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Using the IRAM 30m telescope, we mapped the methanol emission in the pre-stellar core L1544 and observed singly deuterated methanol (CH$_2$DOH and CH$_3$OD) towards the dust peak of L1544. Non-LTE radiative transfer modelling was performed…

Solar and Stellar Astrophysics · Physics 2014-09-17 Luca Bizzocchi , Paola Caselli , Silvia Spezzano , Elvira Leonardo

We present the first census of the interstellar Complex Organic Molecules (iCOMs) in the low-mass Class I protostar SVS13-A, obtained by analysing data from the IRAM-30m Large Project ASAI (Astrochemical Surveys At IRAM). They consist of an…

We report the first detection of doubly-deuterated methanol (CHD2OH), as well as firm detections of the two singly-deuterated isotopomers of methanol (CH2DOH and CH3OD), towards the solar-type protostar IRAS16293-2422. From the present…

We studied the line emission from CH3CN and its deuterated isotopologue CH$_2$DCN towards the prototypical Class I object SVS13-A, where the deuteration of a large number of species has already been reported. Our goal is to measure the…

HH212, a nearby (400 pc) object in Orion, is a Class 0 protostellar system with a Keplerian disk and collimated bipolar SiO jets. Deuterated water, HDO and a deuterated complex molecule, methanol (CH2DOH) have been reported in the source.…

Astrophysics of Galaxies · Physics 2018-02-07 Dipen Sahu , Young-Chol Minh , Chin-Fei Lee , Sheng-Yuan Liu , Ankan Das , Sandip K. Chakrabarti , Bhala Sivaraman

Deuterated methanol is one of the most robust windows astrochemists have on the individual chemical reactions forming deuterium-bearing molecules and the physicochemical history of the regions where they reside. The first-time detection of…

The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…

Solar and Stellar Astrophysics · Physics 2015-12-02 A. Faure , M. Faure , P. Theulé , E. Quirico , B. Schmitt

Water and methanol are key components of interstellar ices and gas in star- and planet-forming regions, but direct observations of water in low-mass protostars are challenging due to atmospheric absorption. We present high-resolution (R =…

Recent observations indicate that organic molecules are prevalent towards starless and prestellar cores. Deuteration of these molecules has not been well-studied during the starless phase. Published observations of singly-deuterated…

Astrophysics of Galaxies · Physics 2020-12-02 Hannah E. Ambrose , Yancy L. Shirley , Samantha Scibelli

Deuterium fractionation, as studied through mono-deuterated methanol, is frequently used as a diagnostic tool to trace the physical conditions and chemical evolution of interstellar sources. This study investigates methanol deuteration in…

Solar and Stellar Astrophysics · Physics 2025-06-10 Shaoshan Zeng , Jae-Hong Jeong , Takahiro Oyama , Jeong-Eun Lee , Yao-Lun Yang , Nami Sakai

We report the first high angular resolution imaging (3.4\arcsec $\times$ 3.0\arcsec) of deuterated formaldehyde (HDCO) toward Orion--KL, carried out with the Submillimeter Array (SMA). We find that the spatial distribution of the…

Astrophysics of Galaxies · Physics 2015-08-06 Cecile Favre , Edwin Bergin , Justin Neill , Nathan Crockett , Qizhou Zhang , Dariusz Lis

Deuterated molecules have been detected and studied toward Orion BN/KL in the past decades, mostly with single-dish telescopes. However, high angular resolution data are critical not only for interpreting the spatial distribution of the…

Astrophysics of Galaxies · Physics 2015-06-05 T. -C. Peng , D. Despois , N. Brouillet , B. Parise , A. Baudry

The formation of singly and doubly deuterated isotopomers of formaldehyde and of singly, doubly, and multiply deuterated isotopomers of methanol on interstellar grain surfaces has been studied with a semi-empirical modified rate approach…

Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…

Solar and Stellar Astrophysics · Physics 2015-05-28 S. Cazaux , P. Caselli , M. Spaans

Deuterium fractionation is highly efficient during the early stages of star formation, particularly in starless and prestellar cores where temperatures are low (<10 K) and molecular freeze-out onto dust grains is significant. Methanol forms…

Deuteration is a powerful tracer of the history of the cold prestellar phase in star forming regions. Apart from methanol, little is known about deuterium fractionation of complex organic molecules in the interstellar medium, especially in…

Astrophysics of Galaxies · Physics 2016-05-31 A. Belloche , H. S. P. Müller , R. T. Garrod , K. M. Menten

High deuterium fractionation is observed in various types of environment such as prestellar cores, hot cores and hot corinos. It has proven to be an efficient probe to study the physical and chemical conditions of these environments. The…

Astrophysics of Galaxies · Physics 2015-05-18 Karine Demyk , S. Bottinelli , Emmanuel Caux , Charlotte Vastel , Cecilia Ceccarelli , Claudine Kahane , Alain Castets

The study of hot corinos in Solar-like protostars has been so far mostly limited to the Class 0 phase, hampering our understanding of their origin and evolution. In addition, recent evidence suggests that planet formation starts already…

Accurate quantification of the column density of di-deuterated methanol is a key missing puzzle piece in the otherwise thoroughly constrained family of D-bearing methanol in the deeply embedded low-mass protostellar system and astrochemical…

Methanol (CH$_3$OH) and formaldehyde (H$_2$CO) are chemically coupled organic molecules proposed to act as an intermediate step between simple molecules and more complex prebiotic compounds. Their abundance distributions across disks…