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This review covers the important advances in recent years in the physics of thin film ferroelectric oxides, the strongest emphasis being on those aspects particular to ferroelectrics in thin film form. We introduce the current state of…

Materials Science · Physics 2009-11-11 M. Dawber , K. M. Rabe , J. F. Scott

Ferroelectricity has recently been demonstrated in germanium-based inorganic halide perovskites. We use atomistic first-principles-based simulations to study ultra-thin CsGeBr$_3$ films with thicknesses of 4-18 nm and develop a theory for…

Materials Science · Physics 2024-04-08 Ravi Kashikar , Arlies Valdespino , Charlton Ogg , Edvin Uppgard , S. Lisenkov , I. Ponomareva

The interplay between electrochemical surface charges and bulk ferroelectricity in thin films gives rise to a continuum of coupled ferro-ionic states. These states are exquisitely sensitive to chemical and electric conditions at the…

Materials Science · Physics 2017-05-24 Anna N. Morozovska , Eugene A. Eliseev , Nicholas V. Morozovsky , Sergei V. Kalinin

Ferroelectricity, a hallmark of spontaneous inversion-symmetry breaking, has been a central concept in condensed matter physics and functional materials research, yet recent discoveries are revealing that switchable polarization can emerge…

Materials Science · Physics 2026-05-11 Yudi Yang , Changming Ke , Shi Liu

A first-principles-derived approach is developed to study the effects of uncompensated depolarizing electric fields on the properties of Pb(Zr,Ti)O$_3$ ultrathin films for different mechanical boundary conditions. A rich variety of…

Materials Science · Physics 2009-11-10 Igor Kornev , Huaxiang Fu , L. Bellaiche

The four-state model is proposed for description of phase transition in ferroelectric crystals of DMAGaS and DMAAlS type. Thermodynamical functions of the model are obtained in the mean field approximation. The phase transition between…

Materials Science · Physics 2007-05-23 I. V. Stasyuk , O. V. Velychko

A large number of experimental studies suggest two-terminal resistive switching devices made of a dielectric thin film sandwiched by a pair of electrodes exhibit reversible multi-state switching behaviors; however coherent understanding of…

Applied Physics · Physics 2023-08-22 Foroozan S. Koushan , Nobuhiko P. Kobayashi

Ferroelectric materials are established candidates for beyond complementary metal-oxide-semiconductor technology, owing to their non-volatile spontaneous electrical polarization. The recent boom in electric dipole texture engineering and…

Materials Science · Physics 2026-01-29 Bixin Yan , Valentine Gillioz , Ipek Efe , Morgan Trassin

We consider both experimentally and analytically the transient oscillatory process that arises when a rapid change in voltage is applied to a $Ba_xSr_{1-x}TiO_3$ ferroelectric thin film deposited on an $Mg0$ substrate. High frequency…

Materials Science · Physics 2015-05-19 J. -G. Caputo , A. I. Maimistov , E. D. Mishina , E. V. Kazantseva , V. M. Mukhortov

The linear and nonlinear processes in ferromagnetic films at low temperatures T<< Tc are studied in a microscopic theory. Both the long-range magnetic dipole-dipole and the Heisenberg exchange interactions to nearest and next-nearest…

Strongly Correlated Electrons · Physics 2009-10-31 R. N. Costa Filho , M. G. Cottam , G. A. Farias

The reorientation transition of the magnetization of ferromagnetic films is studied on a microscopic basis within Heisenberg spin models. Analytic expressions for the temperature dependent anisotropy are derived from which it is seen that…

Statistical Mechanics · Physics 2009-10-31 A. Hucht , K. D. Usadel

A thermodynamic theory of ferroelectric thin film multilayers is developed. The free energy function is written down using a multilayer model in which c-domain layers of one ferroelectric material alternate with a-domain layers of a second…

Materials Science · Physics 2007-05-23 M. D. Glinchuk , E. A. Eliseev , V. A. Stephanovich , M. G. Karkut , R. Farhi

Silver nanoparticles embedded in a dielectric matrix are investigated for their potential as broadband-absorbing optical sensor materials. This contribution focuses on the electrical properties of silver nanoparticles at various…

Materials Science · Physics 2011-06-21 Haoyan Wei , Hergen Eilers

Ferroelectric ordering in liquids is a fundamental question of physics. Here, we show that ferroelectric ordering of the molecules causes formation of recently reported splay nematic liquid-crystalline phase. As shown by dielectric…

In the paper we consider size effects of phase transitions and polar properties of the thin antiferroelectric films. We modified phenomenological approach proposed by Kittel. The Euler-Lagrange equations were solved by direct variational…

Materials Science · Physics 2007-05-23 E. A. Eliseev , M. D. Glinchuk , A. N. Morozovska

Type-II multiferroics, where spin interactions induce a ferroelectric polarization, are interesting for new device functionalities due to large magnetoelectric coupling. We report on a new type of multiferroicity in the quadruple-perovskite…

Polycrystalline hafnia-based thin films exhibit mixed ferroelectric (FE), antiferroelectric (AFE), and dielectric (DE) behavior, with switching characteristics strongly influenced by microstructure and phase distribution. Here, we develop a…

Materials Science · Physics 2026-02-17 P. Pankaj , Sandeep Sugathan , Si Joon Kim , Pil-Ryung Cha

Epitaxial thin films of relaxor PbMg1/3Nb2/3O3 and PbSc0.5Nb0.5O3, and ferroelectric PbZr0.65Ti0.35O3, Pb0.955La0.045Zr0.65Ti0.35O3, and Ba0.4Sr0.6TiO3 were prepared, and their dielectric properties were studied in a broad range of the…

Materials Science · Physics 2009-11-11 M. Tyunina , J. Levoska , I. Jaakola

The electric coupling between surface ions and bulk ferroelectricity gives rise to a continuum of mixed states in ferroelectric thin films, exquisitely sensitive to temperature and external factors, such as applied voltage and oxygen…

Materials Science · Physics 2017-05-24 Anna N. Morozovska , Eugene A. Eliseev , Nicholas V. Morozovsky , Sergei V. Kalinin

Phase-field simulation (PFS) have revolutionized the understanding of domain structure and switching behavior in ferroelectric thin films and ceramics. Generally, PFS is based on solution of a (set) of Ginzburg-Landau equations for a…

Materials Science · Physics 2017-01-04 Ye Cao , Sergei V. Kalinin