Related papers: The pyrochlore Ho2Ti2O7: Synthesis, crystal growth…
We report the anisotropic magnetic properties of Ho2Ge2O7 determined from dc and ac magnetization, specific heat and powder neutron diffraction experiments. The magnetic lanthanide sublattice, seen in our refinement of the tetragonal…
Bi$_2$Sr$_{2-x}$La$_x$CuO$_{6+\delta}$ (0$\leq x \leq$1.00) single crystals with high-quality have been grown successfully using the travelling-solvent floating-zone technique. The patterns of X-ray diffraction suggest high crystalline…
We report a detailed study of structural and magnetic properties of the pyrochlore-type (Bi2-xPrx)Ru2O7 series. Eleven compositions with 0 <= x <= 2 were prepared by solid state reaction at 1050 degrees C and found to form a solid solution…
High-quality single crystals are essentially needed for the investigation of the novel bulk properties of unconventional superconductors. The availability of such crystals grown by the floating-zone method has helped to unveil the…
A comprehensive study of the structural properties of the heavily investigated rare-earth A2Ir2O7 series under extreme conditions is presented. The series is covered by studying iridates with A = Pr, Sm, Dy-Lu. Temperature- and…
The pyrochlore compounds Ho2Ti2O7 and Dy2Ti2O7 show an exotic form of magnetism called the spin ice state, resulting from the interplay between geometrical frustration and ferromagnetic coupling. A fascinating feature of this state is the…
Crystal growth experiments (micro-pulling down or Czochralski methods, respectively) and DTA/TG measurements with Fe2+ containing olivines (fayalite--forsterite solid solution) and with FeO (wustite) are performed. For both substances the…
We report on the synthesis of LiCrTe$_2$ single crystals and on their anisotropic magnetic properties. We have obtained these single crystals by employing a Te/Li-flux synthesis method. We find LiCrTe$_2$ to crystallize in a TlCdS$_2$ -type…
In this work we present a neutron Larmor diffraction study of the rare earth pyrochlores $R_2$Ti$_2$O$_7$, with $R$ = Tb, Dy, Ho. We measured the temperature dependence of the lattice parameter with precision $10^{-5}$, between 0.5 K and…
We discuss the important aspects of synthesis and crystal growth of MgB2 under high pressure (P) and temperature (T) in Mg-B-N system, including the optimisation of P-T conditions for reproducible crystal growth, the role of liquid phases…
The layered delafossite-like antiferromagnet AgCrSe$_2$ is a superionic conductor at high temperatures and has been reported to exhibit anomalous Hall behavior and Kondo physics at low temperatures. These extraordinary transport properties…
High resolution X-ray scattering measurements on single crystal Tb2Ti2O7 reveal finite structural correlations at low temperatures. This geometrically frustrated pyrochlore is known to exhibit a spin liquid, or cooperative paramagnetic…
We have investigated the atomically-resolved substrate and homoepitaxial thin film surfaces of SrTiO3(001) using low-temperature scanning tunneling microscopy/spectroscopy (STM/STS) combined with pulsed laser deposition (PLD). It was found…
The Tb$_2$Ti$_2$O$_7$ pyrochlore magnetic material is attracting much attention for its {\em spin liquid} state, failing to develop long range order down to 50 mK despite a Curie-Weiss temperature $\theta_{\rm CW} \sim -14$ K. In this paper…
The synthesis and characterization of the pyrochlore solid solutions, Y2Ti2-xNbxO7-y, Lu2Ti2-xNbxO7-y, Y2Ti2-xTaxO7-y and Lu2TiTaO7-y (-0.4<y<0.5), is described. Synthesis at 1600 C, and 10-5 Torr yields oxygen deficiency in all systems.…
Temperature-dependent crystallographic and magnetic studies on stoichiometric single crystals of LiCu2O2 are reported. The magnetic properties are similar to earlier findings demonstrating antiferromagnetic ordering below 25 K. Evidence of…
The oxide pyrochlore Bi$_2$Ti$_2$O$_7$ is in some ways analogous to perovskite PbTiO$_3$, in that Bi$_2$Ti$_2$O$_7$ has two cations, Bi$^{3+}$ and Ti$^{4+}$ in oxidation states that are normally associated with a propensity to off-center.…
Over the past two decades, the magnetic ground states of all rare earth titanate pyrochlores have been extensively studied, with the exception of Sm$_2$Ti$_2$O$_7$. This is, in large part, due to the very high absorption cross-section of…
A single crystal of lead-zirconate-titanate (PZT), composition Pb(Zr0.80Ti0.20)O3, was studied by polarized-Raman scattering as a function of temperature. Raman spectra reveal that the local structure deviates from the average structure in…
The presence of small hematite (Fe2O3) clusters at low coverage on titanium dioxide (TiO2) surface has been observed to enhance photocatalytic activity, while excess loading of hematite is detrimental. We conduct a comprehensive density…