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We give a perturbative analysis of Crooks relation and Jarzynski equality in an arbitrary driven quantum system weakly coupled to a heat bath. Invoking no efficient Hamiltonian nor any restriction on the form of the coupling, we derive the…

Statistical Mechanics · Physics 2017-09-15 Yi Peng , Heng Fan

We study how Thomson's formulation of the second law: no work is extracted from an equilibrium ensemble by a cyclic process, emerges in the quantum situation through the averaging over fluctuations of work. The latter concept is carefully…

Statistical Mechanics · Physics 2007-05-23 A. E. Allahverdyan , Th. M. Nieuwenhuizen

Fluctuation theorems are fundamental results in nonequilibrium thermodynamics beyond the linear response regime. Among these, the paradigmatic Tasaki-Crooks fluctuation theorem relates the statistics of the works done in a forward…

Statistical Mechanics · Physics 2024-06-19 Gianluca Francica , Luca Dell'Anna

The validity of the Jarzynski equation for a very simple, exactly solvable quantum system is analyzed. The implications of two different definitions of work proposed in the literature are investigated. The first one derives from…

Statistical Mechanics · Physics 2009-11-11 A. Engel , R. Nolte

This chapter reviews an information theoretic approach to deriving quantum fluctuation theorems. When a thermal system is driven from equilibrium, random quantities of work are required or produced: the Crooks equality is a classical…

Quantum Physics · Physics 2019-05-01 Z. Holmes

We investigate the connection between recent results in quantum thermodynamics and fluctuation relations by adopting a fully quantum mechanical description of thermodynamics. By including a work system whose energy is allowed to fluctuate,…

Quantum Physics · Physics 2017-03-27 Álvaro M. Alhambra , Lluis Masanes , Jonathan Oppenheim , Christopher Perry

The concept of work is basic for statistical thermodynamics. To gain a fuller understanding of work and its (quantum) features, it needs to be represented as an average of a fluctuating quantity. Here I focus on the work done between two…

Statistical Mechanics · Physics 2015-06-19 A. E. Allahverdyan

One of the most important goals in quantum thermodynamics is to demonstrate advantages of thermodynamic protocols over their classical counterparts. For that, it is necessary to (i) develop theoretical tools and experimental set-ups to deal…

Quantum Physics · Physics 2019-05-01 Elisa Bäumer , Matteo Lostaglio , Martí Perarnau-Llobet , Rui Sampaio

The work is a concept of fundamental importance in thermodynamics. An open question is how to describe the work fluctuation for quantum coherent processes in the presence of initial quantum coherence in the energy basis. With the aim of…

Quantum Physics · Physics 2022-01-05 Gianluca Francica

The free-energy difference $\Delta F$ between two high-dimensional systems is notoriously difficult to compute, but very important for many applications, such as drug discovery. We demonstrate that an unconventional definition of work…

Soft Condensed Matter · Physics 2024-10-24 Adrianne Zhong , Benjamin Kuznets-Speck , Michael R. DeWeese

We reconsider a well-known relationship between the fluctuation theorem and the second law of thermodynamics by evaluating a probability measure-valued process. In order to establish a bridge between microscopic and macroscopic behaviors,…

Statistical Mechanics · Physics 2015-03-19 Yuki Sughiyama , Masayuki Ohzeki

We present a generalization of Jarzynski's Equality, applicable to quantum systems, relating discretized mechanical work and free-energy changes. The theory is based on a step-wise pulling protocol. We find that work distribution functions…

Quantum Physics · Physics 2012-09-21 Van A. Ngo , Stephan Haas

In this Letter we investigate the concept of quantum work and its measurability from the viewpoint of quantum measurement theory. Very often, quantum work and fluctuation theorems are discussed in the framework of projective two-point…

Quantum Physics · Physics 2022-08-11 Konstantin Beyer , Roope Uola , Kimmo Luoma , Walter T. Strunz

Fluctuation theorems are relations constraining the out-of-equilibrium fluctuations of thermodynamic quantities like the entropy production that were initially introduced for classical or quantum systems in contact with a thermal bath. Here…

Quantum Physics · Physics 2019-02-27 Sreenath K. Manikandan , Cyril Elouard , Andrew N. Jordan

Quantum work fluctuation theorem (FT) commonly requires the system initially prepared in an equilibrium state. Whether there exists universal exact quantum work FT for initial state beyond equilibrium needs further discussions. Here, I…

Statistical Mechanics · Physics 2024-01-12 Bao-Ming Xu

Understanding and manipulating work fluctuations in microscale and nanoscale systems are of both fundamental and practical interest. For example, in considering the Jarzynski equality $\langle e^{-\beta W} \rangle=e^{-\beta \Delta F}$, a…

Statistical Mechanics · Physics 2015-08-26 Gaoyang Xiao , Jiangbin Gong

We propose a definition of externally measurable quantum work in driven systems. Work is given as a quantum observable on a control device which is forcing the system and can be determined without knowledge of the system Hamiltonian…

Quantum Physics · Physics 2020-10-07 Konstantin Beyer , Kimmo Luoma , Walter T. Strunz

Recently there has been growing interest in extending the thermodynamic method from static configurations to dynamical trajectories. In this approach, ensembles of trajectories are treated in an analogous manner to ensembles of…

Statistical Mechanics · Physics 2016-08-23 Robert M. Turner , Thomas Speck , Juan P. Garrahan

We propose a method to evaluate general thermodynamic fluctuations in open quantum systems, based on performing a two-point measurement scheme on the system using dynamics-dependent thermodynamic observables. Our approach allows one to…

Quantum Physics · Physics 2026-04-30 Alessandra Colla , Andrea Smirne , Heinz-Peter Breuer , Bassano Vacchini

In this study, we rederive the fluctuation theorems in presence of feedback, by assuming the known Jarzynski equality and detailed fluctuation theorems. We first reproduce the already known work theorems for a classical system, and then…

Statistical Mechanics · Physics 2015-05-30 Sourabh Lahiri , Shubhashis Rana , A. M. Jayannavar