Using the IRAM 30m telescope, we mapped the methanol emission in the pre-stellar core L1544 and observed singly deuterated methanol (CH2DOH and CH3OD) towards the dust peak of L1544. Non-LTE radiative transfer modelling was performed on three CH3OH emissions lines at 96.7 GHz, using a Bonnor-Ebert sphere as a model for the source. We have also assumed a centrally decreasing abundance profile to take the molecule freeze-out in the inner core into account. The column density of CH2DOH was derived assuming LTE excitation and optically thin emission. The CH3OH emission has a highly asymmetric morphology, resembling a non-uniform ring surrounding the dust peak, where CO is mainly frozen onto dust grains. The observations provide an accurate measure of methanol deuteration in the cold pre-stellar gas. The derived abundance ratio is [CH2DOH]/[CH3OH] =0.10±0.03, which is significantly smaller than the ones found in low-mass Class 0 protostars and smaller than the deuterium Fraction measured in other molecules towards L1544. The low deuterium fractionation observed in L1544 and the morphology of the CH3OH emission suggest that we are mainly tracing the outer parts of the core, where CO just started to freeze-out onto dust grains.
@article{arxiv.1408.2491,
title = {Deuterated methanol in the pre-stellar core L1544},
author = {Luca Bizzocchi and Paola Caselli and Silvia Spezzano and Elvira Leonardo},
journal= {arXiv preprint arXiv:1408.2491},
year = {2014}
}