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A result of great theoretical and experimental interest, Jarzynski equality predicts a free energy change $\Delta F$ of a system at inverse temperature $\beta$ from an ensemble average of non-equilibrium exponential work, i.e., $\langle…

Statistical Mechanics · Physics 2017-10-18 Juan D. Jaramillo , Jiawen Deng , Jiangbin Gong

We define common thermodynamic concepts purely within the framework of general Markov chains and derive Jarzynski's equality and Crooks' fluctuation theorem in this setup. In particular, we regard the discrete time case that leads to an…

Statistical Mechanics · Physics 2022-12-14 Pedro Hack , Sebastian Gottwald , Daniel A. Braun

Thermodynamics constrains changes to the energy of a system, both deliberate and random, via its first and second laws. When the system is not in equilibrium, fluctuation theorems such as the Jarzynski equality further restrict the…

We study the thermodynamics of quantum projective measurements by using the set up for the Jarzynski equality. We prove the fluctuations of energy change induced by measurements satisfy the Jarzynski equality, revealing that the quantum…

Statistical Mechanics · Physics 2015-08-31 Juyeon Yi , Yong Woon Kim

When a thermally isolated system performs a driving process in the quasistatic regime, its variation of average energy is equal to its quasistatic work. Even though presenting this simple definition, few attempts have been made to describe…

Statistical Mechanics · Physics 2025-02-17 Pierre Nazé

An open question of fundamental importance in thermodynamics is how to describe the fluctuations of work for quantum coherent processes. In the standard approach, based on a projective energy measurement both at the beginning and at the end…

Fluctuation theorems provide universal constraints on nonequilibrium energy and entropy fluctuations, making them a natural framework to assess how and to what extent quantum resources become thermodynamically relevant. We develop a unified…

Quantum Physics · Physics 2025-12-19 Sukrut Mondkar , Sayan Mondal , Ujjwal Sen

Firstly the fluctuation theorems (FT) for expended work in a driven nonequilibrium system, isolated or thermostatted, together with the ensuing Jarzynski work-energy (W-E) relationships, will be discussed and reobtained. Secondly, the…

Statistical Mechanics · Physics 2016-10-31 Carolyne M. Van Vliet

Previously derived expressions for the characteristic function of work performed on a quantum system by a classical external force are generalized to arbitrary initial states of the considered system and to Hamiltonians with degenerate…

Statistical Mechanics · Physics 2008-07-11 Peter Talkner , Peter Hanggi , Manuel Morillo

We study a Jarzysnki type equality for work in systems that are monitored using non-projective unsharp measurements. The information acquired by the observer from the outcome $f$ of an energy measurement, and the subsequent conditioned…

Quantum Physics · Physics 2025-12-22 Daniel Alonso , Antonia Ruiz García

Research on the out-of-equilibrium dynamics of quantum systems has so far produced important statements on the thermodynamics of small systems undergoing quantum mechanical evolutions. Key examples are provided by the Crooks and Jarzynski…

There are two related theorems which hold even in far from equilibrium, namely fluctuation theorem and Jarzynski equality. Fluctuation theorem states the existence of symmetry of fluctuation of entropy production, while Jarzynski equality…

Statistical Mechanics · Physics 2009-11-10 T. Monnai

Fluctuation theorems, such as the Jarzynski equality and the Crooks relation, are effective tools connecting non-equilibrium work statistics and equilibrium free energy differences. However, detailed hands-on, reproducible protocols for…

The standard definition of quantum fluctuating work is based on the two-projective energy measurement, which however does not apply to systems with initial quantum coherence because the first projective energy measurement destroys the…

Quantum Physics · Physics 2019-04-12 Rui Pan , Zhaoyu Fei , Tian Qiu , Jing-Ning Zhang , H. T. Quan

In this paper we give a pedagogical introduction to the ideas of quantum thermodynamics and work fluctuations, using only basic concepts from quantum and statistical mechanics. After reviewing the concept of work, as usually taught in…

Quantum Physics · Physics 2018-05-03 Wellington L. Ribeiro , Gabriel T. Landi , Fernando Semião

In this paper we aim at characterizing the effect of stochastic fluctuations on the distribution of the energy exchanged by a quantum system with an external environment under sequences of quantum measurements performed at random times.…

We derive the fluctuation theorem for quantum-state statistics that can be obtained when we initially measure the total energy of a quantum system at thermal equilibrium, let the system evolve unitarily, and record the quantum-state data…

Statistical Mechanics · Physics 2018-08-01 Naoto Tsuji , Masahito Ueda

At non-zero temperature classical systems exhibit statistical fluctuations of thermodynamic quantities arising from the variation of the system's initial conditions and its interaction with the environment. The fluctuating work, for…

Quantum Physics · Physics 2018-02-07 Rui Sampaio , Samu Suomela , Tapio Ala-Nissila , Janet Anders , Thomas Philbin

We consider the quantum mechanical generalization of Crooks Fluctuation Theorem and Jarzynski Equality for an open quantum system. The explicit expression for microscopic work for an arbitrary prescribed protocol is obtained, and the…

Statistical Mechanics · Physics 2008-12-31 H. T. Quan , H. Dong

The recently demonstrated robustness of fluctuation theorems against measurements [M. Campisi \emph{et al.}, Phys. Rev. Lett. \textbf{105} 140601 (2010)] does not imply that the probability distributions of nonequilibrium quantities, such…

Statistical Mechanics · Physics 2011-04-19 Michele Campisi , Peter Talkner , Peter Hänggi