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Random sequential adsorption of aligned rectangles with two discrete orientations: Finite-size scaling effects

Materials Science 2023-12-01 v1

Abstract

We study saturated packings produced according to random sequential adsorption (RSA) protocol built of identical rectangles deposited on a flat, continuous plane. An aspect ratio of rectangles is defined as the length-to-width ratio, f=l/wf=l/w. The rectangles have a fixed unit area (i.e., l×w=1l \times w=1), and therefore, their shape is defined by the value of ff (l=fl=\sqrt{f} and w=1/fw=1/\sqrt{f}). The rectangles are allowed to align either vertically or horizontally with equal probability. The particles are deposited on a flat square substrate of side length LL (measured in units of particle length, L[20,1000]L \in [20, 1000]) and periodic boundary conditions are applied along both directions. The finite-size scaling effects are characterized by a scaled anisotropy defined as α=l/L=f/L\alpha = l/L = \sqrt{f}/L. We showed that the properties of such packings strongly depend on the value of aspect ratio ff and the most significant scaling effects are observed for relatively long rectangles when lL/2l\ge L/2 (i.e. α0.5\alpha \ge 0.5). It is especially visible for the mean packing fraction as a function of the scaled anisotropy α\alpha. The kinetics of packing growth for low to moderate rectangle anisotropy is to be governed by lnt/t\ln t/t law, where tt is proportional to the number of RSA iterations, which is the same as in the case of RSA of parallel squares. We also analyzed global orientational ordering in such packings and properties of domains consisting of a set of neighboring rectangles of the same orientation, and the probability that such domain forms a percolation.

Keywords

Cite

@article{arxiv.2306.03259,
  title  = {Random sequential adsorption of aligned rectangles with two discrete orientations: Finite-size scaling effects},
  author = {Luca Petrone and Nikolai Lebovka and Michał Cieśla},
  journal= {arXiv preprint arXiv:2306.03259},
  year   = {2023}
}

Comments

14 pages, 9 figures

R2 v1 2026-06-28T10:57:14.082Z