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A microscopic theory of spin fluctuations of localized electrons interacting with optically cooled nuclear spin bath has been developed. Since nuclear spin temperature may stay low enough for macroscopically long time, the nuclear spin…

Mesoscale and Nanoscale Physics · Physics 2015-05-05 D. S. Smirnov

Dynamic nuclear polarization (DNP) of molecules in a solution at room temperature has potential to revolutionize nuclear magnetic resonance spectroscopy and imaging. The prevalent methods for achieving DNP in solutions are typically most…

Chemical Physics · Physics 2016-03-02 Qiong Chen , Ilai Schwarz , Fedor Jelezko , Alex Retzker , Martin B Plenio

We propose a new, more efficient, and potentially cost effective, solid-state nuclear spin hyperpolarization method combining the Cross Effect mechanism and electron spin optical hyperpolarization in rotating solids. We first demonstrate…

Quantum Physics · Physics 2022-01-25 Frederic Mentink-Vigier , Vinayak Rane , Thierry Dubroca , Krishnendu Kundu

Recent experimental breakthroughs have demonstrated that the electron spin in silicon can be reliably injected and detected as well as transferred over distances exceeding 1 mm. We propose an on-chip communication paradigm which is based on…

Materials Science · Physics 2011-09-23 Hanan Dery , Yang Song , Pengke Li , Igor Zutic

It is shown that in organic semiconductors where organic magnetoresistance (OMAR) is observed, the exchange interaction between electrons and holes localized at different molecules leads to dynamic spin polarization in the direction of the…

Disordered Systems and Neural Networks · Physics 2022-04-06 A. V. Shumilin

Dissolution Dynamic Nuclear Polarisation (dDNP) increases the sensitivity of magnetic resonance experiments by $>10^4$-fold, permitting isotopically-labelled molecules to be transiently visible in MRI scans. dDNP requires a source of…

By applying a new technique for dynamic nuclear polarization involving simultaneous excitation of electronic and nuclear transitions, we have enhanced the nuclear polarization of the nitrogen nuclei in 15N@C60 by a factor of 1000 at a fixed…

Transition metal defects in SiC give rise to localized electronic states that can be optically addressed in the telecom range in an industrially mature semiconductor platform. This has led to intense scrutiny of the spin and optical…

The nature of the nano-scale environment presents a major challenge for solid-state implementation of spin-based qubits. In this work, a single electron spin in an optically pumped nanometer-sized III-V semiconductor quantum dot is used to…

Despite decades of research, demonstration of all-optical detection and control of free electron spins in silicon remains elusive. Here, we directly probe the electron spin properties in bulk silicon by measuring the polarization of…

We report hyperpolarization of the electronic spins associated with substitutional nitrogen defects in bulk diamond crystal. Hyperpolarization is achieved by optical pumping of nitrogen vacancy centers followed by rapid cross relaxation at…

Mesoscale and Nanoscale Physics · Physics 2017-02-22 M. Loretz , H. Takahashi , T. F. Segawa , J. M. Boss , C. L. Degen

We discuss the polarization dynamics during solid effect dynamic nuclear polarization (DNP) in a central spin model that consists of an electron surrounded by many nuclei. To this end we use a recently developed formalism and validate first…

Other Condensed Matter · Physics 2016-03-23 Daniel Wiśniewski , Alexander Karabanov , Igor Lesanovsky , Walter Köckenberger

Spin-$\frac{1}{2}$ $^{119}$Sn nuclei in a silicon semiconductor could make excellent qubits. Nuclear spins in silicon are known to have long coherence times. Tin is isoelectronic with silicon, so we expect electrons can easily shuttle from…

Quantum Physics · Physics 2022-06-14 Wayne M. Witzel , Jesse J. Lutz , Dwight R. Luhman

The electron spins of semiconductor defects can have complex interactions with their host, particularly in polar materials like SiC where electrical and mechanical variables are intertwined. By combining pulsed spin resonance with ab-initio…

We determine the polarization of the bulk $^{13}$C nuclear spin system in diamond produced by interaction with optically oriented nitrogen-vacancy (NV-) defect centers. $^{13}$C nuclei are polarized into the higher energy Zeeman state with…

Other Condensed Matter · Physics 2015-05-14 Jonathan P. King , Patrick J. Coles , Jeffrey A. Reimer

Optically polarizable nitrogen-vacancy (NV) center in diamond enables the hyperpolarization of $^{13}$C nuclear spins at low magnetic field and room temperature. However, achieving a high level of polarization comparable to conventional…

Quantum Physics · Physics 2024-10-01 Vladimir V. Kavtanyuk , Changjae Lee , Keunhong Jeong , Jeong Hyun Shim

Dynamic nuclear polarization enables the hyperpolarization of nuclear spins beyond the thermal-equilibrium Boltzmann distribution. However, it is often unclear why the experimentally measured hyperpolarization is below the theoretical…

Chemical Physics · Physics 2023-12-13 Gevin von Witte , Aaron Himmler , Sebastian Kozerke , Matthias Ernst

In a theoretical study, we investigate the spin dynamics of interacting nitrogen-vacancy (NV) centers and quadrupolar I = 3/2 nuclear spins, specifically 11B spins in hexagonal boron nitride (h-BN) nanosheets located near the microdiamond…

Quantum Physics · Physics 2024-10-03 Lu Chen , Jiawen Jiang , Martin B. Plenio , Qiong Chen

Van der Waals layered materials are a focus of materials research as they support strong quantum effects and can easily form heterostructures. Electron spins in van der Waals materials played crucial roles in many recent breakthroughs,…

The hyperpolarisation of nuclear spins within target molecules is a critical and complex challenge in magnetic resonance imaging (MRI) and nuclear magnetic resonance (NMR) spectroscopy. Hyperpolarisation offers enormous gains in signal and…