CH$_3$CN deuteration in the SVS13-A Class I hot-corino. SOLIS XV
Abstract
We studied the line emission from CH3CN and its deuterated isotopologue CHDCN towards the prototypical Class I object SVS13-A, where the deuteration of a large number of species has already been reported. Our goal is to measure the CHCN deuteration in a Class I protostar, for the first time, in order to constrain the CHCN formation pathways and the chemical evolution from the early prestellar core and Class 0 to the evolved Class I stages. We imaged CH2DCN towards SVS13-A using the IRAM NOEMA interferometer at 3mm in the context of the Large Program SOLIS (with a spatial resolution of 1.8"x1.2"). The NOEMA images have been complemented by the CHCN and CHDCN spectra collected by the IRAM-30m Large Program ASAI, that provided an unbiased spectral survey at 3mm, 2mm, and 1.3mm. The observed line emission has been analysed using LTE and non-LTE LVG approaches. The NOEMA/SOLIS images of CH2DCN show that this species emits in an unresolved area centered towards the SVS13-A continuum emission peak, suggesting that methyl cyanide and its isotopologues are associated with the hot corino of SVS13-A, previously imaged via other iCOMs. In addition, we detected 41 and 11 ASAI transitions of CHCN and CH2DCN, respectively, which cover upper level energies (Eup) from 13 to 442 K and from 18 K to 200 K, respectively. The derived [CH2DCN]/[CH3CN] ratio is 9\%. This value is consistent with those measured towards prestellar cores and a factor 2-3 higher than those measured in Class 0 protostars. Contrarily to what expected for other molecular species, the CH3CN deuteration does not show a decrease in SVS13-A with respect to measurements in younger prestellar cores and Class 0 protostars. Finally, we discuss why our new results suggest that CH3CN was likely synthesised via gas-phase reactions and frozen onto the dust grain mantles during the cold prestellar phase.
Cite
@article{arxiv.2202.09285,
title = {CH$_3$CN deuteration in the SVS13-A Class I hot-corino. SOLIS XV},
author = {Eleonora Bianchi and Cecilia Ceccarelli and Claudio Codella and Ana López-Sepulcre and Satoshi Yamamoto and Nadia Balucani and Paola Caselli and Linda Podio and Roberto Neri and Rafael Bachiller and Cécile Favre and Francesco Fontani and Bertrand Lefloch and Nami Sakai and Dominique Segura-Cox},
journal= {arXiv preprint arXiv:2202.09285},
year = {2022}
}
Comments
20 pages, 2 tables, 12 figures