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The paper presents a short overview of research into properties of organic materials and structures that could be used in optoelectrical switches, i.e., switches in which changes in electrical properties are triggered by light of…

Chemical Physics · Physics 2011-12-06 Juliusz Sworakowski , Petro Lutsyk

Organic-inorganic halide perovskites recently have emerged as a promising material for highly effective light-emitting diodes (LEDs) and solar cells (SCs). Despite efficiencies of both perovskite SCs and LEDs are already among the best, the…

Pb-based perovskites are considered to be the most efficient materials for energy harvest. However, real-time application is limited because of their toxicity. As a result, lead-free perovskites that offer similar advantages are potential…

Despite the simplicity of the original perovskite crystal structure, this family of compounds shows an enormous variety of structural modifications and variants. In the following, we will describe several examples of perovskites, their…

Strongly Correlated Electrons · Physics 2022-05-31 Mats Johnsson , Peter Lemmens

This article reviews the polarizability model and its applications to ferroelectric perovskite oxides. The motivation for the introduction of the model is discussed and nonlinear oxygen ion polarizability effects and their lattice dynamical…

Materials Science · Physics 2015-06-05 Annette Bussmann-Holder

Transition-metal perovskite oxides constitute a series of functional material systems for electronics, catalysis and energy-conversion processes, in which oxygen migration and evolution play a key role. However, the stable metal-oxygen…

Materials Science · Physics 2021-11-02 Qian Wang , Youdi Gu , Wenxuan Zhu , Lei Han , Feng Pan , Cheng Song

The complex perovskite Pb2CoTeO6 (PCTO) has been prepared as polycrystalline powders by solid state reaction route, and the crystal structure and magnetic properties have been investigated using a combination of X-ray and neutron powder…

Materials Science · Physics 2010-12-01 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , C. Ritter

ABO3 oxides with the perovskite-related structures are attracting significant interest due to their promising physical and chemical properties for many applications requiring tunable chemistry, including fuel cells, catalysis, and…

Materials Science · Physics 2021-07-13 Su Jeong Heo , Andriy Zakutayev

We investigate the polarity-dependent field-induced resistive switching phenomenon driven by electric pulses in perovskite oxides. Our data show that the switching is a common occurrence restricted to an interfacial layer between a…

Superconductivity · Physics 2009-11-10 S. Tsui , A. Baikalov , J. Cmaidalka , Y. Y. Sun , Y. Q. Wang , Y. Y. Xue , C. W. Chu , L. Chen , A. J. Jacobson

A correlation between structure and vibrational properties related to a ferroelectric to paraelectric phase transition in perovskite Pb(1-x)(Na0.5Sm0.5)xTiO3 (PNST - x) polycrystalline powders is discussed. Substitution leads to reduction…

In this thesis, I discuss several basic science studies in the field of energy materials using neutron scattering as a probe for the lattice dynamics. To enable understanding of neutron scattering spectra, I also use computational and…

Materials Science · Physics 2025-04-25 Tyler C. Sterling

We extract a variable $X$ from electron orbitals $\Psi_{n\bf{k}}$ and energies $E_{n\bf{k}}$ in the parent high-symmetry structure of a wide range of complex oxides: perovskites, rutiles, pyrochlores, and cristobalites. Even though…

Materials Science · Physics 2018-05-23 Nicholas Rajen , Sinisa Coh

Halide perovskites have emerged recently as promising materials for many applications in photovoltaics and optoelectronics. Recent studies of their optical properties suggest many novel opportunities for a design of advanced nanophotonic…

For decades, numerous attempts have been made to produce polar oxynitride perovskites, where some of the oxygen are replaced by nitrogen, but a polar ordered oxynitride has never been demonstrated. Caracas and Cohen studied possible ordered…

Photocatalytic water splitting represents a very promising but at the same time very challenging contribution to a clean and renewable route to produce hydrogen fuel. Developing efficient and cost-effective photocatalysts for water…

Materials Science · Physics 2023-01-12 Manjari Jain , Deepika Gill , Sanchi Monga , Saswata Bhattacharya

Inorganic-organic perovskites semiconductors are becoming increasingly interesting due to their remarkable optical properties, such as a high photoluminescence quantum yield and the possibility to show optical gain in a broad range of…

Optics · Physics 2021-03-30 Michele Bellingeri , Francesco Scotognella

Halide perovskites have been extensively studied as materials of interest for optoelectronic applications. There is a major emphasis on ways to tailor the stability, defect behavior, electronic band structure, and optical absorption in…

Materials Science · Physics 2023-09-29 Jiaqi Yang , Arun Mannodi-Kanakkithodi

Recently, the coupling of ferroelectrics with electrochemical reactions has attracted increasing interest for harvesting waste heat. The change of polarisation of a ferroelectric with temperature can be used to influence chemical reactions,…

The hybrid perovskites are coordination frameworks with the same topology as the inorganic perovskites, but with properties driven by different chemistry, including host-framework hydrogen bonding. Like the inorganic perovskites, these…

In recent years, hybrid organic-inorganic metal halides have been at the forefront of materials research. Typically, the functional (e.g., optoelectronic) properties of hybrid halides are derived from the inorganic structural part, whereas…