locations within the nebulae; observations were obtained at one or…
Mid-IR observations of planetary nebulae (PNe) have revealed diffuse emission associated to their main nebular shells and outer envelopes or haloes. The interpretation of this emission is uncertain because the broad-band mid-IR images may…