Related papers: Decrease of the organic deuteration during the evo…
We have measured the deuterium fractionation (through the column density ratio N(N2D+)/N(N2H+)) and the CO depletion factor (ratio between expected and observed CO abundance) in a sample of 10 high-mass protostellar candidates, in order to…
Extremely large deuteration of several molecules has been observed towards prestellar cores and low-mass protostars for a decade. New observations performed towards low-mass protostars suggest that water presents a lower deuteration in the…
Water in outflows from protostars originates either as a result of gas-phase synthesis from atomic oxygen at T > 200 K, or from sputtered ice mantles containing water ice. We aim to quantify the contribution of the two mechanisms that lead…
Based on recent work, formamide might be a potentially very important molecule in the emergence of terrestrial life. Although detected in the interstellar medium for decades, its formation route is still debated, whether in the gas phase or…
Deuterated molecules are good tracers of the evolutionary stage of star-forming cores. During the star formation process, deuterated molecules are expected to be enhanced in cold, dense pre-stellar cores and to deplete after protostellar…
Aim: In the past, observations of protostellar shocks have been able to set constraints on the formation route of formamide (NH2CHO), exploiting its observed spatial distribution and comparison with astrochemical model predictions. In this…
The [HDO]/[H2O] ratio is a crucial parameter for probing the history of water formation. So far, it has been measured for only three solar type protostars and yielded different results, possibly pointing to a substantially different history…
We present a survey of the formaldehyde emission in nine class 0 protostars obtained with the IRAM 30m and the JCMT millimeter telescopes. Using a detailed radiative transfer code of the envelopes surrounding the protostars, we show that…
Context. Millimetric observations have measured high degrees of molecular deuteration in several species seen around low-mass protostars. The Herschel Space Telescope, launched in 2009, is now providing new measures of the deuterium…
Formaldehyde is a key precursor in the formation routes of many complex organic molecules (COMs) in space. It is also an intermediate step in CO hydrogenation sequence that leads to methanol formation on the surface of interstellar grains…
Cold cores are an early step of star formation, characterized by densities > 10$^4$ cm$^{-3}$, low temperatures (< 15 K), and very low external UV radiation. We investigate the physico-chemical processes at play to tracing the origin of…
We use spectra and maps of NH2D, ND2H, and ND3, obtained with the CSO, IRAM 30m and Arecibo telescopes, to study deuteration processes in dense cores. The data include the first detection of the hyperfine structure of ND2H. The emission of…
The formation of deuterated molecules is favoured at low temperatures and high densities. Therefore, the deuteration fraction D$_{frac}$ is expected to be enhanced in cold, dense prestellar cores and to decrease after protostellar birth.…
Clouds of high infrared extinction are promising sites of massive star/cluster formation. A large number of cloud cores discovered in recent years allows investigation of possible evolutionary sequence among cores in early phases. We have…
We have observed the $^{13}$CH$_3$OH $5_1-4_1$ A$^+$, $^{13}$CH$_3$OH $14_1-13_2$ A$^-$, and CH$_2$DOH $8_{2,6}-8_{1,7}$ $e_0$ lines toward 24 high-mass star-forming regions by using Atacama Large Millimeter/submillimeter Array (ALMA) with…
The deuterium fractionation of water can serve as a tracer for the chemical and physical evolution of water during star formation and can constrain the origin of water in Solar System bodies. We determine the HDO/H$_2$O ratio in the inner…
We present ground-based 2.1 to 4.2 microns observations of four low-mass protostars. We searched for the 4.1 microns OD stretch band, characteristic of solid HDO in grain mantles. We did not detect solid HDO in any of the four sources, but…
We report ALMA high-angular resolution (~ 50 au) observations of the binary system SVS13-A. More specifically, we analyse deuterated water (HDO) and sulfur dioxide (SO2) emission. The molecular emission is associated with both the…
We present observations of HDCO and H2CO emission toward a sample of 15 Class 0 protostars in the Orion A and B clouds. Of these, eleven protostars are Herschel-identified PACS Bright Red Sources (PBRS) and four are previously identified…
The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…