Related papers: The pyrochlore Ho2Ti2O7: Synthesis, crystal growth…
The high-pressure optical floating-zone method enables single crystal growth of the Pmnb high-temperature phase of Li2FeSiO4. The influence of growth conditions on crystal quality, phase homogeneity, and impurity formation in Li2FeSiO4 is…
We investigate sputtering of a Ti3SiC2 compound target at temperatures ranging from RT (no applied external heating) to 970 oC as well as the influence of the sputtering power at 850 oC for the deposition of Ti3SiC2 films on Al2O3(0001)…
The (001)SrTiO3 crystal surface can be engineered to display a self-organized pattern of well-separated and nearly pure single-terminated SrO and TiO2 regions by high temperature annealing in oxidizing atmosphere. By using surface sensitive…
Both amorphous and crystalline materials frequently exhibit low temperature specific heats in excess of what is predicted using the Debye model. The signature of this excess specific heat is a peak observed in $C/T^3$ \textit{versus} $T$.…
Large high-quality single crystals of Bi2Sr2Can-1CunO2n+4+d (n = 2, 3) were successfully grown using an improved traveling solvent floating zone (TSFZ) method, which features a slow growth rate and steep temperature gradient along the…
There are reasons to believe that the ground state of the magnetic rare earth pyrochlore Yb$_2$Ti$_2$O$_7$ is on the boundary between competing ground states. We have carried out $\mathrm{\textit{ab initio}}$ density functional calculations…
We present time-of-flight inelastic neutron scattering measurements at low temperature on powder samples of the magnetic pyrochlore oxides Tb2Ti2O7 and Tb2Sn2O7. These two materials possess related, but different ground states, with…
We report the crystal growth, crystal structure and basic magnetic properties of a new cobalt-based pyrochlore, NaSrCo$_2$F$_7$. Na and Sr are completely disordered on the non-magnetic large atom A sites, while magnetic S=3/2 Co$^{2+}$…
We report structural and magnetic properties studies of large high quality single-crystals of the frustrated magnet, Nd$_2$Zr$_2$O$_7$. Powder x-ray diffraction analysis confirms that Nd$_2$Zr$_2$O$_7$ adopts the pyrochlore structure.…
Ti-O nanoparticles have been synthesized via hollow cathode sputtering in an Ar-O2 atmosphere using high power pulsing. It is shown that the stoichiometry and the size of the nanoparticles can be varied independently, the former through…
While pyrochlore iridate thin films are theoretically predicted to possess a variety of emergent topological properties, experimental verification of these predictions can be obstructed by the challenge in thin film growth. Here we report…
We report on a study of the inelastic scattering properties of (001) and (111) Ho$_2$Ti$_2$O$_7$ single crystals at room temperature. Structural and compositional analysis along with absorption measurement confirms single crystalline phase…
The nature of the low temperature ground state of the pyrochlore compound Tb2Ti2O7 remains a puzzling issue. Dynamic fluctuations and short-range correlations persist down to 50 mK, as evidenced by microscopic probes. In parallel,…
The methodology of single crystal growth of metastable $\beta$-Ti alloy TIMETAL LCB in an optical floating zone furnace is presented in this paper. Chemical compositions of both precursor material and single crystals were checked. It was…
Single crystals of KOs2O6 have been grown in a sealed quartz ampoule. Detailed single crystal X-ray diffraction studies at room temperature show Bragg peaks that violate Fd-3m symmetry. With a comparative structure refinement the structure…
Tb2Ti2O7 is a pyrochlore antiferromagnet that has dynamical spins and only short-range correlations even at 50 mK; the lowest temperature explored so far, which is much smaller than the scale set by the Curie-Weiss temperature T_{CW}~14 K.…
This study aimed primarily at completing and extending the characterization of the crystallographic, spectroscopic and optical properties of polar, biaxial, optically negative 2-aminopyrimidinium(1+) hydrogen phosphite. Besides the…
The pyrochlore material $\rm Ho_{2}Ti_{2}O_{7}$ has been suggested to show ``spin ice'' behaviour. We present neutron scattering and specific heat results that establish unambiguously that Ho$_2$Ti$_2$O$_7$ exhibits spin ice correlations at…
Here we demonstrate the floating zone crystal growth of the $J_\mathrm{eff}=1/2$ Mott insulator Sr$_2$IrO$_4$. Historically, the growth of iridates from a ternary melt has been precluded by the extreme vapor pressure of the metal oxide…
The phonon and crystal field excitations in several rare earth titanate pyrochlores are investigated. Magnetic measurements on single crystals of Gd2Ti2O7, Tb2Ti2O7, Dy2Ti2O7 and Ho2Ti2O7 are used for characterization, while Raman…