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Redox-based memristive devices are among the alternatives for the next generation of non volatile memories, but also candidates to emulate the behavior of synapses in neuromorphic computing devices. It is nowadays well established that the…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Cristian Ferreyra , Wilson Román Acevedo , Ralph Gay , Diego Rubi , María José Sánchez

Oxygen vacancies (OV) are pervasive in metal oxides and play a pivotal role in the switching behaviour of oxide-based memristive devices. In this work we address, through a combination of experiments and theoretical simulations, OV dynamics…

Mesoscale and Nanoscale Physics · Physics 2024-06-21 C. Ferreyra , R. Leal Martir , D. Rubi , María José Sánchez

Multilevel resistance states in silver-manganite interfaces are studied both experimentally and through a realistic model that includes as a main ingredient the oxygen vacancies diffusion under applied electric fields. The switching…

Other Condensed Matter · Physics 2015-05-18 N. Ghenzi , M. J. Sanchez , F. Gomez-Marlasca , P. Levy , M. J. Rozenberg

Memristors are expected to be one of the key building blocks for the development of new bio-inspired nanoelectronics. Memristive effects in transition metal oxides are usually linked to the electromigration at the nanoscale of charged…

Ferroelectric memristors are intensively studied due to their potential implementation in data storage and processing devices. In this work we show that the memristive behavior of metal/ferroelectric oxide/metal devices relies on the…

Applied Physics · Physics 2020-10-28 C. Ferreyra , M. Rengifo , M. J. Sánchez , A. S. Everhard , B. Noheda , D. Rubi

We have extended our recent molecular-dynamic simulations of memristors to include the effect of thermal inhomogeneities on mobile ionic species appearing during operation of the device. Simulations show a competition between an attractive…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 S. E. Savel'ev , A. S. Alexandrov , A. M. Bratkovsky , R. Stanley Williams

Reversible bipolar nano-switches that can be set and read electronically in a solid-state two-terminal device are very promising for applications. We have performed molecular-dynamics simulations that mimic systems with oxygen vacancies…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 S. E. Savel'ev , A. S. Alexandrov , A. M. Bratkovsky , R. Stanley Williams

We introduce a model that accounts for the bipolar resistive switching phenomenom observed in transition metal oxides. It qualitatively describes the electric field-enhanced migration of oxygen vacancies at the nano-scale. The numerical…

Materials Science · Physics 2015-05-14 M. J. Rozenberg , M. J. Sanchez , R. Weht , C. Acha , F. Gomez-Marlasca , P. Levy

Migration of oxygen vacancies has been proposed to play an important role in the bipolar memristive behaviors since oxygen vacancies can directly determine the local conductivity in many systems. However, a recent theoretical work…

A possible mechanism for the resistive switching observed experimentally in Fe/MgO/V/Fe junctions is presented. Ab initio total energy calculations within the local density approximation and pseudopotential theory shows that by moving the…

Materials Science · Physics 2014-08-22 J. M. Aguiar-Hualde , M. Alouani

We model electrical conductivity in metastable amorphous $Ge_{2}Sb_{2}Te_{5}$ using independent contributions from temperature and electric field to simulate phase change memory devices and Ovonic threshold switches. 3D, 2D-rotational, and…

Applied Physics · Physics 2021-02-03 Jake Scoggin , Helena Silva , Ali Gokirmak

Combination of electric fields and Joule self-heating is used to change the oxygen stoichiometry and promote oxygen vacancy drift in a free-standing $\mathrm{(La,Sr)MnO_3}$ thin film microbridge placed in controlled atmosphere. By…

Strongly Correlated Electrons · Physics 2017-02-06 Nicola Manca , Luca Pellegrino , Daniele Marré

We present a theoretical study of the impact of oxygen diffusion in oxide crystals on metal dopants ionic state and the conduction type under dynamic changes. The slow changes under thermal equilibrium are provided in a companion, Part I…

Materials Science · Physics 2018-06-06 Misha Sinder , Zeev Burshtein , Joshua Pelleg

While the recent establishment of the role of thermophoresis/diffusion-driven oxygen migration during resistance switching in metal oxide memristors provided critical insights required for memristor modeling, extended investigations of the…

Memristive switching devices, candidates for resistive random access memory technology, have been shown to switch off through a progression of states with quantized conductance and subsequent non-integer conductance (in terms of conductance…

Mesoscale and Nanoscale Physics · Physics 2016-11-23 Xiaoliang Zhong , Ivan Rungger , Peter Zapol , Olle Heinonen

Understanding the role of defects in oxide heterostructures is crucial for future materials control and functionalization. We hence study the impact of oxygen vacancies (OVs) at variable concentrations on orbital- and spin exchange in the…

Materials Science · Physics 2015-10-13 Malte Behrmann , Frank Lechermann

We report on non-volatile memory devices based on multifunctional manganites. The electric field induced resistive switching of Ti/$La_{1/3}$$Ca_{2/3}$Mn$O_3$/n-Si devices is explored using different measurement protocols. We show that…

Materials Science · Physics 2016-06-20 W. Román Acevedo , D. Rubi , J. Lecourt , U. Lüders , F. Gomez-Marlasca , P. Granell , F. Golmar , P. Levy

Resistance Random Access Memory (RRAMTM) device, with its electrically induced nanoscale resistive switching capacity, has been gaining considerable attention as future non-volatile memory device. Here, we propose a mechanism of switching…

We present a theoretical study of the impact of oxygen diffusion in oxide crystals on metal dopants ionic state and the conduction type under thermal equilibrium. Oxygen vacancy formation acting as a shallow, double-electronic donor is…

Materials Science · Physics 2018-06-06 Misha Sinder , Zeev Burshtein , Joshua Pelleg

Electric pulse induced resistance (EPIR) switching hysteresis loops for Pr0.7Ca0.7MnO3 (PCMO) perovskite oxide films were found to exhibit an additional sharp "shuttle peak" around the negative pulse maximum for films deposited in an oxygen…

Strongly Correlated Electrons · Physics 2015-06-25 Y. B. Nian , J. Strozier , N. J. Wu , X. Chen , A. Ignatiev
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