English

Structure of jammed ellipse packings with a wide range of aspect ratios

Soft Condensed Matter 2023-06-01 v1

Abstract

Motivated in part by the recent observation of liquid glass in suspensions of ellipsoidal colloids, we examine the structure of jammed ellipse packings over a much wider range of particle aspect ratios (α\alpha) than has been previously attempted. We determine ϕJ(α)\phi_{\rm J}(\alpha) to high precision, and find empirical analytic formulae that predict ϕJ(α)\phi_{\rm J}(\alpha) to within less than 0.1% for all 1α101 \leq \alpha \leq 10, for three different particle dispersities. We find that the densest packings possess unusually-well-defined nearest-neighbor shells, including both a higher fraction fZ=6f_{\rm Z = 6} of particles with exactly six contacts and a previously-unreported short-range order marked by ``kinetically suppressed'' regions in their positional-orientational pair correlation function g(r,Δθ)g(r,\Delta \theta). We also show that the previously-reported approach to isostaticity (coordination number ZJZiso6Z_{\rm J} \to Z_{\rm iso} \equiv 6) with increasing α\alpha is interrupted and then reversed as local nematic order increases: ZJ(α)Z_{\rm J}(\alpha) drops towards 4 as ellipses are more often trapped by contacts with a parallel-oriented neighbor on either side and a perpendicularly-oriented neighbor on either end. Finally we show that ϕJ/ϕs\phi_{\rm J}/\phi_{\rm s} (where ϕs\phi_{\rm s} is the saturated RSA packing density) is nearly α\alpha-independent for systems that do not develop substantial local hexatic or nematic order during compression.

Keywords

Cite

@article{arxiv.2305.19990,
  title  = {Structure of jammed ellipse packings with a wide range of aspect ratios},
  author = {Sebastian Rocks and Robert S. Hoy},
  journal= {arXiv preprint arXiv:2305.19990},
  year   = {2023}
}