English

Structure of saturated RSA ellipse packings

Soft Condensed Matter 2022-10-25 v2

Abstract

Motivated by the recent observation of liquid glass in suspensions of ellipsoidal colloids, we examine the structure of (asymptotically) saturated RSA ellipse packings. We determine the packing fractions ϕs(α)\phi_{\rm s}(\alpha) to high precision, finding an empirical analytic formula that predicts ϕs(α)\phi_{\rm s}(\alpha) to within less than 0.1%0.1\% for all α10\alpha \leq 10. Then we explore how these packings' positional-orientational order varies with α\alpha. We find a transition from tip/side- to side/side-contact-dominated structure at α=αTS2.4\alpha = \alpha_{\rm TS} \simeq 2.4. At this aspect ratio, the peak value gmaxg_{\rm max} of packings' positional-orientational paircorrelation functions is minimal, and systems can be considered maximally locally disordered. For smaller (larger) α\alpha, gmaxg_{\rm max} increases exponentially with deceasing (increasing) α\alpha. Local nematic order and structures comparable to the precursor domains observed in experiments gradually emerge as α\alpha increases beyond 33. For α5\alpha \gtrsim 5, single-layer lamellae become more prominent, and long-wavelength density fluctuations increase with α\alpha as packings gradually approach the rod-like limit.

Keywords

Cite

@article{arxiv.2210.02388,
  title  = {Structure of saturated RSA ellipse packings},
  author = {Pedro Abritta and Robert S. Hoy},
  journal= {arXiv preprint arXiv:2210.02388},
  year   = {2022}
}

Comments

Accepted for publication in Physical Review E