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Magnetic relaxation in coordination compounds is largely dominated by the interaction of the spin with phonons. Large zero-field splitting and exchange coupling values have been empirically found to strongly suppress spin relaxation and…

The spin relaxation in the molecular magnet \Mn12 is investigated by a novel type of high-frequency magnetic spectroscopy. By reversing the external magnetic field the intensities of the $|\pm 10>\to |\pm 9>$ transitions within the ground…

Strongly Correlated Electrons · Physics 2016-08-31 M. Dressel , B. Gorshunov , K. Rajagopal , S. Vongtragool , A. A. Mukhin

We present a first-principles investigation of spin-phonon relaxation in a molecular crystal of Co(II) single-ion magnets. Our study combines electronic structure calculations with machine-learning force fields and unravels the nature of…

Materials Science · Physics 2020-05-27 Alessandro Lunghi , Stefano Sanvito

Recent experimental investigations of individual magnetic nanoparticles reveal a diverse range of magnetic relaxation times which cannot be explained by considering their size, shape, and surface anisotropy, suggesting other factors…

Mesoscale and Nanoscale Physics · Physics 2024-07-08 Hugo Bocquet , Armin Kleibert , Peter M. Derlet

Time crystals, a unique non-equilibrium quantum phenomenon with promising applications in current quantum technologies, mark a significant advance in quantum mechanics. Although traditionally studied in atom-cavity and optical lattice…

Quantum Physics · Physics 2024-10-07 Subhajit Sarkar , Yonatan Dubi

Numerical modelling of coherent spin relaxation in nanomagnets, formed by magnetic molecules of high spins, is accomplished. Such a coherent spin dynamics can be realized in the presence of a resonant electric circuit coupled to the magnet.…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 V. I. Yukalov , V. K. Henner , P. V. Kharebov

Single-chain magnets are molecular spin chains displaying slow relaxation of the magnetisation on a macroscopic time scale. To this similarity with single-molecule magnets they own their name. In this chapter the distinctive features of…

Strongly Correlated Electrons · Physics 2014-02-04 Dante Gatteschi , Alessandro Vindigni

Many estimates for the magnetic relaxation time of magnetic nanoparticle systems neglect the effect of the applied field strength. This is despite many applications of magnetic nanoparticles involving relaxation dynamics under the influence…

Mesoscale and Nanoscale Physics · Physics 2024-06-19 Jonathon C. Davidson , Nicholas R. Anderson , Karen L. Livesey

A magnetic particle with atomic spins ordered in an unstable direction is an example of a false vacuum that decays via excitation of internal spin waves. Coupled evolution of the particle's magnetization (or the vacuum state) and spin…

Statistical Mechanics · Physics 2008-05-05 D. A. Garanin , H. Kachkachi , L. Reynaud

The nuclear magnetic relaxation in scandium metal is investigated at liquid helium temeprature for both single crystal and powder samples. The obtained temperature and field dependence of the Korringa constant are described by the means of…

The Raman exponent of single-molecular magnetic relaxation may take various unexpected values because of rich phonon spectrum and spin-phonon coupling of molecular crystals. We systematically examine the origins of different abnormalities,…

Materials Science · Physics 2021-01-13 Lei Gu , Ruqian Wu

We present a newly developed scheme for atomic relaxations of magnetic supported clusters. Our approach is based on the full potential Korringa-Kohn-Rostoker Green's function method and the second moment tight-binding approximation for…

Materials Science · Physics 2007-05-23 V. S. Stepanyuk , A. L. Klavsyuk , L. Niebergall , A. M. Saletsky , W. Hergert , P. Bruno

As the ability to generate magnetic anisotropy in molecular materials continues to hit new milestones, concerted effort has shifted towards understanding, and potentially controlling, the mechanisms of magnetic relaxation across a large…

Chemical Physics · Physics 2019-07-16 Jeremy D. Hilgar , Aaron K. Butts , Jeffrey D. Rinehart

The temperature dependences of spin-lattice relaxation time $T_1$ of $^{133}$Cs in CsFeCl$_3$ and $^{87}$Rb in RbFeCl$_3$ were measured in the temperature range between 1.5 K and 22 K, at various fields up to 7 T applied parallel (or…

Materials Science · Physics 2009-11-07 Mitsuru Toda , Takao Goto , Meiro Chiba , Naoshi Suzuki

The interaction of coherent magnetization rotation with a system of two-level impurities is studied. Two different, but not contradictory mechanisms, the `slow-relaxing ion' and the `fast-relaxing ion' are utilized to derive a system of…

Condensed Matter · Physics 2009-10-31 Vladimir L. Safonov , H. Neal Bertram

Magnetic relaxation in large spin molecular paramagnets is often found to behave as the square root of time at short times t. This behaviour was explained by Prokofiev & Stamp as arising from dipole interactions between molecular spins.…

Statistical Mechanics · Physics 2009-11-11 Jacques Villain

A new mechanism for relaxing the nuclear magnetic moments, in which a pair of spin-polarized BCS quasiparticles is emitted or absorbed, and which dominates at low temperature, is identified in type-II d-wave superconductors in an external…

Superconductivity · Physics 2010-03-29 Robert E. Throckmorton , Oskar Vafek

The preparation and physical characterization are reported for several single-molecule magnet salts to investigate the effects of paramagnetic cations on the magnetization relaxation behavior of [Mn12]- anionic single-molecule magnets.

We argue that to explain recent resonant tunneling experiments on crystals of Mn$_{12}$ and Fe$_8$, particularly in the low-T limit, one must invoke dynamic nuclear spin and dipolar interactions. We show the low-$T$, short-time relaxation…

Condensed Matter · Physics 2009-10-30 Nikolai Prokof'ev , Philip Stamp

The description of the tunneling of a macroscopic variable in the presence of a bath of localized spins is a subject of great fundamental and practical interest, and is relevant for many solid-state qubit designs. Instead of focusing on the…

Mesoscale and Nanoscale Physics · Physics 2007-12-05 Andrea Morello , L. J. de Jongh