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We report first ab initio relativistic correlation calculations of potential curves for ten low-lying electronic states, effective electric field on the electron and hyperfine constants for the ^3\Delta_1 state of cation of a heavy…

Atomic Physics · Physics 2013-05-29 A. N. Petrov , N. S. Mosyagin , T. A. Isaev , A. V. Titov

The energy splitings for $J = 1$, $F=3/2$, $|M_F|=3/2$ hyperfine levels of the $^3\Delta_1$ electronic state of $^{180}$Hf$^{19}$F$^+$ ion are calculated as functions of the external variable electric and magnetic fields within two…

Atomic Physics · Physics 2018-05-16 A. N. Petrov

We report ab initio relativistic correlation calculations of potential curves and spectroscopic constants for four lowest-lying electronic states of the lead monofluoride. We also calculated parameters of the spin-rotational Hamiltonian for…

Atomic Physics · Physics 2013-05-29 K. I. Baklanov , A. N. Petrov , A. V. Titov , M. G. Kozlov

Hyperfine structure of the ground rotational level of the metastable $^3\Delta_1$ electronic state of $^{180}$HfF$^+$ ion is calculated at presence of variable external electric and magnetic fields. Calculations are required for analysis of…

Atomic Physics · Physics 2023-12-14 Alexander N. Petrov

A number of extensions to the Standard Model of particle physics predict a permanent electric dipole moment of the electron (eEDM) in the range of the current experimental limits. Trapped ThF$^+$ will be used in a forthcoming generation of…

Atomic Physics · Physics 2015-12-09 Daniel N. Gresh , Kevin C. Cossel , Yan Zhou , Jun Ye , Eric A. Cornell

Precision spectroscopy of trapped HfF^+ will be used in a search for the permanent electric dipole moment of the electron (eEDM). While this dipole moment has yet to be observed, various extensions to the standard model of particle physics…

An excellent candidate molecule for the measurement of the electron's electric dipole moment (eEDM) is thorium monofluoride (ThF$^+$) because the eEDM-sensitive state, $^3\Delta_1$, is the electronic ground state, and thus is immune to…

We report the theoretical investigation of the suppression of magnetic systematic effects in HfF$^+$ cation for the experiment to search for the electron electric dipole moment. The g-factors for $J = 1$, $F=3/2$, $|M_F|=3/2$ hyperfine…

Atomic Physics · Physics 2017-08-09 A. N. Petrov , L. V. Skripnikov , A. V. Titov

We report the first results of ab initio relativistic correlation calculation of the effective electric field on the electron, E_eff, in the ground state of the HI$^+$ cation. This value is required for interpretation of the suggested…

Atomic Physics · Physics 2013-05-29 T. A. Isaev , N. S. Mosyagin , A. N. Petrov , A. V. Titov

The current constraint on the electron electric dipole moment ($e$EDM), $|d_e|<4.1\times 10^{-30}$ ${e {\cdotp} {\rm cm}}$ (90\% confidence), was recently established using the trapped $^{180}$Hf$^{19}$F$^+$ molecular ions in the $J=1$…

Atomic Physics · Physics 2023-05-16 Alexander N. Petrov , Leonid V. Skripnikov , Anatoly V. Titov

The observation of an electron electric dipole moment (eEDM) would have major ramifications for the standard model of physics. Polar molecules offer a near-ideal laboratory for such searches due to the large effective electric field (${\bf…

Atomic Physics · Physics 2009-11-13 Edmund Meyer , John Bohn

In this article, we have employed relativistic many-body theory to theoretically assess the suitability of TlF+ molecular ion in its ground state for electron electric dipole moment searches. To that end, we have computed values of the…

Atomic Physics · Physics 2022-10-12 R. Bala , V. S. Prasannaa , M. Abe , B. P. Das

This paper is a theoretical work in support of a newly proposed experiment (R. Stutz and E. Cornell, Bull. Am. Soc. Phys. 89, 76 2004) that promises greater sensitivity to measurements of the electron's electric dipole moment (EDM) based on…

Atomic Physics · Physics 2009-11-11 Edmund R. Meyer , John L. Bohn , Michael P. Deskevich

We report the results of theoretical investigation of electronic structure of ThF$^+$ cation which is one of the most interesting systems to search for the electron electric dipole moment (eEDM) [H. Loh, K.C. Cossel, M.C. Grau, K.-K. Ni,…

Atomic Physics · Physics 2015-05-01 L. V. Skripnikov , A. V. Titov

The molecular ion HfF$^+$ is the chosen species for a JILA experiment to measure the electron electric dipole moment (eEDM). Detailed knowledge of the spectrum of HfF is crucial to prepare HfF$^+$ in a state suitable for performing an eEDM…

An experiment to search for the electron electric dipole moment (\eEDM) on the metastable $H^3\Delta_1$ state of ThO molecule was proposed and now in the final stage of preparation by the ACME collaboration [http://www.electronedm.org]. To…

Chemical Physics · Physics 2013-12-13 L. V. Skripnikov , A. N. Petrov , A. V. Titov

The g-factors for $J = 1$, $F=3/2$, $|M_F|=3/2$ hyperfine levels of the ground electronic state $^3\Delta_1$ of the $^{232}$ThF$^+$ cation are calculated as functions of the external electric field. These calculations are necessary for the…

Atomic Physics · Physics 2025-03-05 Alexander Petrov , Leonid Skripnikov

Parity- and time-reversal-symmetry violating interaction constants required for the interpretation of a recent measurement (arXiv:1704.07928 [physics.atom-ph]) of corresponding symmetry violations in the $\Omega=1$ (${^3\Delta}_1$) science…

Atomic Physics · Physics 2017-10-18 Timo Fleig

The combined all-electron and two-step approach is applied to calculate the molecular parameters which are required to interpret the ongoing experiment to search for the effects of manifestation of the T,P-odd fundamental interactions in…

Atomic Physics · Physics 2017-07-14 L. V. Skripnikov

We perform laser induced fluorescence(LIF) spectroscopy on a pulsed supersonic beam of tungsten carbide(WC) molecules, which has been proposed as a candidate molecular system for a permanent Electric Dipole Moment(EDM) search of the…

Atomic Physics · Physics 2015-06-12 J. Lee , J. Chen , L. V. Skripnikov , A. N. Petrov , A. V. Titov , N. S. Mosyagin , A. E. Leanhardt
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