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Aims. The comparative study of several molecular species at the origin of the gas phase chemistry in the diffuse interstellar medium (ISM) is a key input in unraveling the coupled chemical and dynamical evolution of the ISM. Methods. The…

Astrophysics of Galaxies · Physics 2015-05-19 Benjamin Godard , Edith Falgarone , Maryvonne Gerin , Pierre Hily-Blant , Massimo De Luca

Carbon ($^3$P) atom is a reactive species that, according to laboratory experiments and theoretical calculations, condensates with interstellar ice components. This fact is of uttermost importance for the chemistry in the interstellar…

Astrophysics of Galaxies · Physics 2023-07-19 Stefano Ferrero , Cecilia Ceccarelli , Piero Ugliengo , Mariona Sodupe , Albert Rimola

As a work in progress, results from a chemical and physical analysis of molecular cores in early evolutionary stages concerning star formation are presented. Using archival data from the Atacama Large Millimeter Array (ALMA), a sample of 37…

Astrophysics of Galaxies · Physics 2026-03-06 R. D. Taboada , S. Paron , M. E. Ortega , H. Saldaño

We consider six isomeric groups (CH3N, CH5N, C2H5N, C2H7N, C3H7N and C3H9N) to review the presence of amines and aldimines within the interstellar medium (ISM). Each of these groups contains at least one aldimine or amine. Methanimine…

Astrophysics of Galaxies · Physics 2023-03-14 Milan Sil , Prasanta Gorai , Ankan Das , Bratati Bhat , Emmanuel E. Etim , Sandip K. Chakrabarti

(Abridged) Complex organic molecules (COMs) are considered essential precursors to prebiotic species. While COMs were once expected to be efficiently destroyed under UV-irradiated conditions, detections in photodissociation regions (PDRs)…

Straight-chain (normal-propyl cyanide, n - C3H7CN) and branched-chain (iso-propyl cyanide, i - C3H7CN) alkyl cyanides are recently identified in the massive star-forming regions (Sgr B2(N) and Orion). These branched-chain molecules indicate…

Astrophysics of Galaxies · Physics 2022-08-09 Satyam Srivastav , Milan Sil , Prasanta Gorai , Amit Pathak , Bhalamurugan Sivaraman , Ankan Das

The isocyanic acid (HNCO) presents an extended distribution in the centers of the Milky Way and the spiral galaxy IC342. Based on the morphology of the emission and the HNCO abundance with respect to H2, several authors made the hypothesis…

Astrophysics of Galaxies · Physics 2015-05-18 Nemesio Rodriguez-Fernandez , Mario Tafalla , Frederic Gueth , Rafael Bachiller

The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards G10.6-0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We…

Complex organic molecules are readily detected in the inner regions of the gaseous envelopes of forming protostars. In particular, molecules that contain nitrogen are interesting due to the role nitrogen plays in the development of life and…

We investigate the molecular gas properties of the deeply obscured luminous infrared galaxy NGC 4418. We address the excitation of the complex molecule HC3N to determine whether its unusually luminous emission is related to the nature of…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-18 F. Costagliola , S. Aalto

The detection of organic molecules with increasing complexity and potential biological relevance is opening the possibility to understand the formation of the building blocks of life in the interstellar medium. One of the families of…

Astrophysics of Galaxies · Physics 2017-02-22 V. M. Rivilla , M. T. Beltrán , J. Martín-Pintado , F. Fontani , P. Caselli , R. Cesaroni

Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Astrophysics of Galaxies · Physics 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

It is not known whether the original carriers of Earth's nitrogen were molecular ices or refractory dust. To investigate this question, we have used data and results of Herschel observations towards two protostellar sources: the high-mass…

Solar and Stellar Astrophysics · Physics 2018-10-31 Thomas S. Rice , Edwin A. Bergin , Jes K. Jørgensen , S. F. Wampfler

How complex organic - and potentially prebiotic - molecules are formed in regions of low- and high-mass star-formation remains a central question in astrochemistry. In particular, with just a few sources studied in detail, it is unclear…

Astrophysics of Galaxies · Physics 2015-10-14 Julie M. Lykke , Cécile Favre , Edwin A. Bergin , Jes K. Jørgensen

In recent astrochemical studies it has become crucial to study all the complete conformational panorama of the molecule, some of which are potentially detectable in the interstellar medium (ISM). In this context, the isomeric ratio can be…

Astrophysics of Galaxies · Physics 2025-06-04 Miguel Sanz-Novo , Germán Molpeceres , Víctor M. Rivilla , Izaskun Jiménez-Serra

Current gas phase models do not account for the abundances of HNCO isomers detected in various environments, suggesting a formation in icy grain mantles. We attempted to study a formation channel of HNCO and its possible isomers by…

Instrumentation and Methods for Astrophysics · Physics 2014-07-07 A. Jiménez-Escobar , B. M. Giuliano , G. M. Muñoz Caro , J. Cernicharo , N. Marcelino

We present high-spatial-resolution (0.7 to 1.0 arcsec) submillimeter observations of continuum and molecular lines of CH3OCHO, CH3OCH3, and H2CCO toward 11 high-mass star-forming regions using the Atacama Large Millimetre/submillimetre…

Massive star-forming regions exhibit an extremely rich and diverse chemistry, which in principle provides a wealth of molecular probes, as well as laboratories for interstellar prebiotic chemistry. Since the chemical structure of these…

We study the astrochemical diagnostics of the isolated massive protostar G28.20-0.05. We analyze data from ALMA 1.3~mm observations with resolution of 0.2 arcsec ($\sim$1,000 au). We detect emission from a wealth of species, including…

Searches for the prebiotically-relevant cyanamide (NH$_2$CN) towards solar-type protostars have not been reported in the literature. We here present the first detection of this species in the warm gas surrounding two solar-type protostars,…

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