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The multiconfiguration Dirac-Hartree-Fock (MCDHF) method was employed to calculate atomic electric dipole moments (EDM) of the superheavy element copernicium (Cn, $Z=112$). The EDM enhancement factors of Cn, here calculated for the first…

Atomic Physics · Physics 2016-08-10 Laima Radžiūtė , Gediminas Gaigalas , Per Jönsson , Jacek Bieroń

We use advanced computational techniques to study the electronic structure of the Hf$^{12+}$ ion, with the goal of assessing its potential for use in highly accurate atomic optical clocks and search for new physics. Such clocks should…

Atomic Physics · Physics 2025-11-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

Energy levels, magnetic dipole, and electric quadrupole hyperfine structure of the superheavy element rutherfordium (Rf, $Z$=104) and its first three ions are calculated using a combination of the configuration interaction, coupled-cluster…

Atomic Physics · Physics 2021-12-14 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

Heavy polar diatomic molecules are the primary tools for searching for the T-violating permanent electric dipole moment of the electron (eEDM). Valence electrons in some molecules experience extremely large effective electric fields due to…

Atomic Physics · Physics 2015-06-11 V. S. Prasannaa , A. C. Vutha , M. Abe , B. P. Das

Recent improvements in experimental techniques for preparing ultracold molecules that contain alkali atoms (e.g., Li, Na, and K) have been reported. Based on these advances in ultracold molecules, new searches for the electric dipole moment…

Atomic Physics · Physics 2020-01-08 A. Sunaga , M. Abe , V. S. Prasannaa , T. Aoki , M. Hada

We have calculated energy levels and lifetimes of 4f7 and 4f6 5d configurations of Gd IV using Hartree-Fock and configuration interaction methods. This allows us to reduce significantly the uncertainty of the theoretical determination of…

Atomic Physics · Physics 2009-11-07 V. A. Dzuba , O. P. Sushkov , W. R. Johnson , U. I. Safronova

An analytical representation for the potential energy curve for the ground state $X^1\Sigma^+$ of the hydrogen fluoride molecule (HF) is presented in the frame of the Born-Oppenheimer approximation. The analytical expression for the…

Chemical Physics · Physics 2021-10-29 Laura E. Angeles Gantes , Horacio Olivares-Pilón

This paper describes the results of the most recent measurement of the permanent electric dipole moment (EDM) of neutral $^{199}$Hg atoms. Fused silica vapor cells containing enriched $^{199}$Hg are arranged in a stack in a common magnetic…

Atomic Physics · Physics 2017-08-21 B. Graner , Y. Chen , E. G. Lindahl , B. R. Heckel

We have calculated static and dynamic electric dipole (E1) polarizabilities ($\alpha_F$) of the hyperfine levels of the clock transition precisely in $^{133}$Cs. The scalar, vector, and tensor components of $\alpha_F$ are estimated by…

Atomic Physics · Physics 2024-02-09 A. Chakraborty , B. K. Sahoo

In order to realize more sensitive eEDM measurement, it would be worthwhile to find some new laser-cooled molecules with larger internal effective electric field (E$_{eff}$), higher electric polarizability and longer lifetime of the eEDM…

Atomic Physics · Physics 2019-03-13 Zhenghai Yang , Jing Li , Qinning Lin , Liang Xu , Hailing Wang , Tao Yang , Jianping Yin

We investigate the merits of a measurement of the permanent electric dipole moment of the electron ($e$EDM) with barium monofluoride molecules, thereby searching for phenomena of CP violation beyond those incorporated in the Standard Model…

Energies of ns[1/2] (n= 6-9), np[j] (n = 6-8), nd[j] (n= 6-7), and 5f[j] states in neutral Au and Au-like ions with nuclear charges Z = 80 - 83 are calculated using relativistic many-body perturbation theory. Reduced matrix elements,…

Atomic Physics · Physics 2009-11-10 U. I. Safronova , W. R. Johnson

The metastable a(1)[^3\Sigma^+] state of PbO has been suggested as a suitable system in which to search for the electric dipole moment (EDM) of the electron. We report here the development of experimental techniques allowing…

High Energy Physics - Experiment · Physics 2009-11-10 D. Kawall , F. Bay , S. Bickman , Y. Jiang , D. DeMille

We report first configuration interaction calculations of hyperfine constants A_\parallel and the effective electric field W_d acting on the electric dipole moment of the electron, in two excited electronic states of ^{207}PbO. The obtained…

Atomic Physics · Physics 2009-11-10 A. N. Petrov , A. V. Titov , T. A. Isaev , N. S. Mosyagin , D. DeMille

Recently, we determined the detailed energy level structure of the $X^1\Sigma^+$, $A^1\Pi$ and $a^3\Pi$ states of AlF that are relevant to laser cooling and trapping experiments. Here, we investigate the $b^3\Sigma^+, v=0$ state of the AlF…

The radiative decay of excited states of the negative ion of rhodium, Rh$^-$, has been investigated experimentally and theoretically. The experiments were conducted at the Double ElectroStatic Ion Ring Experiment (DESIREE) facility at…

The metastable $H \ {}^3\Delta_1$ state in the thorium monoxide (ThO) molecule is highly sensitive to the presence of a CP-violating permanent electric dipole moment of the electron (eEDM). The magnetic dipole moment $\mu_H$ and the…

Theoretical studies are presented how the electric dipole moment (EDM) of the electron in H-like ions in electrostatic storage rings can sensitively be determined. With the proposed experiments a new constraint of about $10^{-29}$ e cm for…

The LIBELLE experiment performed at the experimental storage ring (ESR) at the GSI Helmholtz Center for Heavy Ion Research in Darmstadt, Germany, has successfully determined the ground state hyperfine (HFS) splittings in hydrogen-like…

A proof-of-principle electron electric dipole moment (e-EDM) experiment using slow cesium atoms, nulled magnetic fields, and electric field quantization has been performed. With the ambient magnetic fields seen by the atoms reduced to less…

Atomic Physics · Physics 2008-11-26 Jason M. Amini , Charles T. Munger , Harvey Gould