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The switching polarization of a ferroelectric is a characterization of the current that flows due to changes in polarization when the system is switched between two states. Computation of this change in polarization in crystal systems has…

Materials Science · Physics 2020-07-29 John Bonini , David Vanderbilt , Karin M. Rabe

Ferroelectric thin films under epitaxial strain exhibit a variety of vortex-like topological polarization textures. To analyze them, we build on the Ginzburg-Landau-Devonshire framework and extend the previously introduced soft-domain…

Materials Science · Physics 2025-09-09 Léo Boron , Anaïs Sené , Yuri Tikhonov , Anna Razumnaya , Igor Lukyanchuk , Svitlana Kondovych

Surprisingly little is known about the microscopic processes that govern ferroelectric switching in orthorhombic ferroelectrics. To study microscopic switching processes we combine ab initio-based molecular dynamics simulations and data…

This paper provides a brief introduction to the phenomenological aspects of the polarization in ferrroelectric materials, and then an analysis of a few selected topics related to the modelling of ferroelectrics. The description of…

Emerging Technologies · Computer Science 2023-11-08 David Esseni , Francesco Driussi , Daniel Lizzit , Marco Massarotto , Mattia Segatto

Far-infrared and terahertz spectroscopy of ferroelectric soft and central modes in thin films on substrates is reviewed. In addition to classical displacive proper ferroelectrics, also incipient and relaxor ferroelectrics and multiferroics…

Materials Science · Physics 2016-11-17 Jan Petzelt , Stanislav Kamba

The films of order-disorder type ferroelectrics were considered in the mean field approximation taking into account depolarization field. It was shown that size effects in this system could be described on the base of bulk system equation…

Materials Science · Physics 2007-05-23 E. A. Eliseev , M. D. Glinchuk

We study ferroelectricity in thin films of pseudo-proper ferroelectrics such as the so-called spiral multiferroics. We find that this type of ferroelectricity stands better against depolarizing fields than conventional one. Its…

Strongly Correlated Electrons · Physics 2015-05-13 A. Cano , A. P. Levanyuk

Reliable organic ferroelectrics for memory applications require extreme endurance under repeated electrical switching. Here we demonstrate exceptional fatigue resistance in highly crystalline 2-methylbenzimidazole (MBI) films grown by…

Materials Science · Physics 2026-03-31 Bibek Tiwari , Yuanyuan Ni , Xiaoshan Xu

Ferroelectric materials can switch their polarization in response to an applied electric field. In this work, ferroelectricity at the single molecule level is proposed and investigated using density functional theory (DFT) calculations.…

Applied Physics · Physics 2017-05-30 Xinfeng Quan , Geoffrey R. Hutchison

Ferroelectric control of two-dimensional magnetism is promising in fabricating electronic devices with high speed and low energy consumption. The newly discovered layered MnBi$_2$Te$_4$(Bi$_2$Te$_3$)$_n$ and their Sb counterparts exhibit…

Materials Science · Physics 2023-09-29 Guoliang Yu , Chuhan Tang , Zhiqiang Tian , Ziming Zhu , Anlian Pan , Mingxing Chen , Xing-Qiu Chen

The demand for renewable and environmentally friendly energy source has attracted extensive research on high performance catalysts. Ferroelectrics which are a class of materials with a switchable polarization are the unique and promising…

Materials Science · Physics 2021-11-30 Weitong Ding , Xiao Tang , Wei Li , Liangzhi Kou , Lei Liu

This paper is concerned with modeling the polarization process in ferroelectric media. We develop a thermodynamically consistent model, based on phenomenological descriptions of free energy as well as switching and saturation conditions in…

Numerical Analysis · Mathematics 2020-09-17 Martin Meindlhumer , Astrid Pechstein , Alexander Humer

Ferroelectrics display spontaneous and switchable electrical polarization. Until recently, ferroelectricity was believed to disappear at the nanoscale; now, nano-ferroelectrics are being considered in numerous applications. This renewed…

Monte Carlo simulations have been used to investigate the dynamic phase behavior of a classical Heisenberg spin system with a bilinear exchange anisotropy in a planar thin film geometry. Studies of the field amplitude, frequency and…

Statistical Mechanics · Physics 2009-11-07 Hyunbum Jang , Malcolm J. Grimson , Carol K. Hall

We use molecular dynamics simulations to understand the mechanisms of polarization switching in ferroelectric BaTiO$_3$ achieved with external electric field. For tetragonal and orthorhombic ferroelectric phases, we determine the switching…

Materials Science · Physics 2009-11-13 Jaita Paul , Takeshi Nishimatsu , Yoshiyuki Kawazoe , Umesh V. Waghmare

A ferroelectric is a material with a polar structure whose polarity can be reversed by applying an electric field. In metals, the itinerant electrons tend to screen electrostatic forces between ions, helping to explain why polar metals are…

The existence of ferroelectricity in {$\mathrm{BiMnO}_3$} has been a long-standing question for both experimentalists and theorists. In addition to a highly distorted bulk structure, the ionic crystal planes cause a large roughness in thin…

Materials Science · Physics 2017-04-11 Yun-Peng Wang , J. N. Fry , Hai-Ping Cheng

Layered perovskites are a versatile class of ferroelectrics with their structural anisotropy reflected in unusual electrostatics that give rise to exceptional ferroelectric properties. These materials fall into four main families:…

Materials Science · Physics 2025-08-29 Elzbieta Gradauskaite

A stochastic model for the field-driven polarization reversal in rhombohedral ferroelectrics is developed, providing a description of their temporal electromechanical response. Application of the model to simultaneous measurements of…

Recent observations of unusual ferroelectricity in thin films of HfO_2 and related materials have attracted broad interest to the materials and led to the emergence of a number of competing models for observed behaviors. Here we develop the…

Materials Science · Physics 2018-11-27 Maya D. Glinchuk , Anna N. Morozovska , Yunseok Kim , Sergei V. Kalinin