Related papers: Are fulleranes responsible for the 21 micron featu…
The carrier of the 21 ${\mu}$m emission feature discovered in a handful of protoplanetary nebulae (PPNe) is one of the most intriguing enigmas in circumstellar chemistry. Investigating the gas-phase molecules in PPNe could yield important…
Fullerenes have recently been identified in space and they may play a significant role in the gas and dust budget of various astrophysical objects including planetary nebulae (PNe), reflection nebulae (RNe) and H II regions. The tenuous…
The coexistence of PAHs and the C$_{60}$ fullerene in different astrophysical environments can give rise to the formation of new complex species denoted as PAH-C$_{60}$ adducts, which may contribute to the infrared (IR) emission observed.…
The carriers of the diffuse interstellar bands (DIBs) still remain an unknown commodity. Both dust and molecules have been suggested as carriers but none proposed have yet been able to explain the nature and the diversity of the DIBs.…
Based on gas-phase laboratory spectra at 6 K, Campbell et al. (2015) confirmed that the diffuse interstellar bands (DIBs) at 9632.7 and 9577.5A are due to absorption by the fullerene ion C60+. They also reported the detection of two other,…
A prominent, mysterious emission feature peaking at ~20.1 micrometer --- historically known as the ``21 micrometer' feature --- is seen in over two dozen Galactic and Magellanic Cloud carbon-rich post-asymptotic giant branch (post-AGB)…
We report on the detection with the Infrared Space Observatory (ISO) of a molecular band at 57.5 microns (174 cm^{-1}) in carbon-rich evolved stars and in Sgr B2. Taking into account the chemistry of these objects the most likelihood…
The electron-conduction properties of fullerene chains are examined by first-principles calculations based on the density functional theory. The conductivity of the C$_{60}$ dimer is low owing to the constraint of the junction of the…
We demonstrate that by combining two robust theoretical quantum chemistry calculation techniques, stepwise ionization of C60 fullerene by UV and extreme UV photons can in principle occur up to a limit as high as q=+26 before coulomb…
We carried out synthetic observations of interstellar atomic hydrogen at 21cm wavelength by utilizing the magneto-hydrodynamical numerical simulations of the inhomogeneous turbulent interstellar medium (ISM) Inoue and Inutsuka (2012). The…
We report the detection of a feature at 65um and a broad feature around 100um in the far-infrared spectra of the diffuse emission from two active star-forming regions, the Carina nebula and Sharpless 171. The features are seen in the…
The identification of the carriers of the diffuse interstellar bands (DIBs) remains to be established, with the exception of five bands attributed to C60+, although it is generally agreed that DIB carriers should be large carbon-based…
The 21micron and 30micron bands are the strongest dust emission features detected in evolved low- and intermediate-mass C-rich stars (i.e. asymptotic giant branch [AGB] stars, proto-planetary nebulae [PPN], and planetary nebulae [PN]).…
The 21 cm signal appears to be a treasure trove to provide an insight into the period when the first generation of luminous objects formed in the Universe. Hydrogen is the predominating fraction of the total baryonic matter during cosmic…
The C_{60} molecule exhibits a remarkable stability and inertness that leads to its survival in ancient carbonaceous rocks initially subject to the high temperatures requisite for its formation. Elementary particles having very high…
Astronomical dust molecule of carbon-rich nebula-Lin49 and nebula-Tc1 could be identified to be polycyclic-pure-carbon C23 by the quantum-chemical calculation. Two driving forces were assumed. One is high speed proton attack on…
The possible detection of C_{24}, a planar graphene, recently reported in several planetary nebulae by Garciaa-Hernandez et al. (2011, 2012) inspires us to explore whether and how much graphene could exist in the interstellar medium (ISM)…
Recent studies have confirmed the presence of buckminsterfullerene (C$_{60}$) in different interstellar and circumstellar environments. However, several aspects regarding C$_{60}$ in space are not well understood yet, such as the formation…
There exists a number of astronomical spectral phenomena that have remained unidentified after decades of extensive observations. The diffuse interstellar bands, the 220 nm feature, unidentified infrared emission bands, extended red…
Computational chemistry is used here to determine the vibrational line spectrum of several candidate molecules. It is shown that the thiourea functional group, associated with various carbonaceous structures (mainly compact and linear…